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Investigating carotenoid loss after drying and storage of

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242<br />

Appendix 1<br />

B/Calculation <strong>of</strong> Arrhenius model robustness using experimental<br />

points – under variable temperature (anisothermal) conditions in the<br />

dark<br />

Solving <strong>of</strong> the Arrhenius equation for a first order kinetics <strong>of</strong> degradation<br />

dC<br />

= −kC<br />

(First order equation) (1)<br />

dt<br />

−Ea<br />

RT<br />

= ek (Arrhenius equation) (2)<br />

C<br />

∞<br />

−Ea<br />

dC RT<br />

∞<br />

C<br />

C0<br />

dC<br />

C<br />

−Ea<br />

dC RT<br />

= −k<br />

e dt (concentrations <strong>and</strong> times are put separately)<br />

= −k<br />

t<br />

−Ea<br />

RT<br />

!!<br />

e dt (integration)<br />

∞<br />

0<br />

t<br />

−Ea<br />

= − ∞ Cek<br />

(1) + (2)<br />

dt<br />

C<br />

RT<br />

ln = −k<br />

∞ e dt<br />

C ! (integrate <strong>of</strong> derivate is equal to logarithm <strong>of</strong> concentration)<br />

C<br />

C<br />

0<br />

0<br />

=<br />

= e<br />

0<br />

k e<br />

t<br />

− Ea<br />

RT<br />

∞ !<br />

0<br />

−<br />

0<br />

dt<br />

k e<br />

t<br />

− Ea<br />

RT<br />

∞<br />

0<br />

−<br />

eC !<br />

(exponential)<br />

dt

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