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6.1. FORSCHUNGSSTELLE “RADIOMETRIE” 169<br />

6.1.9 U-series dating and paleoclimatic interpretation of the stable isotope<br />

profile of stalagmite ER76 from Grotta di Ernesto, Italy<br />

Denis Scholz (Participating scientists: Christoph Spötl (Innsbruck), Silvia Frisia (Trento), Andrea<br />

Borsato (Trento), Jens Fohlmeister)<br />

Abstract Stalagmite ER76 from Grotta di Ernesto, Italy, was precisely dated by TIMS Th/Udating.<br />

The age-depth-model was constructed using a Bayesian approach to improve the dating<br />

uncertainty and applying a mixed effect regression model. Furthermore, high-resolution stable oxygen<br />

and carbon isotope profiles were determined.<br />

A g e [k y r]<br />

1 0<br />

9<br />

8<br />

7<br />

6<br />

5<br />

4<br />

3<br />

2<br />

1<br />

A g e -d e p th m o d e l (H e e g a a rd e t a l., 2 0 0 5 )<br />

9 5 % c o n fid e n c e lim its<br />

N e w U -s e rie s a g e s<br />

U -s e rie s a g e s (M c D e rm o tt e t a l., 1 9 9 9 )<br />

0<br />

0 5 0 1 0 0 1 5 0 2 0 0 2 5 0 3 0 0 3 5 0 4 0 0<br />

D is ta n c e fro m to p [m m ]<br />

Figure 6.10: Final age-depth-model calculated for stalagmite ER76<br />

Background Stalagmite ER76 from Grotta di<br />

Ernesto, Italy, was precisely dated by TIMS<br />

Th/U-dating. The age-depth-model was constructed<br />

using a Bayesian approach to improve the<br />

dating uncertainty and applying a mixed effect regression<br />

model. Furthermore, high-resolution stable<br />

oxygen and carbon isotope profiles were determined.<br />

Methods and results Nine TIMS U-series<br />

ages as well as high-resolution stable isotope profiles<br />

on stalagmite ER76 from Grotta di Ernesto,<br />

Italy, were determined. Due to its low 238 U (20-<br />

40 ng/g) content which is typical for stalagmites<br />

from Grotta di Ernesto, U-series dating of ER76<br />

is rather difficult. Nevertheless, we were able to<br />

determine a 230 Th/U-age of 2.27 0.08 kyr in the<br />

youngest part, at 30 mm distance from top (dft).<br />

However, due to the low U content, the error bars<br />

of some data points overlap significantly. By application<br />

of a Bayesian approach which takes into<br />

account both the results of the U-series dating<br />

and the stratigraphic sequence of the individual<br />

samples the uncertainty of some data points could<br />

be reduced substantially. We suggest to generally<br />

apply this Bayesian approach when the individual<br />

data point errors overlap. Overall, 13 data points,<br />

nine measured in Heidelberg and four by McDermott<br />

et al. [1999], were used to construct the final<br />

age-depth relationship for ER76. The age model<br />

and its uncertainty (see Fig. 6.10) was estimated<br />

using a mixed-effect regression model [Heegaard<br />

et al. , 2005]. Based on the new age model, ER76<br />

exhibits a rather constant growth rate of approximately<br />

0.05 mm/yr between 8.5 and 2 kyr. It<br />

was actively growing when it was collected, and<br />

Frisia et al. [2003] have shown that ER76 exhibits<br />

annual laminae in the period between 1650<br />

and 1995 AD. The thickness of these annual laminae<br />

lies between 0.02 and 0.1 mm. In combination<br />

with the new age model obtained by U-series dating<br />

this shows that there must be a substantial<br />

hiatus between 2 and 0.5 kyr in ER76. Oxygen<br />

and carbon stable isotope profiles were measured<br />

at the University of Innsbruck at a resolution of<br />

0.1 mm between 0 and 8 mm dft and 0.25 mm<br />

below 8 mm dft.<br />

Outlook/Future work An earlier study [Mc-<br />

Dermott et al. , 1999] revealed that ER76 recorded<br />

several Holocene warm/dry and cold/wet phases,<br />

respectively. Because the resolution in that study<br />

was approximately 2 mm, the new profiles have<br />

a ten times higher resolution which should enable<br />

to detect even rapid climate events.<br />

Funding DFG Forschergruppe 668: ”Datierte<br />

Speläotheme: Archive der Paläoumwelt”<br />

Main publication Vollweiler et al. [2006],<br />

Scholz & Mangini [2006], Scholz & Mangini [accepted<br />

for publication], Mangini et al. [accepted<br />

for publication]

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