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Investigating carotenoid loss after drying and storage of

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182<br />

8. Study under controlled conditions<br />

lost some precision, but this corresponded to a moisture content <strong>of</strong> 20.8% on a dry<br />

weight basis, which is outside the usual range <strong>of</strong> <strong>storage</strong> conditions. Sweet potato <strong>of</strong><br />

variety Ejumula stored in Ug<strong>and</strong>a under ambient conditions for four months had<br />

maximum moisture content <strong>of</strong> 13.6% on a dry weight basis (12% on a wet weight basis)<br />

(see Chapter 4).<br />

Moisture (M) g water/g dry weight basis<br />

30%<br />

25%<br />

20%<br />

15%<br />

10%<br />

5%<br />

0%<br />

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9<br />

aw<br />

Figure 8-9: Water sorption curves <strong>of</strong> dried sweet potato chips at 40ºC <strong>and</strong> stored<br />

for 54 days. Experimental data <strong>and</strong> BET model (C = -68.88, M0 = 0.0564).<br />

Under different water activities, trans-β-carotene degradation fitted a first order kinetic<br />

model as shown in Table 8-7.<br />

Table 8-7: First order rates <strong>of</strong> <strong>carotenoid</strong> degradation (k) expressed in day -1 at<br />

various water activities at 40ºC in dried sweet potato chips on a dry weight basis.<br />

Mean <strong>of</strong> triplicate thermal treatments (st<strong>and</strong>ard deviation). Oxygen level 21%<br />

(air).<br />

Saturation salt NaCl NaBr MgCl2 LiCl<br />

Water activity 0.76 0.51 0.30 0.13<br />

Trans-!- k 0.0332 (0.0009) 0.0413 (0.0004) 0.0462 (0.0033) 0.0496 (0.0032)<br />

carotene* R 2 0.991 (0.001) 0.976 (0.001) 0.970 (0.004) 0.945 (0.048)<br />

Under isothermic conditions (40ºC) <strong>and</strong> in samples stored under air, the lower the water<br />

activity the faster the !-carotene was degraded (Figure 8-10).

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