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Dr Faustus of Modern Physics - Department of Speech, Music and ...

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28.1. LIFE AND WORK 123<br />

constitution, <strong>and</strong> the role <strong>of</strong> probability in this relationship are involved<br />

<strong>and</strong> differed quite remarkably in different periods <strong>of</strong> his life. Indeed,<br />

in his first paper in statistical physics <strong>of</strong> 1866, he claimed to obtain a<br />

completely general theorem from mechanics that would prove the second<br />

law. However, thirty years later he stated that the second law could<br />

never be proved by mechanical means alone, but depended essentially<br />

on probability theory.<br />

• In his lifelong struggle with the problem he employed a varying arsenal<br />

<strong>of</strong> tools <strong>and</strong> assumptions. (To mention a few: the so-called<br />

Stosszahlansatz, the ergodic hypothesis, ensembles, the permutational<br />

argument, the hypothesis <strong>of</strong> molecular disorder.) However, the exact<br />

role <strong>of</strong> these assumptions, <strong>and</strong> the results he obtained from them, also<br />

shifted in the course <strong>of</strong> time. Particularly notorious are the role <strong>of</strong> the<br />

ergodic hypothesis <strong>and</strong> the status <strong>of</strong> the so-called H-theorem.<br />

• Moreover, he used “probability” in four different technical meanings.<br />

It is, therefore, not easy to speak <strong>of</strong> a consistent, single “Boltzmannian<br />

approach” to statistical physics. It is the purpose <strong>of</strong> this essay<br />

to describe the evolution <strong>of</strong> a selection <strong>of</strong> these approaches <strong>and</strong> their<br />

conceptual problems.<br />

Wikipedia:<br />

• Around 1900 Boltzmanns science was being threatened by physicists<br />

claiming that all electromagnetic behavior is continuous <strong>and</strong> that all<br />

physical behavior ultimately is electromagnetic (more or less the authors<br />

view). This deeply depressed Boltzmann since it could mean the end <strong>of</strong><br />

his kinetic theory <strong>and</strong> statistical interpretation <strong>of</strong> the second law <strong>of</strong><br />

thermodynamics.<br />

• After Mach’s resignation in Vienna in 1901, Boltzmann returned there<br />

<strong>and</strong> decided to become a philosopher himself to refute philosophical objections<br />

to his physics, but he soon became discouraged again. In 1904<br />

at a physics conference in St. Louis most physicists seemed to reject<br />

atoms <strong>and</strong> he was not even invited to the physics section.<br />

• Rather, he was stuck in a section called “applied mathematics,” he<br />

violently attacked philosophy, especially on allegedly Darwinian grounds<br />

but actually in terms <strong>of</strong> Lamarcks theory <strong>of</strong> the inheritance <strong>of</strong> acquired

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