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56 CHAPTER 2. ATMOSPHERE AND REMOTE SENSING<br />

Figure 2.27: The timeline of continuous novel UV/vis/NIR satellite measurements starts in April<br />

1995 with GOME (1) on ERS-1. With its successors it will hopefully cover a total period of more<br />

than 25 years.<br />

Main activities<br />

How are single projects linked, list/group the subprojects<br />

The various projects can be classified according to their spectral range, viewing geometry, and<br />

analysis method.<br />

- UV/vis DOAS for Nadir viewing geometry The main target is the determination of global maps<br />

of tropospheric trace gas distributions like NO2, BrO, H2O, HCHO, SO2, Glyoxal. Currently measurements<br />

of GOME and SCIAMACHY are under investigation.<br />

- NIR DOAS for Nadir viewing geometry The main target is the determination of global maps of<br />

tropospheric trace gas distributions like CH4, CO2, and CO. Measurements in the near IR spectral<br />

range are carried out only by SCIAMACHY.<br />

-Cloud retrieval for Nadir viewing geometry The main target is the determination of global maps of<br />

cloud cover (effective cloud fraction) from broad band spectral measurements. From the combination<br />

with narrow band absorption measurements of O2 and O4, also additional parameters like cloud top<br />

height can be retrieved.<br />

-UV/vis DOAS for limb viewing geometry The main target is the determination of vertical profiles<br />

of stratospheric trace gases like O3, NO2, BrO, and OClO. Measurements in limb viewing geometry<br />

are carried out only by SCIAMACHY.<br />

-3-D radiative transfer modelling Detailed radiative transfer modelling is the prerequisite for the<br />

correct interpretation of the results of the spectral analysis. The full spherical 3-dimensional Monte<br />

Carlo model is developed and operated in our group. Also a detailed scheme for the simulation of<br />

radiative properties of aerosols is developed.<br />

-Validation of satellite data with independent observations DOAS observations are carried out<br />

from several ground based stations (Kiruna, Paramaribo, Neumayer) as well as from aircrafts and<br />

ships.<br />

Methods and results From the measured spectra, the narrowband absorption features of several<br />

trace gases are analysed using the DOAS method. The result of the spectral analysis represents the<br />

trace gas absorption integrated along the absorption path. In addition, also the broad band spectral<br />

features are analysed; they yield information in particular on the cloud cover, aerosol load and ground<br />

albedo (in particular also vegetation cover). Various algorithms for the analysis of satellite spectra<br />

were developed in the satellite group within the last years. For the detailed interpretation of the<br />

analysed spectral information, radiative transfer modelling is needed. A 3-D Monte-Carlo radiative<br />

transfer model (TRACY-II) was developed in our group, which allows to simulate various complex<br />

viewing geometries and atmospheric properties. The retrieved global data sets are further investigated<br />

using image sequence techniques.

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