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265 IRREVERSIBILITY-THE ENTROPY BARRIER<br />

that at the end of the nineteenth century Bruns and Poincare<br />

demonstrated that most dynamic systems, starting with the<br />

famous "three body" problem, were not integrable.<br />

On the other hand, the very idea of approaching equilibrium<br />

in terms of the theory of ensembles requires that we go beyond<br />

the idealization of integrable systems. As we saw in Chapter<br />

VII I, according to the theory of ensembles, an isolated system<br />

is in equilibrium when it is represented by a "microcanonical<br />

ensemble," when all points on the surface of given energy<br />

have the same probability. This means that for a system to<br />

evolve to equilibrium, energy must be the only quantity conserved<br />

during its evolution. It must be the only "invariant."<br />

Whatever the initial conditions, the evolution of the system<br />

must allow it to reach all points on the surface of given energy.<br />

But for an integrable system, energy is far from being the only<br />

invariant. In fact, there are as many invariants as degrees of<br />

freedom, since each generalized momentum remains constant.<br />

Therefore we have to expect that such a system is "imprisoned"<br />

in a very small "fraction" of the constant-energy (see<br />

Figure 32) surface formed by the intersection of all these invar­<br />

-iant surfaces.<br />

p<br />

Figure 32. Temporal evolution of a cell in phase space p, q. The "volume"<br />

of the cell and its form are maintained in time; moreover, most of the phase<br />

space is inaccessible to the system.<br />

q

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