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311. D. F. Peppard, G. W. Mason, and C. M. Andrejasich, J. Inorg. Nud. Chem. ~, 1175 (1963). 312. D. F. Peppard, G. W. Mason, and S. McCarty, J. Inorg. Nucl. Chem. ~, 138 (1960). 313. D, F. Peppard, G. W. Mason, and R. J. Sironen, J. Inorg, Nucl. Chem. g, 117 (1959). 314. D. F. Peppard, S. W. Moline, and G. W. Mason, J. Inorg. Nucl. Chem. ~, 344 (1957). 315. D. F. Peppard, M. H. Studier, M. V. Gergel, G. W. Mason, J. C. Sullivan, and J. F. Mech, AEC, Wash. D. C., AECD-3016, See also J. Am. Chem. SOC. ~, 2529 (1951). 316. R. W. Perkins, Private Communication, 1961. 317. W. C. Perkins, DP-8741 Feb. 1964. 318. K, A. Petrov et al Russ. J. Inorg. Chem. ~ 237 (1960). [Transl. from —. J Zh. INeorg. Khim. ~ 498 (1960 ).] 319. G. Phillips and E. N. Jenkins, J. Inorg. Nucl. Chem. ~, 220 (1957). 320. N. I. Popov, V. 1. NIedvedovskii, and N. A. Bakh, Atornnaya Energ. ~ 154 (1958). (English transl. AEC-tr-3459. ) 321. J. A. Porter, DP-388, July 1959. 322. J. A. Porter, DP-389, July 1959. 323. J. A. Porter, DP-621, Aug. 1961. 324. A. M. Poskanzer and B. M. Foreman, Jr. , J. Inorg. Nucl. Chem. @ 323 (1961). 325. I. Prevot, J. Corpel, and P. Regnaud, A/CONF. 15/1, Vol. 17, p 96, Paper/1171. 326. S. W. Rabideau, M. J. Bradley, and H. D. Cowan, LASL, LAMS-2236, June 1958. 327. R. H. Rainey, ORNL, CF-59-12-95, Dec. 1959. 328. M. J. Rasmussen and H. W. Crocker, HW-72285, Jan. 1962. 329. J. E. Rein, A. L. Langhorst, Jr. , and M. C. Elliott, LASL, LA-2291, Feb. 1953. 330. Reference eliminated. 331. A. E. Reisenauer and J. L. Nelson, HW-59983, April 1959. 332. B. F. Rider, J. L. Russell, Jr. , D, L. Harris, and S: P. Peterson, Jr. , Gen. Electric Co. Vallectios Atomic Lab. , Pleasanton, Cslif. , GEAP-3373, March 1960. 333. F. P. Roberts and F. P. Brauer, HW-60552, June 1959. 334. A. M. Rozen and E. L Moiseenko, Russ. J. Inor,q. Chem. ~, (1959). 335. T. C. Runion and C. V. Ellison, OR NL-557, Jan. 1950. 336. E. R. Russell, DP-447, Feb. 1960. 337. J. L. Ryan, J. Phys. Chem. ~, 1375 (1960). 338. J. L. Ryan, AEC, Oak Ridge, Term. TID-7607, 1960, PP 2-20. 179
339. 340. 341. 342. 343. 344. 345. 346. 347. 348. 349. 350. 351. 352. 353. 354. 355. 356. 357. 358. 359. 360. 361. 362. 363. 364. 365. 366. 367. 368. 369. J. L. Ryan and E, J. Wheelwright, ~ Feb. 1959. J. L. Ryan and E. J. Wheelwright, A/ CONTF. 15/1, Vol. 17, p 137, Paper/1915. J. Rydberg, Acts Chem. Stand. ~, 1252 (1955). J. Rydberg, J. Inor g, Nucl. Chem. ~, 79 (1957). J. Rydberg and B. Bernstrbm, A. Samartseva, Soviet J. At. Ener gy.~, 279 (1 960). [Transl. from Atomnaya Energiya, ~, 324 (1960 ).] A. G. Samart.seva, Radiokhimiya ~, 647 (1962). In Russian. A. G. Samartseva, Radiokhimiya ~, 28 (1963). In Russian. A. G. Samartseva, Radiokhirniya ~, 526 (1962). In Russian. o samuel~on, llIon x Separations in Analytical Chemistw “ (Almq~st and Wiksell, Stockholm, 1963). S. M. Saders, PL2!L 1956. D. Scargill, K. Alcock, J. M. Fletcher, E. Hesford, and H. A. C. McKay, J. Inorg. Nucl. Chem. ~, 304 (1957). J. Scheicfhauer and L. Messtinguird, Chim. Anal. (Paris) ~ 462 (1961). J. Scheidhauer, L. Messainguiral, and A. M. Meiraneisio, CEA-2354, 1953. C. S, Schlea, M. R. Caverly, H, E. Henry, and W. R. Jenkins, DP-808< April 1963. C. S. Schlea, M. R. Caverly, H. E. Henry, W. R. Jenkins, and W. C. Perkins, JX&Z39, Sept. 1962. Reference deleted. R. A. Schneider and K. M. Harmon, HW-533 68, Feb. 1961. R. A. Schneider, Anal. Chem. ~ 522 (1962). (Alfio HW-SA-2216. ) J. Schubert, Clinton Labs. , Oak Ridge, Term. , CN-1873, 1945. K. Schwabe and D. Nebel, Z. Physik. Chem. 219-220, 339-54 (1962). L. C. Schwendiman and J. W. Hesly, Nucleonics @ 78 (1958). C. A. Seils, Jr. , R. J. Meyer, and R. P. Larsen, Anal. Chem. ~, 1673 (1963). (Also AEC, Oak Ridge, Term. , TID-1883~ .) D. F. Shepard, HW-3271O, 1955. J. C. Sheppard, HW-51958, Aug. 1957. V. B. Shevchenko and I. A. Federov, Radiochemistry (USSR) ~ 1 (1 961). [Transl. from Radiokhimiya ~ 6 (1960 ).] V. B. Shevchenko, N. S. PovitskiJ and A. S. Solovkin, Prorr. Nucl. En errv Ser. HI, Vol. 3, Chap. 3-6, p 217. V. B. Shevchenko, V. S. Schmidt, and E. A. Mezhov, Russ. J. Inorg. Chem. ~, 929 (1960). [Transl. from Zh. Neorgan. Khim. ~, 1911 (1960 ).] V. B. Shevchenko, I. V. Shilin, and Y. F. Zhdanov, Russ, J. Inorg. Chem. ~, 1367 (1960). [Transl. from Zh. Neorgan. Khim. ~, 2832 (1960 ).] V. B. Shevchenko and V. S. Smelov, Soviet J. At. Ener,gy ~, 76 (1960). [Transl. from Atomnaya Energiys ~, 140 (1959 ).] V. B. Shevchenko, A. S. Solovkin, L. M. Kirillov, and A. I. Ivantsev, Radiochemistry (USSR) ~, 186 (1962). [Transl. from Radiokhimiya ~, 503 (1961 ).] 180
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1National Academy of Sciences Natio
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The Radiochemistry of Plutonium. Ge
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PREFACE This report has been prepar
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Procedures (Continued) CONTENTS (Co
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IL GENEWL REVDZWS OF THE RADIWHEMIS
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IV. CHEMISTRY OF PLUTONIUM OF SPECI
Page 13 and 14:
Solution TABLE IV-2. Behavior of PU
Page 15 and 16:
* Compiled primarily from the revie
Page 17 and 18:
TABLE IV-6. Oxidation-Reduction Rea
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c.. Pu(IV)+ Pu(VI) Reagents Solutio
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Concentration Equilibrium Constant
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PU+4 has approximately the same ten
Page 25 and 26:
TABLE IV- 9. Ionic Potential of Plu
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TABLE IV- 11. Stabflity Conetants o
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TABLE IV- 12. Stability Constants o
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D. 1 Co-precipitation and Precipita
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is first oxidized to Pu(VI) with so
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oxygen in the ratio 1:3. If an exce
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the TBP cone entration. Solovkin 39
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D, l? D Ic n. 0 5 10 Concentration
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D 103 ~ ,.2 _ 10 I H ,0-1 ~ / P / P
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100( I0( 1( D 1.( 0. 0.0 0.00 Nltrl
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Table IV- 16. (Continued) Extractan
Page 47 and 48:
Table IV-16. (Continued) Extr actan
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In this equation, HA represents any
Page 51 and 52:
X[N05] = [HN03] ‘( ~ ~[N03] = HN0
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Di-acidic compounds. Mono-2- ethylh
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A may be either a simple anion or t
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n 104 d Id 10 I 10-1 , a ,,81 0.1 M
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The fact that Pu(III) does not extr
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Fig. 25. Extraction of elements as
Page 63 and 64:
TABLE IV- 19. Distribution Coeffici
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10~ I ~ 0.01~ D 0.001 : 0,0001 . La
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loi- 1“’’’’’’’”1
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TABLE IV- 22. Extraction of Plutoni
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m * Amideb N, N-Dihexylformamide N,
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dependence on the TTA concentration
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1.0 D 0.1 —--L~,20 HNOO; CO&NT R
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cupferron, followed by back extract
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. more. Siekierski and Taube, 381 a
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TABLE IV- 27. Slope of the Dependen
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polymerization of the resin to prov
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co ; n 1000L z - 100 z o ~ m oL x z
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Volume distribution coefficient of
Page 89 and 90:
affinity of several ions was Th(IV)
Page 91 and 92:
95% of Pu(IV) was removed from a 0.
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2 d 1.0 I I I 1 I I 1 ,, , , I II r
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X“ 104 , 1 1 1 1 1 .— .-. I Ioa
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200 100 50 20 I O.10 ~ $ NPIX PUIIT
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Fig. 54. Adsorption of the elements
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Toribara et al. 403 used a liquid s
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V. DISSOLUTION OF PLUTON17JM SAMPLE
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m m TABLE VI- 30. Source Preparatio
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o 0 TAIIT.E VI-31. Techniques for M
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Solvent extraction of Pu into a liq
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TABLE VII-33. Basic Data for Critic
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Procedure No. 6. 7. 8. 9a, 9b , Aut
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Procedure 1. Determination of Pu in
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(e) (f) (g) (h) Where C v E The pre
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Procedure 2. Separation and determi
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Procedure 3. Separation and determi
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Procedure 4. Plutonium R. J. Morrow
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Procedure 5. Plutonium D. C, Hoffma
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Procedure m. Pipet tie samples (2~i
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Procedure 6. Separation of Plutoniu
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Procedure 7. Determination of Pu (R
Page 133 and 134:
Procedure 8. Uranium and Plutonium
Page 135 and 136: 15. Add 3 drops of HC1 and 1 drop o
Page 137 and 138: Procedure 9b. Separation of Plutoni
Page 139 and 140: Procedure 11. Uranium and Plutonium
Page 141 and 142: Procedure 12. Plutonium from Enviro
Page 143 and 144: 9. 10. 11. 12. 13. 14. 15. 16. 17.
Page 145 and 146: 10. 11. 12. 13. 14. 15. 16. 17. 16.
Page 147 and 148: Procedure 14. Separation of Plutoni
Page 149 and 150: Procedure 15. Separation of Pu befo
Page 151 and 152: Procedure 16. Separation of Plutoni
Page 153 and 154: Appendix (m) (n) (o) (P) Purificati
Page 155 and 156: Procedure 17. Separation of Np and
Page 157 and 158: Procedure 19. Determination of Plut
Page 159 and 160: NOTE: Reporting Results Results are
Page 161 and 162: Notes .. 1. 2. 3. The element prase
Page 163 and 164: 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13
Page 165 and 166: Procedure 22. Determination of Amer
Page 167 and 168: concentrated nitric acid in a block
Page 169 and 170: Preparation of Sample The 24-hr or
Page 175 and 176: “The Actinide Elements” (McGraw
Page 177 and 178: 48. D. H. Boase, J. K. Foreman, and
Page 179 and 180: 108. 109. 110. 111. 112. 113, 114.
Page 181 and 182: 159. 160. 161. 162. 163. 164. 165.
Page 183 and 184: 217. W. E. Keder, J. Inorg. Nucl. C
Page 185: 279. 280. 281. 282. 283. 284. 285.
Page 189 and 190: 397. 398. 399. 400. 401. 402. 403.
Page 191 and 192: 451. C. E. Honey, Jr., R. N. R. Mul
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