List of <strong>Abstracts</strong> 215Ca, Cd, Cu, Fe, Mg, Mn, Mo, Ni, Pb, S, Sb, Sn, and Zn) was determined in the different sizes of the samples(A < 37 µm, 37< B < 55, 55< C < 75 and 75< D < 100). X-ray powder diffraction was selected to detectmajor components: minerals, silicate glass and sulphates. Individual mineral dust particles were analyzed bySEM- EDAX showing that sulphur tended to reside on the particles surface, while Al, Ca, Mg, K, Fe and Siwere all an integral part of the particles. Elements content was quantified by ICP OES in the four particlesize ranges. Special attention was paid to the determination of key traffic related elements (TRE´s): Cu, Mo,Pb, Ni, S, Sb and Zn. Concentrations of elements were averaged over the monitoring sites. Geologicalelements exhibited the higher concentrations: Fe (28-43 mg g-1) > Al (13-40 mg g-1) >> Ca (1.7-6.9 mg g-1), followed by Mg (2.5-5.5 mg g-1) > S (0.2-1.7 mg g-1). Concentrations pattern showed high variability inthe four fractions but in all cases, higher concentrations were detected in the smaller size fractions (A and B).The TRE´s concentrations (mg g-1) varied from < 0.3 (for Ni) to 1.53 (for Zn). The smallest size fractionwere particularly enriched in Sb > Cd > Cu which are of particular interest from the environmental andhuman health standpoint. To the best of our knowledge this is the first study devoted to the multielementalcharacterization of the Buenos Aires road dust.P-Observations 2.96 ID:4604 10:30WOODSMOKE SOURCE APPORTIONMENT AND HOME INFILTRATION STUDY IN THERURAL ANNAPOLIS VALLEY, NOVA SCOTIA, CANADAMark Gibson 1 , Tony J. Ward 2 , Amanda J. Wheeler 3 , Judy R. Guernsey 1 , Matt P. Seaboyer 1 , PatrickBazinet 1 , Gavin H. King 1 , Neil K. Brewster 1 , James Kuchta 1 , Adrian Macdonald 1 , Jenna Higgins 1 , RyanPotter 1 , Dave M. Steib 41 Atlantic RURAL Centre, Dalhousie University, Halifax, NS, Canada2 Center for Environmental Health Sciences, University of Montana, Missoula, Montana, USA3 Air Health Science Division, Health Canada, Ottawa, Ontario, Canada4 Healthy Environments and Consumer Safety Branch, Health Canada, Ottawa, Ontario, CanadaContact: mark.gibson@dal.caWoodsmoke has recently received increasing attention as an important source of particulate matter,particularly in rural areas. Indoor woodstoves and outdoor wood boilers are widely used in the AnnapolisValley, in rural Nova Scotia, and the area’s topography is conducive to trapping emissions especially duringthermal inversions. In an effort to quantify the impact of these factors on local air quality, the sourcecontribution of residential wood burning to ambient PM2.5 at one fixed site in the Annapolis Valley, wasanalyzed during the winter 2008/2009 (phase 1). 4 x 24-hr PM2.5 filters, continuous PM2.5 using TSI Inc.Dust Traks, and associated gases (VOC, NO2, O3) were measured over 50 days between 24 February 2009and 7 May 2009 near the town of Middleton, located in the longitudinal centre of the Annapolis Valley. ThePM2.5 chemical species analyzed included levoglucosan (woodsmoke marker), elements, ions, C14(confirmatory marker for woodsmoke), organic and elemental carbon. g m-3 observed fromµThere werenumerous short-term excursions over 100 PM2.5 Dust Trak measurements. There was no significantdifference (P = 0.524) between the Dust Trak PM2.5 and Dust Trak PM10 concentrations suggesting that thePM10 size fraction was dominated by PM2.5. Chemical Mass Balance (USEPA CMB v8.2/SPECIATEv4.2) conducted on 16 of the 50 PM2.5 samples thus far yielded an average source contribution of residentialwoodsmoke to the total PM2.5 concentration of 56.2% (range 32.6% – 73%), with 12.4 % NH4NO3 (range5.0% - 20%), 24.1% SO4 (range 11.0% - 47%), 9.2% (NH4)2SO4 (range 2% - 19.8%), 3.9% unknown mass(range 0.6% - 14%) with no CMB statistically significant input from vehicle emissions. In phase 2 of thestudy, an investigation of woodsmoke home infiltration in 30 homes was conducted during winter2009/2010, together with an evaluation of the effectiveness of electrostatic air cleaners at reducing indoorPM2.5 concentrations. Significant (P
List of <strong>Abstracts</strong> 216P-Observations 2.97 ID:4358 10:30Trends in wet deposition in South AfricaElne Conradie 1 , Kobus Pienaar 1 , Paul Beukes 1 , Pieter Van Zyl 1 , Gabi Mkhatshwa 2 , Gerhard Fourie 3 ,Corinne Galy-Lacaux 41 North-West University, South Africa2 Eskom Holdings, Resources and Strategy Division, Rosherville, Johannesburg, South Africa3 Sasol Technology Research and Development, Sasolburg, South Africa4 Laboratoire d’Aérologie 14, Av. Edouard Belin 31 400 Toulouse, FranceContact: 12407690@nwu.ac.zaPotential adverse environmental impacts due to increased anthropogenic emissions into the atmospherenecessitate the execution of long-term atmospheric deposition programmes. Atmospheric deposition ofemitted chemical species back to the earth’s surface through wet and dry processes plays an important role incontrolling the concentrations of pollutants present in the troposphere. Deposited species can provideessential nutrients to ecosystems or can cause disturbances. Deposition of chemical species was measured atselected sites in southern Africa during the DEBITS (Deposition of Biogeochemical Important TraceSpecies) programme. The study of the chemical composition of rain (wet deposition) is essential to trace thetemporal and spatial evolution of atmospheric chemistry.Earlier collection of rainwater utilising wet-only samplers was conducted at Louis Trichardt and Amersfoortfrom 1986 until 1999 and at Skukuza during the period of 1999-2002. Collection of rain water at these sitesrecommenced in 2008 and is still ongoing. The study area is classified as semi-arid savannah. Skukuza,which is situated in the Kruger National Park and Louis Trichardt situated in the Limpopo Province areconsidered to be background and rural sites, while Amersfoort represent industrial activity in theMpumalanga Highveld. Back trajectory analysis of the region further indicate that air mass originating fromthe Mpumalanga Highveld Industrial region are circulated over the sites at Skukuza and Louis Trichardt,impacting these sites with no significant local emission sources.The most important inorganic and organic ions present in the collected rainwater samples were determinedwith an ion chromatograph. The chemical composition of the rainwater samples collected at each of the sitesfor the various sampling periods was compared. The variation in concentrations for each of the measuredchemical species over the sampling periods and the observed changes in trends are reported.P-Observations 2.98 ID:4348 10:30Atmospheric nucleation in the eastern Mediterranean marine boundary layerNikos Kalivitis 1 , Iasonas Stavroulas 1 , Aikaterini Bougiatioti 1 , Giorgos Kouvarakis 1 , Stéphanie Gagné 2 ,Hanna E. Manninen 2 , Markku Kulmala 2 , Alfred Wiedensohler 3 , Nikolaos Mihalopoulos 11 ECPL, Department of Chemistry, University of Crete, Greece2 Department of Physics, University of Helsinki, Finland3 Leibniz-Institute for Tropospheric Research, Leipzig, GermanyContact: nkalivitis@chemistry.uoc.grAtmospheric nucleation has been reported to take place in varying locations and environments worldwide.Most of the observations were made during daytime, suggesting that photochemical processes play a keyrole in new particle formation mechanisms. Night-time observations have so far been scarce in literature andnone of them refers to the marine boundary layer (MBL). At the environmental research station of theUniversity of Crete at Finokalia, Crete (35˚20΄N, 25˚40΄E, 250 a.s.l) measurements of atmospheric aerosolproperties were performed during the period April 2008 – April 2009. The site is considered representativeiCACGP-<strong>IGAC</strong> 2010 14 July, 2010
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- Page 238 and 239: List of Authors 237Beck, Veronica .
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