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316 - Regional patterns and geochemical controls on shallow<br />

groundwater chemistry in Southeastern Ontario<br />

Laura M. Colgrove, Stewart M. Hamilton, & Fred J. Longstaffe<br />

Department of Earth Sciences – University of Western Ontario, London, Ontario, Canada<br />

This study reports regional chemistry for shallow groundwater from southeastern Ontario<br />

and identifies the dominant geochemical processes responsible for its variability. The database<br />

includes chemical analyses of groundwater from 264 wells located between the Frontenac<br />

Arch and the Quebec border, which were sampled as part of the Ambient Groundwater<br />

Geochemistry Program of the Ontario Geological Survey. Users of groundwater<br />

in eastern Ontario experience unusually elevated levels of many chemical constituents,<br />

including Na + , Cl - , I - , DOC, DIC and TDS. Whereas typical drinking water has TDS<br />

ranging from 500-700 ppm, 39 Eastern Ontario samples can be classified as “brackish”,<br />

ranging from 1000 – 10000 ppm, and 1 sample classified as saline at 10400 ppm. Spatial<br />

variations in groundwater chemistry show a strong correlation with the occurrence of<br />

Pleistocene (“Leda”) clays deposited by the Champlain Sea. Halogen ratios, water stable<br />

isotope compositions and major-ion proportions suggest that the regional groundwater<br />

flow system may be interacting with Champlain seawater still present in parts of the study<br />

area. Infiltrating meteoric water is confined by thickening Champlain Sea clays, and its<br />

chemistry evolves through ion exchange and mixing with Pleistocene water. Ion exchange<br />

with these clays softens the water, creating potential health-related implications for drinking<br />

water, including those associated with elevated concentrations of sodium and fluoride.<br />

Elevated DIC, DOC and I - , along with the presence of HS - and CH 4<br />

, are attributed to<br />

anaerobic decomposition of organic matter associated with the Champlain Sea clays and<br />

shale. The combined contributions of Champlain seawater and decomposition of associated<br />

organic matter has produced the highest I - concentrations so far measured in Ontario,<br />

which commonly exceed those of seawater by an order of magnitude.<br />

119 - Challenges and Issues Related to the Water Supply from the<br />

Brandon Channel Buried Valley Aquifer – Brandon, Manitoba<br />

Jeffrey J. Bell<br />

Friesen Drillers Ltd., Steinbach, Manitoba, Canada<br />

The hydrogeology and recharge characteristics of buried valley aquifers on the Canadian<br />

prairies are complex. The City of Brandon, in western Manitoba, relies on a water supply<br />

from the Assiniboine River. A large buried deposit of sand and gravel was present within a<br />

valley in the shale bedrock in Brandon. This deposit is called the Brandon Channel Aquifer.<br />

The Brandon area was once a key restriction in the northerly drainage of the vast majority<br />

of Central North America. This river system deposited a large amount of sediment. The<br />

area was subsequently glaciated several times, during the Pleistocene. These glacial events<br />

deposited related glacial deposits.<br />

Two industrial plants utilize 30,000 m 3 /day of groundwater for process and cooling applications.<br />

The aquifer is narrow in places and varies considerably in thickness and structure.<br />

IAH-CNC 2015 WATERLOO CONFERENCE<br />

171

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