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Alternatives for Brominated Flame Retardants - Miljøstyrelsen

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lected based in the name or CAS number of the suggested compound. There<strong>for</strong>e,<br />

a precise match of name and number is required and as shown in the<br />

table above a poor availability of data is not uncommon. However, if the<br />

compound is a slight modification of another compound or belongs to a<br />

family of related compounds it is possible that useful in<strong>for</strong>mation can be<br />

obtained by searching <strong>for</strong> in<strong>for</strong>mation on such compounds in a more comprehensive<br />

project (e.g. in the case of quinidine carbonate).<br />

Several of the inorganic compounds are salts of metals and may dissociate in<br />

the hydrosphere. To some extent the lack of data on the selected compounds<br />

may be ameliorated by using data on the parent metal. In the case of zinc<br />

borate this is, however, somewhat complicated since both zinc and boric<br />

acid may contribute to the combined toxicity.<br />

The type of data that are missing varies between compound. Typically<br />

missing data on the environment side are biodegradation data and bioaccumulation<br />

data. On the health side a less clear pattern is observed.<br />

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The available data indicate that the triphenyl and tricresyl phosphates may<br />

have low impact on health, but are quite toxic in the environment. Poor data<br />

availability <strong>for</strong> the structurally related resorcinol prohibits conclusions regarding<br />

the effect pattern.<br />

For this compound only very few data was identified. The phosphonic acid<br />

(dimethyl ester) appears acutely toxic at 13 mg/kg bodyweight in rats and<br />

mutagenic effects has been reported. A <strong>for</strong>mulation of the compound was<br />

lethal to fish (LC 50 ) at approx. 1 ml/l (density unknown).<br />

The data sets on these compounds are relatively limited. It appears that limited<br />

toxic effects can be induced in mammals after exposure to high doses.<br />

Aluminium trihydroxide is generally not toxic in the available tests. Both<br />

metal-ions play a metabolic role in mammals, but the data <strong>for</strong> the metal-ions<br />

indicates acute toxic levels <strong>for</strong> Al to fish and crustaceans at

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