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Ecological Evaluation Technical Guidance - State of New Jersey

Ecological Evaluation Technical Guidance - State of New Jersey

Ecological Evaluation Technical Guidance - State of New Jersey

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Toxicity Equivalence Concentration (TEC). The sum <strong>of</strong> all the TECs is referred to as thetotal, or ∑, TEQ. See Figure I-1: “Example Determination <strong>of</strong> 2,3,7,8-TCDD Equivalents(TEQs).”Contaminant Concentration Avian TEF TEC(ppt)Chlorinated dibenzo-p-dioxins2,3,7,8-TCDD 13.5 1 13.51,2,3,6,7,8-HxCDD 7.9 0.01 0.079PCDD TEQ = ∑ PCDD TECs = 13.5 + 0.079 = 13.58Chlorinated dibenz<strong>of</strong>urans2,3,4,7,8-PeCDF 16.2 1 16.21,2,3,4,7,8-HxCDF 0.5 0.1 .05OCDF 21.7 0.0001 0.00217PCDF TEQ = ∑PCDF TECs = 16.2 + 0.05 + 0.00217 = 16.25Non-ortho-substituted PCBs3,3’4,4’,5-pentaCB (PCB 126) 682 0.1 68.23,3’4,4’,5,5’-hexaCB (PCB 169) 524 0.001 0.524PCB TEQ = ∑ PCB TECs = 68.2 + 0.524 = 68.72∑ TEQ = ∑ PCDD TEQ + ∑PCDF TEQ+ ∑ PCB TEQ = 13.58 + 16.25 + 68.73 = 98.56Figure I-1. Example Determination <strong>of</strong> 2,3,7,8-TCDD Equivalents (TEQs)Two approaches can be used for the handling <strong>of</strong> nondetect data: assume nondetects aszero or nondetects as 1/2 the reported detection limit. For situations in which the primarycontaminant is 2,3,7,8-TCDD and good detection limits are achieved for all congeners(generally less than 10 ppt), using either procedure usually results in similar outcomes forthe calculated sample-specific TEQ. However, if elevated detection limits are reportedfor many <strong>of</strong> the congeners, it is recommended that non-detects are factored in at 1/2 thereported detection limit (adjusted based on TEF) given the uncertainty because <strong>of</strong> theelevated detection limit.TEQ <strong>Evaluation</strong>The individual 2,3,7,8-TCDD concentration, each <strong>of</strong> the three class-specific TEQs, andthe ∑ (total) TEQ are compared with ecological screening criterion for 2,3,7,8-TCDD asper Section 5.4. The resultant HQs are carried through the EE process.<strong>Ecological</strong> <strong>Evaluation</strong> <strong>Technical</strong> <strong>Guidance</strong> Document 127Version 1.2 8/29/12

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