2001) and the FSPM (NJDEP, 2005) for guidance on statistically determining theappropriate number <strong>of</strong> samples.5.3.1 When to Collect SamplesWhen contaminants are found in on-site media in excess <strong>of</strong> the ESC and ESNRsare on, adjacent to or potentially impacted by the site, as defined at N.J.A.C.7:26E-1.8, environmental samples are to be collected in the potential migrationpathways and in the ESNRs, as appropriate. N.J.A.C. 7:26E-1.8 definescontaminated sites as all portions <strong>of</strong> environmental media at a site and anylocation where contamination is emanating, or which has emanated, therefrom,that contain one or more contaminants at a concentration which fails to satisfy anyapplicable remediation standard. If the investigator can provide documentationthat site-related contamination in surface water, sediment, wetlands, or soil inESNRs is unlikely, based on site-specific conditions, site history, etc., thenadditional sampling <strong>of</strong> ESNR or contaminant migration pathways may not berequired, refer to Figure 3-1.Samples should be collected in ESNRs and contaminant migration pathwaysunder any <strong>of</strong> the following conditions:(1) if known historical discharges have occurred or on-going dischargesare occurring, as determined pursuant to Section 5.2.3;(2) if there is a presence <strong>of</strong> stressed vegetation, sheens, seeps, discoloredsoil or sediment along the shoreline or on the surface water body orwetland;(3) if there is evidence <strong>of</strong> stream impacts from historical dischargesincluding historical ecological studies documenting differences inorganism population density and diversity in areas potentiallyimpacted by the site relative to areas not impacted by the site; or(4) if there is a groundwater discharge to surface water or a wetland, withcontaminants originating on site above the applicable SWQS or ESC.Sampling must be designed to account for seasonal or short-term flow and waterquality fluctuations caused by dry- versus wet-weather flow, system hydraulics(obtaining flow-proportioned samples where applicable), and potentialcontaminant characteristics (e.g., density and solubility) (N.J.A.C. 7:26E-3.6(b)).In addition to other required analyses, sediments must also be analyzed for totalorganic carbon (TOC), pH, and particle size (N.J.A.C. 7:26E-3.6(b)). These dataare required to develop appropriate remediation standards. Depending on the type<strong>of</strong> contaminant, type <strong>of</strong> discharge (e.g., surficial and subsurface), and mediapotentially impacted, the sampling methods and depth will vary as indicatedbelow.5.3.2 Where to Collect SamplesThe following sections provide general and media-specific guidance for theselection <strong>of</strong> sampling locations.<strong>Ecological</strong> <strong>Evaluation</strong> <strong>Technical</strong> <strong>Guidance</strong> Document 21Version 1.2 8/29/12
5.3.2.1 Potential Contaminant Migration PathwaysI. Ditches and SwalesDitches and swales that do not contain standing or flowing water should besampled as indicated in Section 5.3.2.2 II or III. Ditches and swales thatcontain standing water should be sampled as indicated in Section 5.3.2.2 I. A.Ditches and swales that contain flowing water should be sampled as indicatedin Section 5.3.2.2 I. B.II. Overland FlowWhen the potential migration pathway consists <strong>of</strong> general overland flow withno discernable ditches or swales, samples should be collected as indicated inSection 5.3.2.2 III.III. GroundwaterWhen the potential migration pathway consists <strong>of</strong> groundwater, samplesshould be collected in accordance with N.J.A.C. 7:26E-3.5, Site investigationgroundwater,and the relevant technical guidance. Samples from the mostdowngradient monitoring wells or piezometers, or samples in the closestproximity to ESNRs will be considered indicative <strong>of</strong> the migration pathway.5.3.2.2 Environmentally Sensitive Natural ResourcesI. Aquatic SystemsIn aquatic systems, the areas <strong>of</strong> greatest contamination will generally occur indepositional areas, thus these should be specifically targeted by the samplingplan. Such depositional areas are generally characterized by slow-movingwater where fine sediments tend to accumulate (e.g., pool areas, river bends).Sediment samples collected for chemical analysis, toxicity testing, and benthiccommunity surveys should be spatially and temporally collocated. Sedimentsamples should be collected in a manner to avoid the loss <strong>of</strong> fine-grainedsediments. Surface water and sediment samples should be spatially andtemporally collocated. Surface water samples should be collected beforesediment samples to avoid suspended sediments in surface-water samples.Samples should be collected in downstream areas first, and then successivelyat upstream sampling locations.A. Standing water areas (e.g., ponds, lakes, wetlands, surface impoundments,lagoons, storm water detention ponds, fire ponds, and excavations, naturaldepressions and diked areas that can accumulate water) should be sampledas follows:1. Collect a minimum <strong>of</strong> three surface water samples and three sedimentsamples in each area where there is evidence <strong>of</strong> a historical or ongoingdischarge, including but not limited to, stressed vegetation, sheens,seeps, discolored soil or sediment along the shoreline or in a wetland, orother evidence <strong>of</strong> a discharge;<strong>Ecological</strong> <strong>Evaluation</strong> <strong>Technical</strong> <strong>Guidance</strong> Document 22Version 1.2 8/29/12
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N.J.A.C. 7:26E-4.8(c)1. The ERA may
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sediment (i.e., that fraction that
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Twelve dioxin-like PCB congeners ha
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indicates burial of potential dioxi
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of evidence for evaluating risk unt
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7.2.1 Apparent Effects Threshold Ap
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when site conditions are most simil
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destroying 10 acres of the mature f
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ASTM (American Society for Testing
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Establishing Sediment Quality Crite
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N.J.A.C. (New Jersey Administrative
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USEPA. 1989c. Risk Assessment Guida
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http://www.epa.gov/owow/oceans/regu
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USEPA 2006a. Data Quality Assessmen
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Appendix A - Habitat Survey FormsEc
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Ecological Evaluation Technical Gui
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Appendix B - Sampling Procedures fo
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Appendix C - Surface Water Toxicity
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Short-term chronic studies, endpoin
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Appendix D - Sediment Toxicity Test
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Toxicity Test DesignSediment toxici
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Appendix E - Sediment Pore Water an
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The seven-day daphnid survival and
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Surber or Square-foot BottomThis sa
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Appendix H - Soil Toxicity TestingS
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another sample may still have a sub
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Data PresentationTabular presentati