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116 - The Effect of Injection Methods on the Distribution of<br />

Remedial Compounds<br />

Rick McGregor<br />

InSitu Remediation Services Ltd, St. George, Ontario, Canada<br />

The application of in situ methods for treating contaminants within groundwater and soil<br />

has increased over the past decade. The understanding of how contaminants are remediated<br />

using a variety of compounds is fairly well understood and demonstrated. However,<br />

numerous studies/project using in situ remediation have resulted in incomplete realization<br />

of the remedial objectives. In order for in situ methods to be effective, the injected compounds<br />

must interact directly or indirectly with the contaminant. Site specific factors such<br />

as geology, hydrogeology, geochemistry, contaminant distribution, etc. play an important<br />

role in controlling the design of any in situ program, as does understanding the role of<br />

advection and diffusion in the delivery and transport of the compounds to the contaminant.<br />

Unfortunately very few studies have been completed in the field to look at the actual<br />

distribution of compounds.<br />

A field study was conducted in an unconsolidated, unconfined aquifer to evaluate various<br />

injection and delivery methods for a variety of oxidants and reductants including persulfate,<br />

percarbonate, hydrogen peroxide and emulsified vegetable oil. Delivery methods examined<br />

for each oxidant included injection through vertical wells, injection by direct push technology<br />

using drop point and side tool technologies. The results of the study indicated that the<br />

delivery method has a significant impact on the distribution of the compound within the<br />

subsurface whereas the type of compound also impacted the distribution geometry within<br />

the aquifer tested. Direct push technology offered superior distribution compared to injection<br />

of the compounds into vertical wells with injection through side tools showing better<br />

vertical and lateral distribution than drop point methodology. These results suggest that<br />

the choice of delivery method is a key design parameter for any in situ remedial program<br />

and that the delivery method needs to be customized based on site-specific factors to the<br />

choice of remedial compound being used.<br />

249 - Enhanced in situ Bioremediation of Chlorinated Solvents in<br />

Canada<br />

Jeff Roberts, Phil Dennis, Sandra Dworatzek & Peter Dollar<br />

SiREM, Guelph, Ontario, Canada<br />

Bioremediation of chlorinated solvents, including perchloroethene (PCE) and trichloroethene<br />

(TCE), in groundwater is a proven and cost effective remedial approach. KB-1 ® , a<br />

bioaugmentation culture that promotes the complete dechlorination of chlorinated ethenes<br />

to ethene has been used extensively for bioremediation projects around the world. KB-<br />

1® is the only anaerobic bioaugmentation culture to receive Federal regulatory acceptance<br />

through the New Substance Notification (NSN) regulation process and was added to the<br />

Domestic Substances List in 2008. Since then KB-1 ® has been applied successfully at<br />

several sites in Canada.<br />

IAH-CNC 2015 WATERLOO CONFERENCE<br />

45

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