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enlargement. In another test, metal fuel operated for 223 days after the cladding<br />

breach, including many start-up and shut-down transients. The breach site remained<br />

small. It was concluded that although metal fuel is very reliable, if a fuel failure<br />

does occur the failed fuel pins can be left in the core until their normal end of life<br />

without raising any particular operational or safety concerns. This is true of no other<br />

fuel, in fast reactors or in LWRs.<br />

The eutectic formation (melting) temperature between the fuel and the cladding<br />

is a critical parameter for metal fuel. The onset of fuel/cladding eutectic formation<br />

starts at 700-725 o C range, depending on the fuel alloy and cladding types. At onset,<br />

however, not much occurs. In fact, even at a hundred degrees above the eutectic<br />

temperature the eutectic penetration into the cladding is minimal in one hour. Only<br />

at much higher temperatures, approaching the melting point of the fuel material<br />

itself on the absence of cladding, does the eutectic penetration into cladding become<br />

rapid. Eutectic formation therefore, is not a primary safety concern even during<br />

transient overpower conditions.<br />

It does have a practical effect. Reactor designers tend to place limits on the<br />

coolant outlet temperature to assure the eutectic temperature is not reached at the<br />

fuel/cladding interface. A coolant outlet temperature limit of 500-510 o C is very<br />

conservative, and up to 550 o C provides ample margins to the onset of eutectic<br />

formation. The conservative design approach will probably be relaxed with more<br />

experience.<br />

6.9 Minor Actinide Containing Fuel<br />

Equilibrium recycled IFR fuel will contain transuranic elements near to<br />

plutonium in atomic weight, so the U-Pu-Zr fuel test matrix included fuels<br />

containing these minor actinides. The typical composition of the actinides in LWR<br />

spent fuel is about 90% plutonium and 5% each for neptunium and americium. IFR<br />

ternary fuel, U-20Pu-10Zr, will contain about 1% Np and 1% Am. For an upper<br />

bound case, a 1.3% Np and 2% Am addition was selected for the irradiation tests.<br />

Americium has high volatility and fuel fabrication at elevated temperatures with<br />

Americium will be a challenge for any fuel material. For the IFR metal fuel, the<br />

standard injection casting technique was altered slightly to have the feedstock of<br />

80Pu-20Am inserted into the molten fuel late in the melt cycle to minimize the time<br />

at temperature. When the Pu-Am stock was added, ―sparks‖ were observed. The<br />

sparks were probably induced by boiling of contaminants in the Pu-Am feedstock,<br />

which contained about 3% calcium and 2000 ppm magnesium. Both of these<br />

elements boil below the casting temperature. The resulting agitation of the molten<br />

pool probably contributed to the higher-than-expected evaporation of americium.<br />

Three slugs were cast, and about 40% of americium was evaporated in the casting.<br />

132

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