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natural or anthropogenic hazards and water quality risk prediction. A minimum suite of<br />

parameters including the 7 major ions, pH, redox and certain dissolved gases, in addition<br />

to any health-related parameters of interest, provides much more information than the<br />

sum of their individual contributions.<br />

A full-matrix groundwater geochemical sampling program has been completed in southern<br />

Ontario at an unmatched scale, density and degree of analytical completeness. 2300<br />

samples collected at 1850 stations at a uniform sample density across the 96,000 km 2 area<br />

allows the mapping of groundwater geochemical regimes in most of southern Ontario for<br />

the first time. Dozens of phenomena and processes have been identified at all scales, many<br />

of which were previously unknown. A few examples of the processes Identified include: (1)<br />

wide regions of biogenic shale gas, (2) a 1400 km 2 breathing well zone expelling hypoxic<br />

gases, (3) stagnant flow zones, (4) provincial-scale patterns in the distribution of tritium in<br />

groundwater, (5) regions where iodine in potable water exceeds seawater by many times,<br />

(6) decadal-scale trends in aquifer recovery and depletion, (7) the replacement of ancient<br />

water in aquifers with modern water due to pumping, (8) provincial-scale regions of natural<br />

fluoride hazard (9) areas of systemic bacterial occurrence in aquifers, and (10) widespread,<br />

discreet zones of karstic groundwater flow. Most of these discoveries could not have<br />

been anticipated when the program began 8 years ago, which demonstrates the efficacy of<br />

primary data collection and geological mapping in the support of groundwater studies.<br />

207 - A study of flow system dynamics utilizing a diverse set of<br />

isotopic and geochemical methods; Oak Ridges Moraine, Ontario<br />

Lori Labelle & Shaun Frape<br />

Department of Earth and Environmental Science, University of Waterloo, Waterloo, Ontario,<br />

Canada<br />

Rick Gerber<br />

Oak Ridges Moraine Hydrogeology Program, Toronto, Ontario, Canada<br />

The Oak Ridges Moraine (ORM) is a 160-km long ridge a mixture of sand, silt and gravel<br />

deposits north of Lake Ontario, and extends west to east from the Niagara Escarpment to<br />

Peterborough and the Trent River. Understanding the complex flow system is complicated by<br />

the regional geology, which includes aquifers in the bedrock valleys, till aquifers, and eroded<br />

tunnel channels separated by aquitards. The Oak Ridges Moraine is recognized as a regionally<br />

significant groundwater recharge area and is an important source of domestic water for<br />

the Greater Toronto Region, along with providing base flow to hundreds of local streams.<br />

This regional study examines a diverse moraine complex, consisting of sediments ranging<br />

from earlier glaciations (~130k) to considerably younger materials from recent glacial<br />

events (~20k) (Barnett et al. 1998). This results in a very complex flow system within<br />

the Oak Ridges Moraine, consisting of multiple aquifer/aquitard units and end members<br />

causing multiple potential mixing scenarios. To assess this complicated hydrostratigraphy<br />

a diverse range of age dating and isotopic methods have been used in the study. Naturally<br />

occurring stable isotopes can be used to trace groundwater flow paths and provide direct<br />

evidence of the vulnerability of an aquifer; as well as provide insight into flow systems at<br />

56 IAH-CNC 2015 WATERLOO CONFERENCE

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