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FOUNDATIONS OF QUANTUM MECHANICS

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24 CHAPTER II. THE FORMALISM<br />

A set of projectors P 1 , . . . , P N is called mutually orthogonal if<br />

P i P j = δ ij P i for i, j = 1, . . . , N, (II. 42)<br />

a set of mutually orthogonal projectors is called complete if<br />

N∑<br />

P i = 11. (II. 43)<br />

i=1<br />

In particular, in accordance with (II. 19), for an orthonormal basis |α i ⟩, . . . , |α N ⟩ it holds that the<br />

associated 1 - dimensional projectors form a complete set,<br />

N∑<br />

|α i ⟩ ⟨α i | = 11. (II. 44)<br />

i=1<br />

II. 3<br />

EIGENVALUE PROBLEM AND SPECTRAL THEOREM<br />

If |β 1 ⟩, . . . , |β N ⟩ is an arbitrary orthonormal basis, an operator A is represented in this basis as<br />

an arbitrary N × N - matrix,<br />

A ij = ⟨β i | A | β j ⟩. (II. 45)<br />

A powerful tool for the study of such matrices is obtained if they can be ‘diagonalized’, i.e., if an<br />

orthonormal basis |α 1 ⟩, . . . , |α N ⟩ can be found where the matrix representation of A is of the form<br />

⎛ ⎞<br />

a 1<br />

A = ⎝ . ..<br />

0<br />

⎠ , (II. 46)<br />

0 a N<br />

or, equivalently,<br />

A ij = a j δ ij . (II. 47)<br />

For such a basis it holds that<br />

A |α i ⟩ = a i |α i ⟩. (II. 48)<br />

Equation (II. 48) is called the eigenvalue equation of the operator A, the values a i are called the<br />

eigenvalues of A, the set of eigenvalues of A the spectrum of A, written as Spec A, the vectors |α i ⟩<br />

are called the eigenvectors, and the system |α 1 ⟩, . . . , |α N ⟩ an eigenbasis of A. For a self - adjoint<br />

operator it holds that the eigenvalues are all real, and the eigenvalues are not negative if the operator<br />

is positive. For a unitary operator U all eigenvalues u i ∈ C are on the complex unit circle, |u i | = 1,<br />

for a projector the eigenvalues are 0 or 1.<br />

The eigenvalue equation does, however, not always have a solution. See as an example operator<br />

(II. 29). The conditions under which the equation can be solved are given by the next important<br />

theorem which we mention without proof.

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