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Champ and Janis Gulens of AECL and Richard Jackson of Environment Canada) to<br />

explain the sequential occurrence of DO, nitrate, Fe, Mn and sulphide species. Stumm<br />

also provided guidance on the interpretation of Eh measurements by platinum electrodes<br />

that were problematic in most aqueous environments. Champ noted that the microbial<br />

requirements for functioning in groundwater systems were easily met by available nutrients<br />

dissolved in groundwater, while Gulens explained the effects of various sorbed<br />

species (e.g., DO, sulphide, cyanide from Zobell’s solution) on the measured Pt electrode<br />

potential. Jackson wrote the paper that appeared in 1979 in the Canadian Journal of<br />

Earth Sciences based on field data from a short (1 km) flow system he was studying at<br />

Chalk River including data from Back and Barnes and Edmunds.<br />

Thus chemical thermodynamics and electrochemical theory were incorporated into hydrogeology<br />

through the necessity understanding complex groundwater quality patterns<br />

and Eh measurements. This work in the 1970s set the stage for the adoption of monitored<br />

natural attenuation for the biodegradation of chlorinated and fuel hydrocarbons<br />

in the 1990s.<br />

115 - Temporal Scales in Groundwater Science:<br />

The Challenge to Hydrogeologists<br />

William M. Alley<br />

National Ground Water Association, San Diego, California, USA<br />

One of the great challenges facing groundwater hydrologists is to communicate the highly<br />

variable temporal characteristics of groundwater systems and their responses to human and<br />

natural stresses. Just as hydraulic conductivity spans many orders of magnitude, temporal<br />

scales range from real-time to many millennia. This presentation examines the different<br />

time scales of interest to hydrogeologists with an emphasis on how these time scales relate<br />

back to groundwater management and governance.<br />

248 - Laboratory demonstration of confined and unconfined<br />

aquifer storage characteristics<br />

Robert W. Gillham<br />

Department of Earth and Environmental Sciences, University of Waterloo, Waterloo,<br />

Ontario, Canada<br />

Undergraduate students of hydrogeology commonly have difficulty appreciating the differences<br />

in processes of water storage and release in confined and unconfined aquifers.<br />

After several attempts to teach the concepts, but with only moderate success, a laboratory<br />

model was developed that provided a physical and visual demonstration of specific<br />

yield, specific storage and several related phenomena. As reflected in answers to exam<br />

questions, there was a dramatic improvement in the level of student understanding. A detailed<br />

description of the model and a worked example is included in: Gillham, R. W. and<br />

O’Hannesin, S. F. 1984. Apparatus for demonstrating confined and unconfined aquifer<br />

characteristics. Journal of Geological Education, 32: 261-264.<br />

190 IAH-CNC 2015 WATERLOO CONFERENCE

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