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paraffin wax deposition and fouling

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— 19<br />

-<br />

toat sur:ace.<br />

hjsima.a ot al showed that the nature of the<br />

couou:us aesorbed on a surface woulu determine its wettaoilty<br />

characteristic -<br />

Cole <strong>and</strong> Jessen<br />

studied the effect of wettabilitv on usraffin<br />

<strong>deposition</strong>.<br />

Their ecoerimental apparatus has been discussed in<br />

section 2.3.2.<br />

The wettability characteristic of a coroer nlate was<br />

varied by aurlying different silicone coatings. The contact angles<br />

were measurec. woth water.<br />

The amount of <strong>paraffin</strong> o.esosited for a<br />

given temrerature aiiierential decreasea iith increasing contact<br />

ang.Le. See fig. 2.3.7.. t was found that temperature differential<br />

<strong>and</strong> free surface energy acted inderendently in determining the amount<br />

of <strong>wax</strong> deposited.<br />

Cole <strong>and</strong> Jessen concluded that as <strong>paraffin</strong> <strong>wax</strong> is derosited on<br />

a surface, it is held in place by adsorption forces.<br />

These adsoru<br />

tion forces are dependent upon the free surface energy possessed by<br />

both the raraffin <strong>and</strong> the surface.<br />

..s the free surface energy of<br />

the plate is reduced, a resultant decrease in the adsorption forces<br />

holding the <strong>paraffin</strong> to the plate surface takes place.<br />

This causes<br />

a decrease in the ar.ount of raraffin which can be retair.ed on the<br />

plate surface for the flow conditions rresent.<br />

hunt .C<br />

developed the cold spot tester <strong>and</strong> studied the effect<br />

of roughness or. <strong>paraffin</strong> derosition.<br />

iP nis wenl tucong somu.atior. tests.<br />

used e same solution as<br />

Lie SOLUtiOfl c_ou& poInt was<br />

5900 <strong>and</strong> it was maintained at 4900 in t:te atoaratus roa.-cong It a<br />

<strong>wax</strong>—oI s..nirry. The tests snowea that cieposo;s aoc. not acnere to<br />

a rolosnec. staor._css ste surace, out aonerec. to a sana o_as;aa<br />

s;ainess stee_ sur:ace.<br />

.o oeuosots were :ounc to orm on s::ootn<br />

rastic coatlogs out cierosots were neci :orn.y on r...ace on sanc.—<br />

Paper rougnenea coat:n::s.<br />

nunS concauaeo tnat para::on aemosots<br />

00 OCt acuiere to a meta. sur:ace cut are ne_a on r.ace cy sur:ace

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