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208 - Impacts of alkaline stabilized biosolids application on<br />

emerging substances of concern (ESOC) in groundwater<br />

Carolina Klabunde & Jana Levison<br />

University of Guelph, Guelph, Ontario, Canada<br />

Gordon W. Price & Rob Jamieson<br />

Dalhousie University, Truro, Nova Scotia, Canada<br />

Anthony Tong & John Murimboh<br />

Acadia University, Wolfville, Nova Scotia, Canada<br />

Mehdi Sharifi<br />

Trent University, Peterborough, Ontario, Canada<br />

Shiv Prasher<br />

McGill University, Montréal, Québec, Canada<br />

Cathryn Ryan<br />

University of Calgary, Calgary, Alberta, Canada<br />

Beth Parker<br />

University of Guelph, Guelph, Ontario, Canada<br />

This multidisciplinary study, part of a broader investigation about the environmental fate<br />

of biosolids application to agricultural fields, aims to better understand the transport of<br />

ESOC to a shallow sedimentary fractured bedrock aquifer. Application of biosolids on<br />

agricultural land is a growing practice and disposal alternative, and can replace the use of<br />

chemical fertilizers. The biosolids applied for this study are produced using an advanced<br />

alkaline stabilization process. There is a desire to understand potential environmental implications<br />

from the application of these soil amendments to ensure that they can be applied<br />

without negative impacts on the underlying aquifer. The relationship between biosolid<br />

application rates and resulting concentrations of ESOC in aquifers requires further investigation.<br />

The research objectives are to identify potential impacts of biosolids application<br />

on groundwater quality in a shallow bedrock aquifer, looking at both temporal and spatial<br />

variability, and to determine whether tile drainage systems affect the leaching of ESOC<br />

to the aquifer. The research site is located at the Bio Environmental Engineering Centre<br />

(BEEC) in Bible Hill, Nova Scotia. Local soils are usually acidic, allowing the utilization<br />

of the amendments applied in this study. Previously, the field had received yearly applications<br />

of manure and herbicides for 11 years, meeting needs of the alternating barley,<br />

soybean and spring wheat crops. The saturated zone is a red sandstone bedrock aquifer<br />

(Wolfville formation). The field site is instrumented with a modern and efficient high<br />

resolution design, using a newly installed CMT multilevel system (25 m deep), tile drain<br />

sampling and 5 shallow piezometers (1 m to 5 m deep). Two loads of 14Mg/ha each of<br />

biosolids were incorporated into the soil (November 2014 and May 2015) in a field which<br />

has not previously received biosolids. The monitoring approach facilitates obtaining distinct<br />

insights on water quality and contaminant behaviour, capturing a detailed picture<br />

of contaminant leaching into the subsurface. In addition, a bromide tracer experiment is<br />

used to further characterize the groundwater flow and travel times from the surface to the<br />

aquifer. A site conceptual model is developed to characterize the surface-to-aquifer transport<br />

of relevant ESOC tailored to the local overburden and sedimentary bedrock aquifer<br />

IAH-CNC 2015 WATERLOO CONFERENCE<br />

145

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