List of <strong>Abstracts</strong> 165number of gases including Carbonyl Sulfide.P-Observations 2.5 ID:4461 10:30Pilot Study Preliminary Results for a Marine Boundary Layer Site near Ucluelet on Vancouver IslandCorinne Schiller, Roxanne Vingarzan, Keith Jones, Anne Marie Macdonald, Richard LeaitchEnvironment CanadaContact: Corinne.Schiller@ec.gc.caA one year pilot study is taking place from April 2010 to April 2011 on the west coast of Vancouver Islandto determine its feasibility as a Marine Boundary Layer (MBL) site. The MBL site is located at AmphitritePoint on Vancouver Island (48.9217, -125.5411) at an elevation of about 20 meters above sea level. Due tothe Beaufort Mountain range bisecting Vancouver Island from NW to SE, the winds in the region arepredominantly parallel to the island or WNW in the summer and ESE in the winter. Back trajectories showthat transpacific air should impact the site on the majority of days with typical meteorological patterns.Occasionally air reaching the site may be impacted by the Seattle area or the Vancouver area. Measurementsat the site include particulate as well as gas samples. Preliminary data from the spring 2010 will bepresented.P-Observations 2.6 ID:4292 10:30Characterisation of the Cape Verde Observatory's air mass origin and chemistry using the NAMEdispersion modelZoë Fleming 1 , Paul Monks 2 , Roland Leigh 3 , Katie Read 4 , Lucy Carpenter 5 , Luis Mendes 61 National Centre for Atmospheric Science, University of Leicester, UK2 Department of Chemistry, University of Leicester, UK3 Earth Observation Science, Department of Physics & Astronomy, University of Leicester, UK4 National Centre for Atmospheric Science, Department of Chemistry, University of York, UK5 Department of Chemistry, University of York, UK6 Instituto Naçional de Meteorologia and Geofisca (INMG), Delegação de São Vicente, Cape VerdeContact: zf5@le.ac.ukThe UK Met office’s NAME atmospheric dispersion model has been used to develop station footprints forthe Humberto Duarte Fonseca WMO Global Observatory on the Cape Verde islands in the Atlantic Ocean.The model output has been run every 3 hours over a period of three years, tracking air mass origin over theprevious 10 days. The most common air mass trajectories types have been identified and each back run wasassigned to one trajectory type.The long term trace gas measurements at Cape Verde from the past three and a half years were used tocalculate an average composition (of O3, NO2, CO, CN, VOCs etc.) for each type of trajectory over thewhole period. Saharan dust episodes are particularly common at the station during the winter months but airfrom the coastal areas just off the African continent are the main route to the islands all year round. Many airmasses originate from North America or from Europe a few days before and tracking the pollutant loadingsof these gives us an idea of the extent of the oxidation that occurs during transport. This seasonal andgeographical characterisation of the chemistry of the air masses arriving at the Cape Verde islands canelucidate the long term pathways and transformations of pollution across the Atlantic Ocean.iCACGP-<strong>IGAC</strong> 2010 14 July, 2010
List of <strong>Abstracts</strong> 166P-Observations 2.7 ID:4406 10:30Chemical composition of aerosols in a tropical region considering the influence of local and longdistance transport of pollutantsAdriana Gioda, Beatriz Silva AmaralPontifical Catholic UniversityContact: agioda@puc-rio.brAerosols can affect the climate by changing the way radiation is transmitted through the atmosphere. Directobservations of aerosols are quite limited, making any attempt to estimate their global effect difficult. Due tothe uncertainties of aerosol radiative forcing measurements around the world, especially in SouthernHemisphere tropical regions, to a better estimate of their effects is necessary. The objective of this study is todetermine the chemical composition of aerosol samples collected in the Rio de Janeiro metropolitan area,under the influences of different local (natural, industrial and traffic) and long-range transport. The aerosolsamples were collected for one year (2008-2009). Concentration levels of aerosols, metals, water- solubleions, and soluble organic and nitrogen fractions were measured. Preliminary results showed that the meanaerosol concentrations were 36 µg/m3; 50 µg/m3 and 74 µg/m3 at the natural, downtown and industrial sites,respectively. An increase in the average particle concentrations was observed in the period from May toSeptember probable due to air stagnation increasing pollutant concentrations. Average concentrations ofanions were 1.7 µg/m3 for Cl-, 2.7 µg/m3 for NO3-, 2.5 µg/m3 for SO4= and for cations were 2.9 µg/m3 forNa+, 1.0 µg/m3 for Ca++, 0.3 µg/m3 for K+ and Mg++. Low levels of NH4+ and organic acids (0.04-0.10µg/m3) were measured. Average water-soluble organic compounds (WSOC) were detected in similarconcentrations to the main ions species (2.1 µg/m3). The studied species concentrations are influenced by thesite locations. At the natural site, lower concentrations of NO3- and SO4= were detected as well as when airmasses came from the ocean. According to satellite images, Saharan dust reached the sampling sites,increasing from two to five times aerosols, Ca2+and K+ concentrations. This is the first study reporting theincrease of some aerosol species in Rio de Janeiro due to African outbreaks. Other results of nitrogencompounds and metals will be presented at the meeting.P-Observations 2.8 ID:4306 10:30Dry deposition of trace elements in central IndiaMadhuri Rajak 1 , K.S. Patel 1 , G. Agnihotri 1 , W. Corns 2 , B. Chen 2 , B. Blazhev 3 , E. Yubero 4 , J. Nicolás 41 School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur-492010, India2 PS Analytical Ltd, Arthur House, Unit 3 Crayfields Industrial Estate, Orpington, Kent, BR5 3HP, UK3 Central Laboratory for Chemical Testing and control, 1330-Sofia, Bulgaria4 Atmospheric Pollution Laboratory, Applied Physics Department, Miguel Hernandez University, Avda de lContact: analrsu@sify.comThe vast industrialization and urbanization result in substantial increase of the aerosol concentration in urbansites of India. The aerosol concentration is reached maximum in the winter season (December/January) of ayear with serious environmental and health hazards. The nature of atmospheric deposition reflects the qualityof water and precipitates. Therefore, thirteen resuspended dust deposited in the roof of building of Raipurcity (capital of Chhattisgarh state, India) from the residential(Re), commercial(Co) and industrial(In) siteswere collected in January, 2009. The dust of mesh size ≥ 0.1 mm was sieved out. The concentration of traceelements and ions in dust were determined. The metals i.e. Al, Fe and Mn showed the highest concentration,ranged from 2.6 – 4.0, 5.2 – 12.4 and 0.3 – 9.5% with mean value of 3.0±0.2, 9.2±1.3 and 1.9±1.6%,respectively at 95% probability. Similarly, the concentration of Cr, Ni, Cu, Zn, Cd and Pb is ranged from 54– 527, 25 – 172, 37 – 157, 72 – 408, 63 – 251 and 0.10 – 0.91 mg kg-1 with mean value of 127±68, 49±21,74±19, 275±48, 115±30 and 0.29±11 mg kg-1, respectively. Four metals i.e. Fe, Mn, Zn and Cd exhibitediCACGP-<strong>IGAC</strong> 2010 14 July, 2010
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List of Authors 237Beck, Veronica .
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