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Investigating carotenoid loss after drying and storage of

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24<br />

1. Literature review<br />

A activity (Rodriguez-Amaya 1997; Tanumihardjo 2002). β-carotene is the <strong>carotenoid</strong><br />

with the highest provitamin A activity (100%) because the β-carotene molecule can be<br />

entirely converted into two molecules <strong>of</strong> vitamin A or retinol (Figure 1-11; Table 1-3).<br />

Figure 1-11: Structures <strong>of</strong> the most common provitamin A <strong>carotenoid</strong>s <strong>and</strong> retinol.<br />

National Academy <strong>of</strong> Sciences/Institute <strong>of</strong> Medicine (2001).<br />

Table 1-3: Relatives bioactivities (%) <strong>of</strong> some provitamins A compounds in<br />

comparison with trans-β-carotene as reported by Bauernfeind (1972); Zechmeister<br />

(1949) <strong>and</strong> summarised by Rodriguez-Amaya (1997).<br />

Provitamin A Bauernfeind (1972) Zechmeister (1949)<br />

trans-β-carotene 100 100<br />

13-cis-β-carotene - 53<br />

9-cis-β-carotene - 38<br />

trans-#-carotene 50-54 53<br />

cis-#-carotene (13-cis?) - 16<br />

cis-#-carotene (9-cis?) - 13<br />

trans-5-6-monoepoxy-β-carotene 21 -<br />

trans-γ-carotene 42-50 42<br />

cis-γ-carotene - 19<br />

trans-β-cryptoxanthin 50-60 57<br />

cis-β-cryptoxanthin (9-cis?) - 27<br />

cis-β-cryptoxanthin (15-cis?) - 42<br />

trans-β-apo-8-carotenal 72 -<br />

trans-β-zeacarotene 20-40 -<br />

trans-mutachrome 50 -<br />

About 50 <strong>carotenoid</strong>s are known to have a provitamin A activity (Lee et al. 1989). Of<br />

these compounds, provitamin A carotenes most commonly encountered include β-

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