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186. 187. 188. 189. 190. 191. 192. 193. 194. 195. 196. 197. 198. 199. 200. 201. 202. 203. 204. 205. 206. 207. 208. 209. 210. 211. 212. 213. 214. 215. 216. D. E. Homer and C. F. Coleman, ORNL-2830, Nov. 1959. D. E. Homer and C. F. Coleman, ORNL-3051, March 1961. G. R, Howells, T, G. Hughes, and K. Saddin@on, Progr. Nucl. Enerpy Ser. III, Vol. 3, Chap. 3-2, P 151. (See also A/ CONF. 15/1, Vol. 17, p 3, Paper/ 307.) D. L. Hufford and B. F. Scott, in “The Transuranium Elements,ll p 1149, Paper/ 16.l. A. Hultgren and E. Haeffner, A/ CONF. 15/1, Vol. 17, p 324, Paper/ 144. G. J. Hunter and R. B. Chenley, UK-AIM, AERE-AM-19, 1959. E. K. Hyde, “The Nuclear Properties of the Heavy Elements. II. Detailed Radioactivity Properties” (Prentice Hall, Inc. , New Jersey, 1964) pp 804-838. C. H. Ice, HW-10277, June 1948. M. G. Inghram, D. C. Hess, P. R. Fields, and G. L. Pyle, “Half-life of ~u240 236 as Determined by its U Daughter, ” briefly noted in ANL-4653. E. R. Irish and W. H. Rease, HW-49483, April 1957. H. Irving and D. N. Edgington, J. Inorg. Nucl. Chem. ~, 158 (1960). H. Irving and D. N. Edgington, J. Inorg. Nucl. Chem. ~, 321 (1961). H. Irving and D. N. Edgington, J. Inorg. Nucl. Chem. ~, 314 (1961), See Ref. 197. H. Irving and D. N. Edgington, J. Inor g . Nucl, Chem. 21, 169 (1961). N. M. Isaac, P. R. Fields, and D. M. Gruen, J. Inorg. h’ucl. Chem. ~, 152 (1960). T. Ishimori, K. Watanabe, and T. Fujino, J, At. Ener gy Sot. Japan ~ 507 (1961). T. Ishimori and J. Akatsu, Radiochim. Acts ~, 11 (1962). N. Jackson and J. F. Short, UKAEA, AERE-M-444, July 1959. W. R. Jacobsen, ANL-6637, 1962, pp33-42. Seventh Annual Meeting on Bio-assay and Analytical Chemistry, Oct. 12-13, 1961. Argonne National Laboratory. USA EC, 1962. A. H. Jaffey, “The Actinide Elements, ” pp 596-732. , D. B. James and E. L. Christensen, LASL, LADC-5424, March 1963. E. N. Jenkins and G. W. Sneddon, UKAEA, AERE-C-R-1399, hTov. 1954. E. N. Jenkins and R. J. W. Streeton, UKAEA. AERE-R-3158, Dec. 1959. W. J. Jenkins, J. Inorg. Nucl. Chem. ~ 463 (1963). E. R. Jette, J. Chem. Phys. ~ 365 (1955). N. R. Johnson, E. Eidiler, and G. D. OIKelley, in “Inorganic Chemistry” (Interscience Pubs. , New York, 1963) Vol. 2, Chap, VII. N. R. Johnson, E. Eidiler, and G. D. O’Kelley, in “Inorganic Chemistry” (Inters cience Pubs. , New York, 1963) Vol 2, Chaps. III and VI. M. M. Jones, HW-30384, Dec. 1953. M. Kasha and G. E. Sheline, in “The Transuranium Elements, ” Paper/3. 14. R. E. Kartushova, T. I. Rudenko, and V. V. Fomin, Atomnaya Energ. ~, 24 (1958). In Russian. English trans. Soviet J. At. Energy ~, 831 (1958). 175
217. W. E. Keder, J. Inorg. Nucl. Chem. ~, 561 (1962). 218. W. E. Keder, J. C. Ryan, and A. S. Wilson, J. Inor~. Nucl. Chem. ~, 131 (1961). 219. W. E. Keder, J. C. Sheppard, and A. S. Wilson, J. Inorg. Nucl. Chem. ~, 327 (1960). 220. D. M. Kemp, UKAEA, AERE-R-4119, July 1962. 221. J. Kennedy, UKAEA, ~ Aug. 1962. 222. J. Kennedy, R. V. Davies, and B. K. Robinson, UKAEAJ AERE-C/R-1896, 1956. 223. J. Kennedy, J. W. Peckett, and R. Perkins, UKAEA, AERE-R-4516, 1964. 224. V. A. Khalkin, P. N. Palei, and A. A. Nemodruk, Radiokhimiya ~, 215 (1963). 225. K. Kimura, Chem. Sot. Japan J. ~, 1038 (1960). 226. K. Kimura, Chem. Sot. Japan J. ~, 63 (1961). 227. E. L. King. ANL-JJK-14B-45, 1946. (See also Clinton Labs., Oak Ridge, Term. CN-2726, Dec. 1944). 228. E. L. King and W. H. Reas, J. Am. Chem. Sot. ~, 1804 (1951). 229. P. Kirk and C. J. Redden, “Transuranic Elements: Analytical Chemistry, ” Manhattan Dist; Oak Ridge, Term. 1947, AEC Report TID-5002; Nov. 1954. 230. J. Kleinberg, LASL, LA 1721 (Rev), 1954. 231. W. Knoch and R. Lindner, Z. Elektrochem. U, 1021 (1960). In German. 232. W. Knoch, Z. Naturforsch. ~, 525 (1961). 233. R. Ko,’ ~ Jan. 1956. 234. R. Ko, HW-79738, 1963. 235. R. J. Kofoed, Jr. , HW-53368 (Supp. 1), 1963. 236. J. Kooi, JENER-Pub-11, 1956. 237. J. Kooi and U. Hollstein, Health Phys. Q, 41 (Feb. 1962); U. Hollstein, A. H. M. Hoogma, and J. Kooi, Health Phys, 8, 49 (1 962). — 238. V. N. Kosyakov, E. S. Gureyev, and G. N, Yakolev, “Separation of Transuranium ~ements by Solution Extraction in Alkyl Phosphoric Acids, ” Paper given at Transplutonium Symposium, Argonne National Laboratory, nl. , May 1963. (Proceedings not published.) 239. K. A, Kraus, A/ CONF. 8/7, p 245, Paper/731. 240. K. A. Kraus and F. Nelson, A/CONF. 8/7, p 113, Paper/837. 241, K. A. Kraus and F. Nelson, Ann. Rev. Nucl. Sci. ~, 31 (1957). 242. K. A. Kraus, H. O. Phillips, T. A. Carlson, and J. S. Johnson, A/CONF. 15/1, Vol. 26, p 3, Paper/1832. 243. I. K. Kressin and G. R. Waterbury, Analyt. Chem. ~, 1598 (1962). 244. M. E. Krevinskaya et al Radiokhimiya ~ 545 (1959). —- J 245. L. Ku~a, Collection Czech. Chem. Commun. 27, 2372 (Oct. 1962). In German. 246. L. Ku~a, Jaderna Energie ~ 286 (1962). In Czech. 247. V. I. Kuznetsov and T. G. Akimow, Radiokhimiya ~, 357 (1 960). [See also Sotiet J. At. Ener HS, 135 (1960 ).] 248. W. H. Langham, Manhattan Dist. Oak Ridge, Term. AEC Report ~ 1947. (~”SO LAMS-603. ) 176
Page 1 and 2:
1National Academy of Sciences Natio
Page 3 and 4:
The Radiochemistry of Plutonium. Ge
Page 5 and 6:
PREFACE This report has been prepar
Page 7 and 8:
Procedures (Continued) CONTENTS (Co
Page 9 and 10:
IL GENEWL REVDZWS OF THE RADIWHEMIS
Page 11 and 12:
IV. CHEMISTRY OF PLUTONIUM OF SPECI
Page 13 and 14:
Solution TABLE IV-2. Behavior of PU
Page 15 and 16:
* Compiled primarily from the revie
Page 17 and 18:
TABLE IV-6. Oxidation-Reduction Rea
Page 19 and 20:
c.. Pu(IV)+ Pu(VI) Reagents Solutio
Page 21 and 22:
Concentration Equilibrium Constant
Page 23 and 24:
PU+4 has approximately the same ten
Page 25 and 26:
TABLE IV- 9. Ionic Potential of Plu
Page 27 and 28:
TABLE IV- 11. Stabflity Conetants o
Page 29 and 30:
TABLE IV- 12. Stability Constants o
Page 31 and 32:
D. 1 Co-precipitation and Precipita
Page 33 and 34:
is first oxidized to Pu(VI) with so
Page 35 and 36:
oxygen in the ratio 1:3. If an exce
Page 37 and 38:
the TBP cone entration. Solovkin 39
Page 39 and 40:
D, l? D Ic n. 0 5 10 Concentration
Page 41 and 42:
D 103 ~ ,.2 _ 10 I H ,0-1 ~ / P / P
Page 43 and 44:
100( I0( 1( D 1.( 0. 0.0 0.00 Nltrl
Page 45 and 46:
Table IV- 16. (Continued) Extractan
Page 47 and 48:
Table IV-16. (Continued) Extr actan
Page 49 and 50:
In this equation, HA represents any
Page 51 and 52:
X[N05] = [HN03] ‘( ~ ~[N03] = HN0
Page 53 and 54:
Di-acidic compounds. Mono-2- ethylh
Page 55 and 56:
A may be either a simple anion or t
Page 57 and 58:
n 104 d Id 10 I 10-1 , a ,,81 0.1 M
Page 59 and 60:
The fact that Pu(III) does not extr
Page 61 and 62:
Fig. 25. Extraction of elements as
Page 63 and 64:
TABLE IV- 19. Distribution Coeffici
Page 65 and 66:
10~ I ~ 0.01~ D 0.001 : 0,0001 . La
Page 67 and 68:
loi- 1“’’’’’’’”1
Page 69 and 70:
TABLE IV- 22. Extraction of Plutoni
Page 71 and 72:
m * Amideb N, N-Dihexylformamide N,
Page 73 and 74:
dependence on the TTA concentration
Page 75 and 76:
1.0 D 0.1 —--L~,20 HNOO; CO&NT R
Page 77 and 78:
cupferron, followed by back extract
Page 79 and 80:
. more. Siekierski and Taube, 381 a
Page 81 and 82:
TABLE IV- 27. Slope of the Dependen
Page 83 and 84:
polymerization of the resin to prov
Page 85 and 86:
co ; n 1000L z - 100 z o ~ m oL x z
Page 87 and 88:
Volume distribution coefficient of
Page 89 and 90:
affinity of several ions was Th(IV)
Page 91 and 92:
95% of Pu(IV) was removed from a 0.
Page 93 and 94:
2 d 1.0 I I I 1 I I 1 ,, , , I II r
Page 95 and 96:
X“ 104 , 1 1 1 1 1 .— .-. I Ioa
Page 97 and 98:
200 100 50 20 I O.10 ~ $ NPIX PUIIT
Page 99 and 100:
Fig. 54. Adsorption of the elements
Page 101 and 102:
Toribara et al. 403 used a liquid s
Page 103 and 104:
V. DISSOLUTION OF PLUTON17JM SAMPLE
Page 105 and 106:
m m TABLE VI- 30. Source Preparatio
Page 107 and 108:
o 0 TAIIT.E VI-31. Techniques for M
Page 109 and 110:
Solvent extraction of Pu into a liq
Page 111 and 112:
TABLE VII-33. Basic Data for Critic
Page 113 and 114:
Procedure No. 6. 7. 8. 9a, 9b , Aut
Page 115 and 116:
Procedure 1. Determination of Pu in
Page 117 and 118:
(e) (f) (g) (h) Where C v E The pre
Page 119 and 120:
Procedure 2. Separation and determi
Page 121 and 122:
Procedure 3. Separation and determi
Page 123 and 124:
Procedure 4. Plutonium R. J. Morrow
Page 125 and 126:
Procedure 5. Plutonium D. C, Hoffma
Page 127 and 128:
Procedure m. Pipet tie samples (2~i
Page 129 and 130:
Procedure 6. Separation of Plutoniu
Page 131 and 132: Procedure 7. Determination of Pu (R
Page 133 and 134: Procedure 8. Uranium and Plutonium
Page 135 and 136: 15. Add 3 drops of HC1 and 1 drop o
Page 137 and 138: Procedure 9b. Separation of Plutoni
Page 139 and 140: Procedure 11. Uranium and Plutonium
Page 141 and 142: Procedure 12. Plutonium from Enviro
Page 143 and 144: 9. 10. 11. 12. 13. 14. 15. 16. 17.
Page 145 and 146: 10. 11. 12. 13. 14. 15. 16. 17. 16.
Page 147 and 148: Procedure 14. Separation of Plutoni
Page 149 and 150: Procedure 15. Separation of Pu befo
Page 151 and 152: Procedure 16. Separation of Plutoni
Page 153 and 154: Appendix (m) (n) (o) (P) Purificati
Page 155 and 156: Procedure 17. Separation of Np and
Page 157 and 158: Procedure 19. Determination of Plut
Page 159 and 160: NOTE: Reporting Results Results are
Page 161 and 162: Notes .. 1. 2. 3. The element prase
Page 163 and 164: 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13
Page 165 and 166: Procedure 22. Determination of Amer
Page 167 and 168: concentrated nitric acid in a block
Page 169 and 170: Preparation of Sample The 24-hr or
Page 175 and 176: “The Actinide Elements” (McGraw
Page 177 and 178: 48. D. H. Boase, J. K. Foreman, and
Page 179 and 180: 108. 109. 110. 111. 112. 113, 114.
Page 181: 159. 160. 161. 162. 163. 164. 165.
Page 185 and 186: 279. 280. 281. 282. 283. 284. 285.
Page 187 and 188: 339. 340. 341. 342. 343. 344. 345.
Page 189 and 190: 397. 398. 399. 400. 401. 402. 403.
Page 191 and 192: 451. C. E. Honey, Jr., R. N. R. Mul
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