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with a fibre optic cable. A new cable coupling technique using a flexible borehole liner was<br />

tested and was shown to be highly effective for enhancing the seismic signal recorded with<br />

the DAS. A comparison between two different cable structures, tight buffer and loose tube,<br />

were also examined and it was determined that the different structures can strongly influence<br />

the amplitude of the seismic signal. With good cable coupling, the DAS can provide<br />

high-resolution VSPs to provide information on the bedrock aquifer matrix and optimal<br />

cable structures can help maximize the signal to noise ratio of the profile.<br />

297 - Depth-discrete contaminant mass composition and<br />

concentration distribution emanating from an aged DNAPL source<br />

zone in sedimentary rock<br />

A. Buckley, J.R. Meyer, & B.L. Parker<br />

G360 Centre for Applied Groundwater Research, School of Engineering, University of<br />

Guelph, Guelph, Ontario, Canada<br />

Prior to 1970 an estimated 72,700 L of dense non-aqueous phase liquids (DNAPLs)<br />

were released into the subsurface at a site in south central Wisconsin. Investigations at<br />

the site found that the DNAPL accumulated about 56 m bgs in a fractured sandstone<br />

unit. Groundwater flow through the DNAPL source zone over three decades resulted in<br />

a dissolved phase mixed organic contaminant plume extending about 3 km downgradient.<br />

Evaluation of potential remedial options requires quantification of the mass and phase<br />

distribution in and near the DNAPL source zone. In 2014, five holes were continuously<br />

cored to between 55 and 63 m bgs in a transect downgradient of the source zone. The core<br />

lithology and fractures were logged in detail and over 630 rock samples were taken (at least<br />

1 per 30 cm) from the continuous cores for extraction and analysis of the contaminants<br />

of concern. A comprehensive suite of geophysical and hydro-physical logs were collected<br />

from each of the boreholes and all of the data was utilized to design high resolution multilevel<br />

systems (MLSs) for each borehole. Hydraulic heads were measured and groundwater<br />

samples for contaminant analyses were collected from the MLSs. The rock core contaminant<br />

profiles provide a quantitative and high resolution view of the contaminant mass<br />

and phase distribution in the rock matrix; commonly showing over an order of magnitude<br />

change in concentration across less than 1 m of depth. The groundwater contaminant<br />

profiles collected from the multilevel systems represent the contaminant distribution in the<br />

fractures. Integration of the data sets provides a robust understanding of the two-dimensional<br />

contaminant mass and phase distribution along a transect orthogonal to groundwater<br />

flow to show the concentration distribution and mass composition relative to the<br />

high permeability fractures and mass stored in the lower permeability matrix immediately<br />

downgradient of the DNAPL source zone. Ultimately the variability in the contaminant<br />

composition and concentration at different spatial scales across this transect will be compared<br />

to geologic and hydrogeologic properties to provide additional insights into controls<br />

on contaminant transport and fate in sedimentary rock.<br />

IAH-CNC 2015 WATERLOO CONFERENCE<br />

151

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