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CHEM01200604004 Shri Sanyasinaidu Boddu - Homi Bhabha ...

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Eu 3+ ions after heat treatment at 500°C.<br />

Fig.35:<br />

XRD patterns of β-Ga 2 O 3 doped with 0, 0.75, 1, 3 and 5 at % of Eu 3+ (peak<br />

marked * correspond to Eu 2 O 3 ). Values in brackets show average crystallite size<br />

Fig.36: TEM images of (a) 0, (b) 0.75, (c) 3 and (d) 5 at % Eu doped β - Ga 2 O 3<br />

Fig.37: (a) Emission spectra, (b) decay curve corresponding to 5 D 4 level of Tb 3+ in Tb 3+<br />

doped GaOOH, α-Ga 2 O 3 and β-Ga 2 O 3 nanomaterials. (λ exc = 255 nm and λ em =<br />

544 nm).<br />

Fig.38: (a) Emission spectra of β-Ga 2 O 3 nanomaterials doped with 0, 0.5, 1 and 2 at %<br />

Tb 3+ ions. The corresponding excitation spectra for 1 at % Tb 3+ doped sample,<br />

monitored at 460 and 544 nm emission, are shown in Fig. 38 (b).<br />

Fig. 39: Decay curves corresponding to excited state of the host emission of β-Ga 2 O 3<br />

nanomaterials doped with 0, 0.5, 1 and 2 at % Tb 3+ ions.<br />

Fig.40:<br />

Emission spectrum (a) obtained after 260 nm excitation and excitation<br />

spectrum (b) corresponding to 575 nm emission from β-Ga 2 O 3 :Dy 3+<br />

nanomaterials. Corresponding emission (λ exc = 280 nm) and excitation (λ em =<br />

613 nm) spectrum from Ga 2 O 3 :Eu nanorods are shown in Fig.40 (c and d).<br />

Fig.41:<br />

(a) Emission spectrum and (b) excitation spectrum from Ga 2 O 3 :Er 3+ nanorods.<br />

The excitation and emission wavelengths are 380 and 1535 nm, respectively.<br />

Fig. 42:<br />

XRD pattern of (a) Sb 2 O 3 sample prepared at room temperature in isopropanol<br />

medium. Corresponding patterns from the samples heated at 100, 200 and 400°C<br />

along with bulk Sb 2 O 3 are shown in (b)–(e), respectively.<br />

Fig.43:<br />

(a and b) AFM images showing the nanorods of Sb 2 O 3 at two representative<br />

regions of the sample. TEM and SAED images for the nanorods along with that<br />

of bulk sample are shown in (c)–(f), respectively<br />

Fig. 44: Emission spectra of (a) Sb 2 O 3 nanorods and (b) bulk Sb 2 O 3 as a function of<br />

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