THE RADIOCHEMISTRY OF PLUTONIUM - Sciencemadness.org
THE RADIOCHEMISTRY OF PLUTONIUM - Sciencemadness.org
THE RADIOCHEMISTRY OF PLUTONIUM - Sciencemadness.org
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B. Pu(~)~ Pu(LU)<br />
Reagents Solution Temp. Rate Reference<br />
Hydroquinone mute HN03 R.T. Rapid<br />
H2, Pt 0.5 g - 4. O~HCl R.T. > 9~0 reduced in 40 min<br />
I- 0.1 yKI+ 0.4 ~ HC1 R.T.<br />
Hso; 0.05 ~ NH4HS03, R.T.<br />
0.3 ~ mo~<br />
NH30H+ 0.5 M HN03<br />
NH36H+<br />
+ 0.1 ~ R.T.<br />
NH20H. HC1, HC1 ----<br />
Zn .0.5 ~ HC1 R.T.<br />
S02 1 ~ HN03 R.T.<br />
Ti# 6 ~ HC1, R.T.<br />
dilute H2S04 R.T.<br />
1 ~ HN03 + 1 ~H2S04R.T.<br />
Cr++ Dilute HC1 or H2S04 R.T.<br />
Ascorbic HN03<br />
Acid 0.5 ~HN03, 0.01 ~ R.T.<br />
Ascorbic acid<br />
6 MHN03 O.1~<br />
A s~orbic acid, Fe(II)<br />
Sulf amat e R.T.<br />
H202 7J~HCl R.T.<br />
11<br />
‘1/2 =2min<br />
‘1/2<br />
‘1/2<br />
= -2 min 65<br />
-40 min<br />
-----------------------<br />
Rapid<br />
tl]<br />
< 1 min<br />
2<br />
Very rapid 235<br />
Very rapid 235<br />
Rapid 103<br />
Rapid 235, 449<br />
Rapid 416,402<br />
Rapid 65<br />
Rapid 65<br />
Complete in several hr 145
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