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131 LA UR 03 5862 - National Nuclear Security Administration ...

131 LA UR 03 5862 - National Nuclear Security Administration ...

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captured in the Laboratory’s annual groundwater status report. The most recent status report covers FY 2002(Nylander et al. 20<strong>03</strong>).Highlights of the regional aquifer water chemistry from these characterization wells are as follows:• Natural groundwater ranges from calcium-sodium bicarbonate composition (Sierra de los Valles) tosodium-calcium bicarbonate composition (White Rock Canyon springs) (Longmire 2002a, b; Blake et al.1995; <strong>LA</strong>NL 2001). Silica is the second most abundant solute found in surface water and groundwaterbecause of reactions between soluble silica glass in the rock and water. Trace metals, including barium,strontium, and uranium, vary within the different saturated zones (alluvial, intermediate, and regional aquifer)depending on how long the water has been in contact with the host rock (Nylander et al., 20<strong>03</strong>). Oldergroundwater within the regional aquifer tends to have higher concentrations of trace elements.• Dissolved organic carbon, in the form of humic and fulvic acids, is present in groundwater inconcentrations typically less than 3 milligrams carbon per liter. These acids occur as anions and cancomplex with calcium and magnesium. Higher concentrations of dissolved organic carbon occur in alluvialgroundwater where runoff through grasslands and forests takes place. Shortly after the Cerro Grande Fire,increased concentrations of total organic carbon were observed in surface water and alluvial groundwaterwithin Pueblo Canyon, Los Alamos Canyon, Pajarito Canyon, and other watersheds. Since 2002,concentrations of total organic carbon have decreased in surface water, but remain elevated in alluvial andperched-intermediate groundwater. Total organic carbon provides an excellent tracer for tracking movementof recent water (post Cerro Grande Fire) in the subsurface.• Groundwater impacted by <strong>LA</strong>NL-derived effluent is characterized by elevated concentrations of majorions (calcium, magnesium, potassium, sodium, chloride, bicarbonate, nitrate, and sulfate); trace solutes (forexample, molybdenum, perchlorate, barium, boron, and uranium); high explosive compounds and othervolatile organic compounds; and radionuclides (tritium, americium-241, cesium-137, plutonium isotopes,strontium-90, and uranium isotopes) (Longmire 2002a, b, c, d; <strong>LA</strong>NL 2001c).• With regard to interconnection between alluvial groundwater, intermediate saturated zones, andthe regional aquifer, contaminant source terms correlate reasonably well with chemical data for mobilesolutes collected at down gradient characterization wells (Longmire 2002a, <strong>LA</strong>NL 2001c). Non-adsorbingcontaminants (perchlorate, nitrate, RDX, and TNT) are the most mobile and travel the greatest distancesalong groundwater-flow paths.Concentrations of some of thesechemicals in groundwater havebeen observed above establishedmaximum contaminant levels andrecommended health and actionlevels in wells (<strong>LA</strong>NL 2001c,Broxton et al. 2002):• MCOBT-4.4:intermediate saturatedzone, nitrate, perchlorate• R-25: intermediatesaturated zone, highexplosives (RDX)• Alluvial wells: alluvialaquifer, actinides,metals, and fissionproducts (Los AlamosCanyon, Pueblo Canyon,and Mortandad Canyon)Drilling auger and crew3-30SWEIS Yearbook—2002

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