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Barley for Food and Health: Science, Technology, and Products

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WHOLE-GRAIN PROCESSING 111<br />

contained high levels of β-glucan <strong>and</strong> an intermediate level of arabinoxylan,<br />

whereas bran exhibited the opposite ratio of β-glucan <strong>and</strong> arabinoxylan, which<br />

is representative of the outer layers of the kernel.<br />

Andersson et al. (2003) presented data on the tocol content of the milling<br />

fractions. The tocol levels in the whole barleys are shown in Table 4.4. Analyses<br />

of the milling fractions showed the highest levels of each of the eight tocol<br />

isomers in bran, intermediate in shorts, <strong>and</strong> least in flour. Tocotrienols (T3) were<br />

significantly higher than tocopherols (T) in each milling fraction. Totals of T3<br />

<strong>and</strong> T (mg/kg) in flour, shorts, <strong>and</strong> bran were 9.6, 6.0; 45.3, 13.1; <strong>and</strong> 55.7, 14.0,<br />

respectively. The ratios of T3 to T in flour, bran, <strong>and</strong> shorts were 1.6 : 1, 3.5 : 1,<br />

<strong>and</strong> 4.0 : 1, respectively.<br />

Other research centers have evaluated the nutritional <strong>and</strong> functional characteristics<br />

of hulless barley. Ames et al. (2006) milled 10 hulless barley genotypes<br />

in a Bühler mill producing straight-grade flour, shorts, <strong>and</strong> bran. Composition of<br />

the straight-grade flour <strong>and</strong> shorts <strong>and</strong> bran fractions exhibited wide genotypic<br />

variation. Seven of the genotypes had straight-grade flours with low levels of<br />

β-glucan (6.5% β-glucan, >18%<br />

dietary fiber, <strong>and</strong> less than 60% starch. The shorts <strong>and</strong> bran fractions of all genotypes<br />

contained higher concentrations of β-glucan <strong>and</strong> total dietary fiber than<br />

those of the straight-grade flour. The shorts <strong>and</strong> bran fractions from the two<br />

genotypes with the high levels of β-glucan <strong>and</strong> dietary fiber were also higher in<br />

these components than in comparable fractions from the other genotypes.<br />

<strong>Barley</strong> β-glucans present major problems to overcome if barley is to be<br />

roller-milled successfully to produce straight-grade flour. Starch type also presents<br />

challenges, as in addition to having different granule sizes, the waxy <strong>and</strong> highamylose<br />

types also contain higher-than-normal levels of β-glucans. Shorts <strong>and</strong><br />

bran fractions offer possibilities of use to enhance the nutritional components<br />

in certain types of baked goods, such as cookies, muffins, cakes, <strong>and</strong> specialty<br />

breads. Major improvements in roller-milling techniques have been made to produce<br />

flour from barley that can be used in a multitude of food products.<br />

Malting<br />

<strong>Barley</strong> has been malted, or germinated, prior to consumption <strong>for</strong> thous<strong>and</strong>s of<br />

years. It has been documented that any barley having a sound, viable kernel will<br />

produce malt, but quality factors would be sacrificed in most cases. Commercial<br />

malt is defined as a modified kernel from which the dried rootlets <strong>and</strong> sprouts<br />

have been separated <strong>and</strong> removed. In modern malting operations, strict criteria<br />

are observed in the selection of barley <strong>for</strong> malting, not the least of which are the<br />

desires <strong>and</strong> wishes of the brewery, distillery, <strong>and</strong>/or the brewmaster. A number<br />

of major considerations paramount in the choice of a barley <strong>for</strong> malting include<br />

genotypes, kernel size, soundness, color, brightness, a germinating capacity of ≥<br />

96%, relatively low protein (≤12.0%), <strong>and</strong> the absence of insect, microbial, heat,<br />

<strong>and</strong> weather damage. Observations on the rate of modification of various barleys

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