22.07.2013 Views

THE ROLE OF THE

THE ROLE OF THE

THE ROLE OF THE

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

Traditional Role of the Chemist in the Automobile Plant Environment 19<br />

table 2.4<br />

Property table of salts of ricinoleic acid oligomer cutting Fluids<br />

r or esters of<br />

Polymer (X)<br />

(X-ocor) pH<br />

rust Inhibition test<br />

duration (h) a<br />

24 48 72<br />

Friction<br />

coefficient<br />

surface<br />

tension<br />

10 –3<br />

(n/m)<br />

Initial<br />

seizure<br />

load<br />

(mPa)<br />

dimer-o-cor<br />

C 9H 19 9.0 10 10 10 0.09 41 1.91<br />

C 11H 23 9.1 10 10 10 0.08 41 1.76<br />

C 17H 33 9.4 10 10 10 0.08 41 1.96<br />

trimer-o-cor<br />

C 9H 19 9.0 10 10 10 0.09 41 1.96<br />

C 11H 23 8.9 10 10 10 0.08 42 1.96<br />

C 17H 33 9.3 10 10 10 0.08 43 1.76<br />

tetramer-o-cor<br />

C 9H 19 9.0 10 10 10 0.09 43 1.96<br />

C 11H 23 9.1 10 10 10 0.08 44 1.96<br />

C 17H 33 9.6 10 10 10 0.08 41 1.96<br />

Hexamer-o-cor<br />

C9H19 9.4 10 10 9 0.09 44 1.96<br />

C11H23 9.3 10 10 10 0.08 45 1.96<br />

C17H33 9.3 10 10 10 0.08 37 1.96<br />

Ricinoleic acid 8.8 10 9 8 0.12 43 1.81<br />

Ricinoleic acid<br />

dimer<br />

9.1 10 9 8 0.1 41 1.86<br />

Ricinoleic acid<br />

trimer<br />

9.7 9 9 7 0.09 37 1.67<br />

Ricinoleic acid<br />

tetramer<br />

9.8 9 9 7 0.09 36 1.81<br />

Ricinoleic acid<br />

hexamer<br />

10.0 9 9 7 0.09 43 1.91<br />

Triethanolamine<br />

(2% aqueous<br />

solution)<br />

10.1 7 6 5 0.21 70 0.83<br />

a Evaluation of rust inhibition test:<br />

amount of rust<br />

valuation<br />

Point<br />

No appearance of rust 10<br />

One point of rust 9<br />

Two points of rust 8<br />

Some points of rust 7<br />

Many points of rust 6<br />

Many points of rust and stains 5<br />

Source: Watanabe, S. J. Oleo Sci., 56, 385, 2007. With permission.

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!