List of <strong>Abstracts</strong> 129Contact: jeremy.vouzelaud@aero.obs-mip.frNO y species play a major role in the tropospheric chemistry by controlling ozone. In the upper troposphere,NO y is principally emitted on the form of NO x through aircraft, surface emissions, stratospheric intrusionsand lightning activity. This study aims to discriminate lightning emissions and to evaluate their influence onthe NO y and O 3 distributions over the northern midlatitudes. We use 5 years (2001-2005) of aircraftobservations (NO y , CO, O 3 , Relative Humidity) from the MOZAIC program, ground based and satelliteobservations of clouds (GOES, METEOSAT) and lightning (LIS, NLDN, ATD), combined with systematicsimulations of the FLEXPART model, in order to assess the location of NO x sources and to quantifylightning activity and the main transport agents driving NO y and O 3 distributions. During fall and winterlightning emissions are generally characterised by low NO y /CO correlation, with NO y values higher than 1ppbv and low CO. In one case sampled over the Atlantic, mean NO y (0.70 ppbv) and CO (83 ppbv)concentrations were associated with lightning activity over the Gulf of Mexico, 72 hours prior to themeasurements, with more than 80.000 CG flashes. During summer, most of the large-scale plumes with highNO y are associated with lightning NO x emissions and pollution. Nevertheless, during July 2003, a 1000 kmzonal plume influenced by clean convection was observed over the Atlantic (87 ppbv of CO, 90 ppbv. of O 3 ,2.1 ppbv of NO y ), associated with lightning activity over the Gulf of Mexico with more than 100.000 flashesone to four days before the observation. Based on the observations, transport and lightning activityproperties, we estimate the NO y and O 3 produced for each episode. It is finally expected that the outcome ofsuch an exploitation of the MOZAIC records will serve as a basis to build a comprehensive climatology ofNO y in the upper troposphere.P-Transformation.14 ID:4168 10:30Record of Concentration, δ¹³C and δ¹⁸O of Atmospheric CO over the last millennium from AntarcticIce CoresZhihui Wang 1 , Jérôme Chappellaz 2 , Mak John 11 State University of New York at Stony Brook2 Laboratoire de Glaciologie et Géophysique de l'EnvironnementContact: zhihui.wang@stonybrook.eduA record of preindustrial biomass burning over the past ~650 years in the extratropical Southern Hemisphereis derived from the carbon monoxide (CO) isotope record based on new measurements of CO concentration,δ¹³C, and δ¹⁸O from 40 Antarctic ice core samples covering the time period from 1360 to 1900. COconcentration decreases by ~25% (14 ppbv) from 1360 to around 1600, then recovers completely from 1700to the late 1800s, followed by a very slight decrease by 2000. δ¹³C and δ¹⁸O of CO decrease by about 2‰and 4‰ respectively from 1360 to 1600, then increase by about 2.5‰ and 4‰ respectively frompreindustrial times to the late 1800s. Present day values of both isotopic ratios are close to those observedduring the 1600s. Based on these observations, we conclude that biomass burning strongly modulated theCO budget during preindustrial times and decreased significantly from the early 20th century to the presentday. This decrease was nearly compensated by the concomitant methane increase, which is an isotopicallydepleted source of atmospheric CO, bringing present day CO concentrations close to its maximum levelobserved over the last 650 years.iCACGP-<strong>IGAC</strong> 2010 14 July, 2010
List of <strong>Abstracts</strong> 130P-Transformation.15 ID:4289 10:30In Situ Spectral Study Of Ozone Hydrates Formation And Their Reaction With Chlorine-containingCompounds Under Stratospheric ConditionsSerguei Savilov, Tatiana Yagodovskaya, Tatiana Vysokhih, Natalia Strokova, Valery LuninContact: savilov@chem.msu.ruOzone is one of the unique chemical substances: at the same time it demonstrates favorable and harmfulactivity on the people’s life, along with easiness of decomposition its amount in the Earth’s atmosphere isreasonable. Nevertheless chemistry of ozone up to date is not investigated totally. Only few literature dataconcern ozone hydrates: they are supposed to belong to type II clathrates with (H2O/O3) ratio equal to 5.75.The experiments on the laboratory simulation of heterogeneous chemical processes were carried out with theuse of vacuum flowing gas-discharged device under stratospheric conditions. Ozone was synthesized fromthe purified oxygen in gas-discharge tube and trapped at liquid nitrogen temperature. Thin reactant filmswere produced on the thermostated gold reaction mirrors of the specially designed grazing angles reflectioncuvette under 10-4 torr and 77K. Reactions were studied at 77K-290K by FTIR spectroscopy at 1 cm-1resolution. Outgoing gases were fixed by time-of-flight mass spectrometer. Spectrum of thin ice filmcovered by ozone at 77K consisted of vibration bands of H2O, O3 and H-bonds in adsorbed state. Growth oftemperature to 85K lead to increasing of ozone bands (660, 678, 1036, 1264, 1300 cm-1) and H-bonds,especially 2107 cm-1. New absorption lines at 704, 1001, 1106, 2045 and strong doublet 2350-2380, 2784см-1 were also observed. The substance formed did not react with HCl untill 220K, while normally reactionof HCl, adsorbed on the ice film, with ozone takes please at 77K. This fact point out on formation of gasclathrate hydrate which decompose only at temperatures higher than 220K. Its reactions with CHCl3 andCHBr3 were studied also. Thus, the present work show the possibility of ozone hydrates formation understratospheric conditions.P-Transformation.16 ID:4485 10:30Production and Transport of Ozone in the Amazon: Comparison of WRF-Chem and CCATT-BRAMS Simulations with In-Situ Observations from the BARCA CampaignMegan Bela 1 , Karla Longo 1 , Saulo Freitas 2 , Veronika Beck 3 , Demerval Moreira 2 , Kenia Wiedemann 4 ,Paulo Artaxo 4 , Niklas Juergens 5 , Meinrat Andreae 5 , Steven Wofsy 61 National Institute for Space Research (INPE), São José dos Campos, Brazil2 National Institute for Space Research (INPE), Cachoeira Paulista, Brazil3 Max Planck Institute for Biogeochemistry, Jena, Germany4 Institute of Physics, University of São Paulo, Brazil5 Biogeochemistry Department, Max Planck Institute for Chemistry, Mainz, Germany6 Harvard UniversityContact: meganbela@gmail.comIn the Amazon Basin, biogenic, biomass burning, and urban emissions react photochemically to produceozone, which is then transported by convection and regional circulations. As the Amazon basin becomesincreasingly populated and developed for agriculture, the ability to predict regional ozone distributions willbe critical to mitigating pollution that harms human health, agriculture, and natural ecosystems. However,major uncertainties remain in characterizing emissions, photochemical processes and pollutant transport inthe Amazon basin. In this study, basin-wide CO and O3 aircraft measurements taken during theLBA/BARCA campaign during the dry-to-wet transition of 2008 are used to evaluate the WRF-Chem andCCATT-BRAMS coupled chemistry and meteorology models, constrain emissions and analyze ozonebudgets in the Amazon. The WRF-Chem (Weather Research and Forecasting with Chemistry) modeliCACGP-<strong>IGAC</strong> 2010 14 July, 2010
- Page 2 and 3:
List of Abstracts 1Plenary.1 ID:459
- Page 4 and 5:
List of Abstracts 3Chemistry-Climat
- Page 6 and 7:
List of Abstracts 5Chemistry-Climat
- Page 8 and 9:
List of Abstracts 7correlations are
- Page 10 and 11:
List of Abstracts 9P-Sources.2 ID:4
- Page 12 and 13:
List of Abstracts 11P-Sources.6 ID:
- Page 14 and 15:
List of Abstracts 13calculation of
- Page 16 and 17:
List of Abstracts 15P-Sources.13 ID
- Page 18 and 19:
List of Abstracts 17emissions made
- Page 20 and 21:
List of Abstracts 19modeling techni
- Page 22 and 23:
List of Abstracts 21than true uncer
- Page 24 and 25:
List of Abstracts 23affect regions
- Page 26 and 27:
List of Abstracts 25P-Sources.31 ID
- Page 28 and 29:
List of Abstracts 27An inverse mode
- Page 30 and 31:
List of Abstracts 29transport of CO
- Page 32 and 33:
List of Abstracts 31in the levels o
- Page 34 and 35:
List of Abstracts 33P-Sources.46 ID
- Page 36 and 37:
List of Abstracts 35Reductions in b
- Page 38 and 39:
List of Abstracts 37P-Sources.53 ID
- Page 40 and 41:
List of Abstracts 39includes emissi
- Page 42 and 43:
List of Abstracts 41will be present
- Page 44 and 45:
List of Abstracts 43parameterizatio
- Page 46 and 47:
List of Abstracts 45measurements an
- Page 48 and 49:
List of Abstracts 47Multiphase halo
- Page 50 and 51:
List of Abstracts 49be explained by
- Page 52 and 53:
List of Abstracts 51Contact: tzhu@p
- Page 54 and 55:
List of Abstracts 53particle-resolv
- Page 56 and 57:
List of Abstracts 551 University of
- Page 58 and 59:
List of Abstracts 57Contact: visahi
- Page 60 and 61:
List of Abstracts 59Weather and cli
- Page 62 and 63:
List of Abstracts 61on the global M
- Page 64 and 65:
List of Abstracts 63will be compare
- Page 66 and 67:
List of Abstracts 65P-Chemistry Cli
- Page 68 and 69:
List of Abstracts 67P-Chemistry Cli
- Page 70 and 71:
List of Abstracts 69have included s
- Page 72 and 73:
List of Abstracts 71Contact: bumiya
- Page 74 and 75:
List of Abstracts 73particle, chang
- Page 76 and 77:
List of Abstracts 75P-Chemistry Cli
- Page 78 and 79:
List of Abstracts 77of the rain bel
- Page 80 and 81: List of Abstracts 79Community Atmos
- Page 82 and 83: List of Abstracts 81climate conditi
- Page 84 and 85: List of Abstracts 835 IMK, Karlsruh
- Page 86 and 87: List of Abstracts 85P-Observations
- Page 88 and 89: List of Abstracts 87P-Observations
- Page 90 and 91: List of Abstracts 89We have previou
- Page 92 and 93: List of Abstracts 91particles, from
- Page 94 and 95: List of Abstracts 933 Department of
- Page 96 and 97: List of Abstracts 95also from agric
- Page 98 and 99: List of Abstracts 97P-Observations
- Page 100 and 101: List of Abstracts 99P-Observations
- Page 102 and 103: List of Abstracts 101(WMO, Geneva),
- Page 104 and 105: List of Abstracts 103START-08 campa
- Page 106 and 107: List of Abstracts 105frequency of t
- Page 108 and 109: List of Abstracts 107Observations 2
- Page 110 and 111: List of Abstracts 109Interfaces 1.1
- Page 112 and 113: List of Abstracts 1111 Met Office H
- Page 114 and 115: List of Abstracts 113year are almos
- Page 116 and 117: List of Abstracts 115transport mode
- Page 118 and 119: List of Abstracts 117of carbon mono
- Page 120 and 121: List of Abstracts 119Plenary 3 ID:4
- Page 122 and 123: List of Abstracts 121In this study,
- Page 124 and 125: List of Abstracts 123both microphys
- Page 126 and 127: List of Abstracts 1251 University o
- Page 128 and 129: List of Abstracts 127humidities bet
- Page 132 and 133: List of Abstracts 131developed at N
- Page 134 and 135: List of Abstracts 133P-Transformati
- Page 136 and 137: List of Abstracts 135We will presen
- Page 138 and 139: List of Abstracts 137airborne data
- Page 140 and 141: List of Abstracts 139P-Transformati
- Page 142 and 143: List of Abstracts 141on the identif
- Page 144 and 145: List of Abstracts 143P-Transformati
- Page 146 and 147: List of Abstracts 145P-Transformati
- Page 148 and 149: List of Abstracts 147hydrometeors a
- Page 150 and 151: List of Abstracts 149intercompariso
- Page 152 and 153: List of Abstracts 151P-Transformati
- Page 154 and 155: List of Abstracts 153P-Transformati
- Page 156 and 157: List of Abstracts 155radicals are t
- Page 158 and 159: List of Abstracts 157of the kinetic
- Page 160 and 161: List of Abstracts 159+ i-butanol) =
- Page 162 and 163: List of Abstracts 161km) covering t
- Page 164 and 165: List of Abstracts 163P-Observations
- Page 166 and 167: List of Abstracts 165number of gase
- Page 168 and 169: List of Abstracts 167the highest va
- Page 170 and 171: List of Abstracts 169range transpor
- Page 172 and 173: List of Abstracts 171P-Observations
- Page 174 and 175: List of Abstracts 173quality proble
- Page 176 and 177: List of Abstracts 175P-Observations
- Page 178 and 179: List of Abstracts 177the tropospher
- Page 180 and 181:
List of Abstracts 179masses and eva
- Page 182 and 183:
List of Abstracts 181P-Observations
- Page 184 and 185:
List of Abstracts 183P-Observations
- Page 186 and 187:
List of Abstracts 185P-Observations
- Page 188 and 189:
List of Abstracts 187OMI also measu
- Page 190 and 191:
List of Abstracts 189seasonal varia
- Page 192 and 193:
List of Abstracts 191P-Observations
- Page 194 and 195:
List of Abstracts 193climate.P-Obse
- Page 196 and 197:
List of Abstracts 195aerosols and c
- Page 198 and 199:
List of Abstracts 197Health Organiz
- Page 200 and 201:
List of Abstracts 199December 2008-
- Page 202 and 203:
List of Abstracts 201P-Observations
- Page 204 and 205:
List of Abstracts 203Contact: anls@
- Page 206 and 207:
List of Abstracts 205P-Observations
- Page 208 and 209:
List of Abstracts 207Temuco is a fa
- Page 210 and 211:
List of Abstracts 209context of Cen
- Page 212 and 213:
List of Abstracts 211P-Observations
- Page 214 and 215:
List of Abstracts 213addition to th
- Page 216 and 217:
List of Abstracts 215Ca, Cd, Cu, Fe
- Page 218 and 219:
List of Abstracts 217for the MBL co
- Page 220 and 221:
List of Abstracts 219and particulat
- Page 222 and 223:
List of Abstracts 2213 Princeton Un
- Page 224 and 225:
List of Abstracts 223Robinson, A.L.
- Page 226 and 227:
List of Abstracts 225Observations 4
- Page 228 and 229:
List of Abstracts 227minor contribu
- Page 230 and 231:
List of Abstracts 229linked to know
- Page 232 and 233:
List of Abstracts 231identified pse
- Page 234 and 235:
List of Abstracts 233Wake-up 1.1 ID
- Page 236 and 237:
List of Abstracts 235Wake-up 2.1 ID
- Page 238 and 239:
List of Authors 237Beck, Veronica .
- Page 240 and 241:
List of Authors 239Dann, Tom.......
- Page 242 and 243:
List of Authors 241Gioda, Adriana .
- Page 244 and 245:
List of Authors 243Keating, Terry .
- Page 246 and 247:
List of Authors 245Mao, Jingqiu....
- Page 248 and 249:
List of Authors 247Perri, Mark.....
- Page 250 and 251:
List of Authors 249Shank, Lindsey .
- Page 252 and 253:
List of Authors 251Van Donkelaar, A