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NAMS 2002 Workshop - ICOM 2008

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model results with bench-scale studies of seawater desalination using<br />

commercially available NF/RO membranes. We have created a simple analytical<br />

model that estimates full-scale NF/RO system product water quality and specific<br />

energy consumption considering a membrane’s water permeability and TDS<br />

rejection, feed water concentration, total system flux, and concentration<br />

polarization. In addition, we have developed a bench scale NF/RO seawater<br />

desalination simulator for testing real NF/RO membrane performances in the<br />

modeled scenarios.<br />

Model results for single-pass SWRO systems suggest the theoretical minimum<br />

specific energy consumption is not yet realized, the effects of concentration<br />

polarization are non-negligible, and increasing SWRO membrane permeability<br />

beyond that of modern BWRO membranes may yield little benefit. These results<br />

may have important implications and could be used to guide future efforts to<br />

engineer better performing SWRO membranes and modules. These results and<br />

their implications will be discussed in the presentation. Model simulations are<br />

also performed to elucidate the optimal combination of first and second pass<br />

NF/RO membrane rejections for a two-pass system. Simulations consider three<br />

scenarios in which (a) membrane resistance and CP are neglected, (b)<br />

membrane resistance is neglected, CP is considered, and (c) membrane<br />

resistance and CP are considered. These results highlight the important role of<br />

membrane resistance and CP in multi-pass system performance. Finally, three<br />

scenarios have been tested in the laboratory: (a) two-pass NF membrane<br />

followed by a high-rejection BWRO membrane, (b) two-pass seawater NF<br />

(SWNF) membrane followed by another SWNF membrane, and (c) a one-pass<br />

SWRO membrane. All three scenarios give desalination performance that may<br />

have practical value. In this presentation we will present details of our modeling<br />

and experimental results, and discuss the implications for single-pass and multipass<br />

NF/RO seawater systems.<br />

Reference:<br />

1.Sauvet-Goichon, B., Ashkelon desalination plant -- A successful challenge. Desalination, 2007.<br />

203(1-3): p. 75.<br />

2.Lomax, I., Experiences of Dow in the field of seawater reverse osmosis. Desalination, <strong>2008</strong>.<br />

224(1-3): p. 111.<br />

3.Harrison, C.J., et al., Bench-scale testing of nanofiltration for seawater desalination. Journal of<br />

Environmental Engineering-Asce, 2007. 133(11): p. 1004-1014.

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