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Barley for Food and Health: Science, Technology, and Products

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SECONDARY PROCESSING 117<br />

malt. These levels are 16 to 18% higher than reported in comparable barley <strong>and</strong><br />

barley malt, respectively where the starch lipids are not included. Shifts in chemical<br />

structure occur in surface <strong>and</strong> internal lipids associated with starch granules<br />

during malting, which suggests that such lipid changes may be responsible <strong>for</strong><br />

oxidation <strong>and</strong> the <strong>for</strong>mation of off-flavors in some malts.<br />

SECONDARY PROCESSING<br />

Extrusion<br />

Extrusion is a technology used <strong>for</strong> conversion of basic dense grain <strong>for</strong>mulations<br />

into light, puffed, <strong>and</strong> crisp products that are cooked (RTE) or partially cooked.<br />

It is a process using high-temperature short-term cooking applicable to producing<br />

RTE breakfast cereal <strong>and</strong> snack foods <strong>and</strong> <strong>for</strong> direct expansion <strong>and</strong> <strong>for</strong>ming of<br />

solid shapes. The basic components <strong>and</strong> operation of extruders are screw(s) rotating<br />

in a barrel propelling food material <strong>for</strong>ward through a die or restrictive orifice,<br />

generating heat <strong>and</strong> pressure in the process. The action of these components on<br />

the substance being extruded is influenced directly by the operating pressure in<br />

the system. Miller (1990) provided a geometric <strong>and</strong> physical explanation of the<br />

principles of die flow. Raw ingredients are first moved into a cooking chamber,<br />

where they are compressed <strong>and</strong> shredded at elevated temperatures to undergo<br />

a melt transition <strong>and</strong> <strong>for</strong>m a viscous fluid. The extruder develops the fluid by<br />

shearing the biopolymers, particularly starch. Shear is a term referring to the<br />

resistance of molecules as they move around a mixture, due to the presence of<br />

intermolecular <strong>for</strong>ces. Starch has a high water-binding capacity during cooking,<br />

which causes viscosity development. The die pressure <strong>and</strong> increased temperature<br />

cause reorganization of the food molecular structure. The fluid is then <strong>for</strong>ced<br />

through dies to <strong>for</strong>m a variety of shapes with low density (Guy 1991).<br />

Extruders may consist of single or twin screws with spirally arranged flights<br />

<strong>for</strong> conveying material through a barrel or tube with a capacity <strong>for</strong> developing<br />

pressure. Heat is produced by steam injection as well as the mechanical energy<br />

developed by the pressure applied. Single-screw extruders were first used to produce<br />

RTE breakfast cereals in the 1960s. Problems were related to movement<br />

through the barrel <strong>and</strong> excessive shear, affecting color <strong>and</strong> appearance of finished<br />

products as well as overgelatinization. Twin-screw extruders have greater<br />

efficiency <strong>and</strong> produce increased solubility of the material being extruded, which<br />

allows <strong>for</strong> greater control (Kent <strong>and</strong> Evers 1994). Fast (2001) described innovations<br />

in twin-screw extruders <strong>and</strong> the advantages in control of the various steps<br />

in the extrusion process, including advantages in die design <strong>and</strong> cutting mechanisms.<br />

Extrusion is a rapidly exp<strong>and</strong>ing technology <strong>for</strong> processing cereals into<br />

RTE breakfast cereals, snack foods, <strong>and</strong> similar products. New developments<br />

include improved designs in all phases of the equipment that allow <strong>for</strong> multiple<br />

use <strong>and</strong> greater control of shear, compression, <strong>and</strong> pressure at the die. The promotion<br />

of whole grains in modern dietary recommendations <strong>and</strong> subsequent health<br />

claim labeling <strong>for</strong> whole grains (FDA 1999) has resulted in new extruded products

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