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THURSDAY PLENARY SESSION<br />

40 Years of Contaminant Hydrogeology<br />

John A. Cherry<br />

Distinguished Emeritus Professor, University of Waterloo,<br />

Waterloo, Ontario, Canada<br />

Forty years have passed since the earth-science sub-discipline<br />

of ‘contaminant hydrogeology’ began to use this designation.<br />

The term “Contaminant hydrogeology” was introduced into the<br />

literature in an overview article published in Geoscience Canada 1 .<br />

Part 2 of this article on the relevant chemical processes was not<br />

completed until much later 2 .<br />

This presentation examines what was known and not known when<br />

this term was introduced and how our thinking has evolved with<br />

some confusion and muddled thinking along the way, the path to<br />

understanding of dispersion being a good example. It also examines the<br />

current state of understanding; some aspects of hydrogeologic science<br />

have matured while others are still in early stages. The initial article<br />

focused on the physical processes in contaminant transport and fate was<br />

based on the sparse groundwater contamination literature up to that time,<br />

which concerned field studies of radionuclides from experimental reactor<br />

accidents in the 1950’s, leachate from municipal landfills, sewage from<br />

septic systems, petroleum hydrocarbons and the early problems caused by<br />

the mobile versions of detergents.<br />

Groundwater contamination by chlorinated solvents and the importance<br />

of DNAPLS for groundwater contamination was unknown until the early<br />

1980’s. The concept of contaminant plumes in groundwater was established<br />

by the mid-1960’s but the belief was widely held until the early 1980’s that<br />

the substantial groundwater contamination would remain minimal due to<br />

the robust assimilation capacity of the subsurface environment. This would<br />

have been correct if it were not for the widespread releases of many types of<br />

halogenated organic chemicals such as chlorinated solvents. These began<br />

entering groundwater in the 1950’s only to be discovered decades later. The<br />

warning signs of the potential for mobile recalcitrant organic chemicals<br />

of common use to cause substantial groundwater contamination occurred<br />

in the early 1960’s when detergents from septic systems were commonly<br />

found in shallow domestic wells in suburbs but this problem subsided with<br />

a change in the detergent formulation in 1963. The larger significance of<br />

this evidence concerning anthropogenic organic chemical in groundwater<br />

went unrecognized.<br />

IAH-CNC 2015 WATERLOO CONFERENCE<br />

17

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