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Abstracts with Programs - Geological Society of America

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SESSION NO. 1<br />

1-4 9:00 AM Johns, Elizabeth K. [218366]<br />

SITE SPECIFIC GEOCHEMICAL MODELING OF GROUNDWATER, ROCK AND CARBON<br />

DIOXIDE INTERACTIONS: IMPLICATIONS FOR GEOLOGIC CARBON SEQUESTRATION<br />

JOHNS, Elizabeth K., Geology, Geography, and Planning, MSU, 901 South National,<br />

Springfield, MO 65897, elizabeth4@live.missouristate.edu and GOUZIE, Douglas R.,<br />

Department <strong>of</strong> Geography, Geology & Planning, Missouri State University, 901 S. National,<br />

Springfield, MO 65897<br />

Geologic carbon sequestration is a process <strong>of</strong> mitigation that has the potential to reduce the<br />

impact <strong>of</strong> carbon dioxide emissions into the atmosphere through the injection <strong>of</strong> carbon dioxide<br />

into a saline aquifer.<br />

This research utilized geochemical modeling <strong>of</strong> groundwater, rock and carbon dioxide<br />

interactions for geologic carbon sequestration purposes. Long term storage <strong>of</strong> carbon dioxide is<br />

an important requirement <strong>of</strong> geologic carbon sequestration. Because geochemical processes<br />

are responsible for the long term storage <strong>of</strong> carbon dioxide, it is necessary to understand the<br />

extent to which carbon dioxide can be trapped by geochemical trapping mechanisms. This study<br />

investigated the extent to which carbon dioxide can be sequestered in the Lamotte Sandstone,<br />

a Cambrian aged saline aquifer, due to solubility and mineral trapping. A comparison <strong>of</strong> the<br />

geochemical suitability <strong>of</strong> three well sites in North-Central Missouri was also conducted. The<br />

program Geochemist’s Workbench was used for the geochemical modeling simulations performed<br />

for this study. Site specific data such as temperature, carbon dioxide fugacity, pH, mineral content<br />

and groundwater composition were the input parameters needed to simulate the sequestration<br />

<strong>of</strong> carbon dioxide in a saline aquifer due to geochemical trapping mechanisms. Preliminary<br />

simulations have been performed for the first site and for both hypothetical injection and post<br />

injection phases <strong>of</strong> carbon sequestration.<br />

For an example site, preliminary results show approximately 67 g/kg aqueous and 4 g/kg solid<br />

phase sequestered CO2, during the injection phase. Post injection phase results for this site<br />

indicate approximately 42 g/kg aqueous and 37 g/kg solid phase sequestered CO2. Aqueous<br />

species most involved in solubility trapping included CO2 (aq) , HCO3-, NaHCO3, CaHCO3+,<br />

MgHCO3+ and FeHCO3+. Mineral species involved in mineral trapping included dawsonite,<br />

dolomite and siderite. For this example site a possible preliminary effective sequestration capacity<br />

was calculated as .36 gigatons per 100 km².<br />

This material is based on work sponsored by the Department <strong>of</strong> Energy National Energy<br />

Technology Laboratory under Award Number DE-NT0006642 to City Utilities <strong>of</strong> Springfield MO.<br />

1-5 9:20 AM Mayle, Emme [218072]<br />

RELATIONSHIP BETWEEN DEPTH AND HYDRAULIC CONDUCTIVITY WITHIN THE<br />

ST. FRANCOIS AQUIFER, MISSOURI<br />

MAYLE, Emme, Geography, Geology, Planning, Missouri State University, 901 S. National,<br />

Springfield, MO 65897, emme27@live.missouristate.edu and ROVEY, Charles W. II,<br />

Geography, Geology, and Planning, Missouri State University, 901 S. National, Springfield,<br />

MO 65897<br />

The St. Francois aquifer is a prolific groundwater source near its outcrop area in southeastern<br />

Missouri, but is rarely tapped in the southwest part <strong>of</strong> the state due to the presence <strong>of</strong> the<br />

shallower Ozark aquifer. Nevertheless, the St. Francois aquifer may become an important<br />

supplementary source <strong>of</strong> groundwater in areas experiencing severe drawdowns <strong>with</strong>in the Ozark<br />

aquifer. This aquifer is also a target for CO2 injection in northern Missouri where the pore water<br />

is saline.<br />

The main water-bearing unit <strong>with</strong>in the St. Francois aquifer is the Lamotte Sandstone, the<br />

basal Cambrian sandstone above Precambrian basement. An overlying sandstone (Reagan),<br />

separated from the Lamotte by low-permeability siltstones and shales, is also present in<br />

portions <strong>of</strong> southwest Missouri. We measured the transmissivity and hydraulic conductivity <strong>of</strong><br />

these sandstones at three sites <strong>with</strong> single-well pumping tests as part <strong>of</strong> the Missouri Carbon<br />

Sequestration Program. We also analyzed time-drawdown and specific-capacity measurements<br />

from 13 additional tests on file at the Missouri Division <strong>of</strong> Geology and Land Survey.<br />

Transmissivity and hydraulic conductivity (K) vary inversely <strong>with</strong> depth. At depths less than<br />

~ 370 m, K varies between 10-3 and 10-2 cm/sec; these wells generally yield > 600 gpm. Below<br />

this depth K decreases due to pervasive cementation. By 550 m, K decreases to ~10-4 cm/sec,<br />

and this depth seems to mark the lower practical limit <strong>of</strong> these sandstones as an aquifer. By<br />

650 m, K decreases to around 10-5cm/sec and the sandstones become marginal for CO injection,<br />

2<br />

except in locations where the Lamotte fills in topographic lows on the Precambrian surface and is<br />

unusually thick.<br />

This material is based on work sponsored by the Department <strong>of</strong> Energy National Energy<br />

National Energy Technology Laboratory under Award Number DE-NT0006642 to City Utilities <strong>of</strong><br />

Springfield, MO<br />

1-6 10:00 AM Stratton, Stephanie L. [218223]<br />

SIMULATION OF CO INJECTION INTO ST. FRANCOIS AQUIFER, GREENE COUNTY,<br />

2<br />

MISSOURI<br />

STRATTON, Stephanie L., Department <strong>of</strong> Geography, Geology, & Planning, Missouri State<br />

University, 901 S. National Ave, Springfield, MO 65897, Stratton89@missouristate.edu and<br />

ROVEY, Charles W. II, Geography, Geology, and Planning, Missouri State University, 901 S.<br />

National, Springfield, MO 65897<br />

Geologic carbon sequestration is being investigated as a means <strong>of</strong> reducing the CO emission<br />

2<br />

from anthropogenic sources in Missouri. The St. Francois aquifer is the deepest available<br />

reservoir in Missouri for carbon sequestration; however, the aquifer is not deep enough to allow<br />

injection <strong>of</strong> CO at supercritical phase <strong>with</strong>in Greene County. The Missouri Carbon Sequestration<br />

2<br />

Project had hoped to establish an injection test into the aquifer at the City Utilities <strong>of</strong> Springfield<br />

Southwest Power Plant (SWPP) site, but the pore fluids were not saline. Since data was available<br />

from the site, it was used to learn more about simulating carbon sequestration.<br />

The program AQTESOLV Pro was used to evaluate pumping and pressure-injection data<br />

from SWPP to determine hydraulic conductivities. Those data were then implemented in the<br />

program PetraSim 5.2 to develop simulations to help determine how the CO might behave<br />

2<br />

hydrodynamically. Compositional simulations <strong>with</strong> pressure gradients <strong>of</strong> 0.98 Pa/m and 9.8 Pa/m<br />

were generated to reveal plume migration patterns under injection and retrograde conditions.<br />

Simulations were a thousand years in duration <strong>with</strong> an initial 30 year injection period followed<br />

by a shut-<strong>of</strong>f period. Simulated injection was <strong>with</strong>in two high hydraulic conductivity zones in the<br />

Reagan Sandstone and Lamotte Sandstone <strong>of</strong> the St. Francois aquifer. A polygonal grid mesh<br />

was also used <strong>with</strong> high resolution around the injection well.<br />

The highest achievable injection rates were <strong>with</strong>in the Reagan Sandstone. This was in<br />

correlation to the upper Reagan Sandstone having a permeability <strong>of</strong> 1.35E-13 m2 ; whereas the<br />

Lamotte Sandstone’s highest permeability was only 8.92E-15 m2 . The maximum migration <strong>of</strong> gas<br />

as a separate phase was approximately 4.0 km after a thousand years for simulations <strong>with</strong> well<br />

completion through the Reagan Sandstone. The maximum migration <strong>of</strong> gas as a separate phase<br />

<strong>with</strong> injection into the Lamotte Sandstone was approximately 700 meters.<br />

This material is based on work sponsored by the Department <strong>of</strong> Energy National Energy<br />

Technology Laboratory under Award Number DEFG2610FE0001790 to Missouri State University.<br />

2 2013 GSA <strong>Abstracts</strong> <strong>with</strong> <strong>Programs</strong><br />

1-7 10:20 AM Smolenski, Rebecca Lynn [218774]<br />

GREENHOUSE GAS EMISSIONS FROM A TEMPERATE AGRICULTURAL RESERVOIR<br />

SMOLENSKI, Rebecca Lynn, <strong>Geological</strong> Sciences, University <strong>of</strong> Cincinnati, 3352 Jefferson<br />

Ave, Apt 2, Cincinnati, OH 45220, smolenrl@gmail.com, BEAULIEU, Jake, Environmental<br />

Protection Agency, Cincinnati, OH 45268, and TOWNSEND-SMALL, Amy, Department<br />

<strong>of</strong> Geology and Department <strong>of</strong> Geography, University <strong>of</strong> Cincinnati, 605 Geology-Physics<br />

Building, Cincinnati, OH 45221<br />

Reservoirs are being built at an increasing rate each year to provide humans <strong>with</strong> resources<br />

such as hydroelectric power and drinking water. These man made systems have provided<br />

society <strong>with</strong> important services but these have come at the cost <strong>of</strong> enhanced greenhouse gas<br />

(GHG) emissions. Recent estimates suggest reservoirs are a globally significant source <strong>of</strong> GHG<br />

emissions but these estimates are largely based on studies <strong>of</strong> oligotrophic boreal and tropical<br />

reservoirs. Reservoirs draining agricultural basins are common throughout much <strong>of</strong> the developed<br />

and are subject to high nutrient loading rates from the watershed. Excess nutrient loading<br />

stimulates algae blooms and degrades water quality in these reservoirs but surprisingly little is<br />

known about how nutrients and algal blooms affect GHG dynamics. To assess GHG dynamics in<br />

an agricultural reservoir we measured GHG emission rates, dissolved concentrations and nutrient<br />

chemistry in William H. Harsha Lake, an agricultural reservoir located in southwestern Ohio on a<br />

monthly basis since October 2011.<br />

Average daily emissions <strong>of</strong> methane (CH ) were 50 mg CH -C m 4 4 -2 d-1 . The highest emissions<br />

rates <strong>of</strong> CH were observed during the summer months and during fall turnover, and the lowest<br />

4<br />

emissions were observed during the winter. Depth pr<strong>of</strong>iles <strong>of</strong> dissolved CH throughout the<br />

4<br />

summer show an accumulation <strong>of</strong> CH in the hypolimnium while the lake is thermally stratified.<br />

4<br />

Average daily nitrous oxide (N O) emissions were 0.80 mg N O-N m 2 2 -2 d-1 . The highest<br />

emissions were during fall turnover. During late summer, parts <strong>of</strong> the lake became a sink for N O, 2<br />

and depth pr<strong>of</strong>iles <strong>of</strong> N O show a similar trend <strong>with</strong> the water column becoming undersaturated<br />

2<br />

<strong>with</strong> N O during this time. Without N O accumulation in the water column during thermal<br />

2 2<br />

stratification, it is likely that the source <strong>of</strong> N O during fall turnover is nitrification <strong>of</strong> remineralized<br />

2<br />

ammonium.<br />

SESSION NO. 2, 8:00 AM<br />

Thursday, 2 May 2013<br />

Geophysics, Geodynamics, etc.<br />

Fetzer Center, Room 2040<br />

2-1 8:00 AM Larson, Mark [218656]<br />

GRAVITY AND MAGNETIC ANALYSIS OF PLUTONS, RING PLUTONS AND MAFIC BODIES IN<br />

THE ST FRANCOIS MOUNTAINS, SE MISSOURI<br />

LARSON, Mark and MICKUS, Kevin, Geology, Missouri State University, Springfield, MO<br />

65897, Mark3@live.missouristate.edu<br />

The St. Francois Mountains <strong>of</strong> southeast Missouri are a Proterozoic volcanic complex composed<br />

<strong>of</strong> felsic plutons, ring intrusions, and massifs, and is the largest exposure <strong>of</strong> Proterozoic lithologies<br />

in the south-central US. The development <strong>of</strong> the St. Francois Mountains is not well understood<br />

and there are three main theories that are currently under consideration: 1) hotspot/melting,<br />

2) subduction volcanism, and 3) rift related volcanism. Since the proterozoic volcanic activity, the<br />

region has been faulted by forces related to the Reelfoot Rift in the Cambrian and reactivation in<br />

the Cretaceous, and more recently by the New Madrid Fault zone. Geologic mapping and regional<br />

magnetic anomaly interpretation has proposed that the region consists <strong>of</strong> a few large felsic<br />

calderas. Our research focuses on analyzing gravity and magnetic data to determine the upper<br />

crustal structure <strong>of</strong> the region in order to relate these data to the location <strong>of</strong> proposed caldera<br />

rims, as well as mafic bodies, and better understand their origin.<br />

Using existing gravity and magnetic data as a guideline for the location <strong>of</strong> new data, we first<br />

conducted a gravity survey to add data to regions <strong>with</strong>out data. The merged data, in the form<br />

<strong>of</strong> Bouguer gravity anomaly maps, identified anomalies that agreed <strong>with</strong> existing structural data<br />

<strong>of</strong> the region. Then additional detailed (1 mile spacing) gravity data were collected along two<br />

pr<strong>of</strong>iles that cut across the large amplitude anomalies associated <strong>with</strong> the calderas. These data<br />

were be modeled by 2D forward modeling to determine the subsurface geometry <strong>of</strong> the calderas<br />

constrained by surface density measurements and surface features. Additionally, a series <strong>of</strong><br />

residual, regional and derivative gravity and magnetic anomaly maps have been constructed to<br />

aid in the interpretation <strong>of</strong> the 2D models. Collection <strong>of</strong> rock samples at the surface has given<br />

density data to constrain our models. Core samples will be analyzed for densities and magnetic<br />

susceptibilities in order to further constrain the gravity models. Using the final anomaly maps and<br />

models we will interpret them in order to determine the nature and origin <strong>of</strong> the calderas in the<br />

St. Francois Mountains region.<br />

2-2 8:20 AM Evans, Kevin R. [217445]<br />

PRE-OUACHITA TECTONISM, DEVELOPMENT OF A BACK-STEPPING SHELF MARGIN,<br />

AND SYN-TECTONIC SEDIMENTATION (MIDDLE DEVONIAN THROUGH MISSISSIPPIAN)<br />

ON SOUTHERN LAURENTIA: A REGIONAL SYNTHESIS OF THE OZARKS<br />

EVANS, Kevin R., Geography, Geology, & Planning Dept, Missouri State University,<br />

Springfield, MO 65897, kevinevans@missouristate.edu, BASSETT, Damon J., <strong>Geological</strong><br />

Sciences, University <strong>of</strong> Missouri, 101 <strong>Geological</strong> Sciences Bldg, Columbia, MO 65211,<br />

ETHINGTON, Raymond L., <strong>Geological</strong> Sciences Dept, University <strong>of</strong> Missouri-Columbia,<br />

Columbia, MO 65211, MANGER, Walter L., Department <strong>of</strong> Geosciences, Univ <strong>of</strong> Arkansas,<br />

Fayetteville, AR 72701, MICKUS, Kevin L., Geosciences, Missouri State Univ, 901 S National<br />

Ave, Springfield, MO 65804-0087, and MILLER, James F., Geography, Geology, & Planning<br />

Dept, Missouri State University, Springfield, MO 655897<br />

Southern Laurentia in the Ozarks region has been characterized as a Late Proterozoic rift<br />

shoulder that developed into a passive margin; docking <strong>with</strong> the Ouachita allochthon during<br />

the Early Pennsylvanian led to development <strong>of</strong> the Arkoma Basin and Ozark Uplift. Yet, why<br />

were pre-Mississippian strata progressively truncated to the north and west? Why was the<br />

Chattanooga Shale preserved in southwestern Missouri and northwestern Arkansas but eroded<br />

below the Mississippian in the Boston Mountains? Why did deep-water Mississippian carbonates<br />

accumulate in southern Missouri on peritidal lower Paleozoic strata? We consider that much <strong>of</strong><br />

the epeirogenic uplift and denudation <strong>of</strong> the Ozarks preceded the Ouachita orogeny, occurring in<br />

the Early to Middle Devonian, and structural evolution persisted through Mississippian and Early<br />

Pennsylvanian time.<br />

The onset <strong>of</strong> convergence led to development <strong>of</strong> the Arkansas Novaculite foredeep, and in<br />

the Ozarks, loading and flexure resulted in progressive truncation <strong>of</strong> much <strong>of</strong> the post-lower<br />

Ordovician to pre-Mississippian succession. Up to 500 m <strong>of</strong> strata were cut out, yet impact

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