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Investigating carotenoid loss after drying and storage of

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Arrhenius model:<br />

=<br />

∞<br />

−<br />

Ea<br />

RT<br />

ek<br />

k : degradation constant rate (day -1 )<br />

k∞ : value <strong>of</strong> k at T = " (day -1 )<br />

T : temperature (K)<br />

Ea : Activation energy (kJ.mol -1 )<br />

R : Molar gas constant = 8.314 J · K−1 · mol −1<br />

ln K (day-1)<br />

-3.00<br />

-3.50<br />

-4.00<br />

-4.50<br />

-5.00<br />

-5.50<br />

-6.00<br />

-6.50<br />

40ºC<br />

y = -7995.9x + 22.391<br />

R 2 = 0.9905<br />

30ºC<br />

240<br />

y = -8354.4x + 23.57<br />

R 2 = 0.9733<br />

Jar 1 Jar 2 Jar 3<br />

20ºC<br />

Appendix 1<br />

y = -8284.2x + 23.34<br />

10ºC<br />

R 2 = 0.9889<br />

0.0032 0.0032 0.0033 0.0033 0.0034 0.0034 0.0035 0.0035 0.0036<br />

1/T (K)<br />

Figure 2: Arrhenius model for temperature between 10-40ºC on a dry weight<br />

basis (mean <strong>of</strong> triplicate (jar); error bars refer to st<strong>and</strong>ard deviation). Oxygen level<br />

21% (air); aw 0.52-0.65.<br />

abk<br />

T<br />

1<br />

ln = − where b <strong>and</strong> a are constant <strong>of</strong> linear equation. b= ln k∞.<br />

Ea<br />

Ea was calculated from the linear equation following the formula: a =<br />

R<br />

In average over the three replicates (jars): Ea = 68.3kJ.mol -1 ; k∞ =1.21.10 10 day -1 .

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