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Investigating carotenoid loss after drying and storage of

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148<br />

6. Effect <strong>of</strong> pre-treatment<br />

with our results, no difference in β-carotene content between sulphurated (by burning<br />

element sulphur in an enclosed place) <strong>and</strong> un-treated (non-sulphurated) apricots <strong>after</strong><br />

<strong>drying</strong> in hot air or in sun was shown by Karabulut et al. (2007). After <strong>drying</strong>, however,<br />

samples treated with sodium metabisulphite or ascorbic acid had better content than<br />

samples soaked in deionised water (Table 6-5). Working on pineapple <strong>and</strong> papaya, Siahn<br />

<strong>and</strong> Ishak (1990) also reported an improvement <strong>of</strong> total <strong>carotenoid</strong> content using sodium<br />

metabisulphite (0.2%; 0.4%; 0.6%) <strong>after</strong> <strong>drying</strong> with deionised water as a control.<br />

However, in another study by Yen et al. (2008) working on pre-treatment with a solution<br />

<strong>of</strong> ascorbic acid (0.1%) + glucose (1%) showed that diced carrots treated with this<br />

solution <strong>and</strong> then hot air or freeze dried had significantly better β-carotene content than<br />

un-soaked ones, <strong>and</strong> disagrees with our results. These divergences in results <strong>after</strong> <strong>drying</strong><br />

between authors could be the result <strong>of</strong> the differences in food products composition, type<br />

<strong>of</strong> chemical added <strong>and</strong> incorporation <strong>of</strong> the chemical in the food matrix.<br />

After a typical <strong>storage</strong> period for dried sweet potato (4-6 months), there was no<br />

significant effect <strong>of</strong> sodium metabisulphite (0.5%) as compared with un-treated or<br />

deionised water-dipped samples (Table 6-6). Working with diced orange-fleshed sweet<br />

potato pre-treated with 0.2% sodium bisulfite for 5 minutes at room temperature, Cinar<br />

(2005) also did not show improvement in half life <strong>of</strong> metabisulphite-treated samples<br />

<strong>after</strong> 120 days at 4ºC or 25ºC. Losses <strong>of</strong> β-carotene from dried carrots <strong>after</strong> 12 months at<br />

room temperature (22-26ºC) with deionised water as control; 0.05% <strong>and</strong> 0.2% sulphite<br />

treated were 60%; 56% <strong>and</strong> 59% respectively (Zhao <strong>and</strong> Chang 1995). This was in<br />

accordance with our results that showed that there were few differences between<br />

untreated <strong>and</strong> sodium metabisulphite treated samples <strong>after</strong> six months. In contrast,<br />

Baloch et al. (1987) showed that soaking carrots in sodium metabisulphite before<br />

dehydration had significant effect on <strong>carotenoid</strong> retention <strong>after</strong> <strong>drying</strong> <strong>and</strong> <strong>after</strong> <strong>storage</strong><br />

at 37ºC for 440 days (14 months). Carotenoid retention was further improved when in<br />

addition to sulphiting carrots were also blanched. The differences <strong>of</strong> results with sodium<br />

metabisulphite might be explained by the incorporation <strong>of</strong> sulphite into the product<br />

which may further influence the degradation <strong>of</strong> sulphite in <strong>storage</strong> (Baloch et al. 1987).<br />

Zhao <strong>and</strong> Chang (1995) described a sharp decrease in residual sulphite content in<br />

sulphite-treated carrots over <strong>storage</strong> (92% <strong>loss</strong> in 12 month). Sulphite may be lost by<br />

reaction with disulfide groups or thiols in proteins <strong>and</strong> low molecular weight

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