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Barley for Food and Health: Science, Technology, and Products

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154 BARLEY FOOD PRODUCT RESEARCH AND DEVELOPMENT<br />

that were the best predictors of the baking quality of wheat–barley admixtures.<br />

Two parameters that showed promise were the content of high-molecular-weight<br />

glutenin subunits of the base wheat <strong>and</strong> the extensibility of the dough measured<br />

by a texture analyzer. This study demonstrated the dynamics of wheat flour <strong>and</strong><br />

barley flour composition <strong>and</strong> interaction in breadmaking.<br />

The effects of substitution of cooked barley flours <strong>for</strong> part of the wheat flour<br />

in yeast bread were reported by Gill et al. (2002) in Canada. These cereal scientists<br />

used two hulless barleys, CDC C<strong>and</strong>le (waxy starch <strong>and</strong> high β-glucan)<br />

<strong>and</strong> Phoenix (normal starch <strong>and</strong> β-glucan). These were first pearled <strong>and</strong> then<br />

pin-milled into flour. The flours were stirred in water to <strong>for</strong>m a slurry be<strong>for</strong>e<br />

cooking in a steam-jacketed kettle at 100 ◦ C <strong>for</strong> 25 minutes. The cooked <strong>and</strong> gelatinized<br />

slurry was then oven dried, reground, <strong>and</strong> sieved. Dextrose equivalents<br />

of flours were determined, to measure the reducing capacity, which influences<br />

the browning of bread crust. Cooked barley flours had higher dextrose equivalents<br />

than any of the native (raw) barley flours. Mono-, di-, <strong>and</strong> oligosaccharide<br />

composition of flours <strong>and</strong> content of these sugars was highest in cooked C<strong>and</strong>le,<br />

possibly due to breakdown of its β-glucan <strong>and</strong> starch. The cooked barley flours<br />

<strong>and</strong> their original native barley flours were made into breads, replacing wheat<br />

flour at the 5, 10, <strong>and</strong> 15% levels. All breads made with barley predictably had<br />

lower loaf volume than that of the all-wheat control. The native barley flours had<br />

decreased loaf volume with increasing barley substitution level, <strong>and</strong> at the 15%<br />

level, C<strong>and</strong>le had the lowest volume, probably due to its higher β-glucan level.<br />

The cooked flour breads at all levels of substitution had lower loaf volume than<br />

those made with native flour, except <strong>for</strong> C<strong>and</strong>le at the 15% level. The cooking<br />

of C<strong>and</strong>le flour appeared to improve its bread quality <strong>and</strong> suggests the potential<br />

of inclusion higher than the 15% level. In other evaluations of these breads,<br />

firmness increased with barley proportion increases, except <strong>for</strong> the 15% cooked<br />

C<strong>and</strong>le bread, which had firmness comparable to that of the control wheat bread.<br />

Cooked C<strong>and</strong>le flour produced dough with a soft consistency that increased at<br />

higher substitution levels. Waxy starches tend to swell <strong>and</strong> bind more water<br />

than regular starch; there<strong>for</strong>e, during baking, native C<strong>and</strong>le would probably gelatinize<br />

<strong>and</strong> bind excess water, suppressing steam generation. However, the starch<br />

in cooked C<strong>and</strong>le flour was already gelatinized, <strong>and</strong> the lack of amylose contributed<br />

to lower crumb strength, lower volume, <strong>and</strong> increased firmness. Scanning<br />

electron microscopy indicated that cooked Phoenix flour had more large starch<br />

particles than C<strong>and</strong>le. Because of C<strong>and</strong>le’s high amylopectin content, particle<br />

agglomeration was minimal. The smaller particles with increased surface area<br />

may have improved starch–protein interactions <strong>and</strong> contributed to loaf volume<br />

<strong>and</strong> texture. Gaosong <strong>and</strong> Vasanthan (2000) had previously reported that C<strong>and</strong>le<br />

β-glucan undergoes molecular fragmentation when subjected to heat <strong>and</strong> shear,<br />

which could reduce viscosity <strong>and</strong> water-holding capacity. In the present study,<br />

the authors also considered the effects of starch character on firmness progression<br />

over time during storage, which is a factor of staling. The resulting breads of this<br />

study were analyzed <strong>for</strong> total (TDF), insoluble (IDF), <strong>and</strong> soluble (SDF) dietary<br />

fiber. One slice of 15% substituted C<strong>and</strong>le bread (28 g) contained 2.2 g of TDF,

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