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A study of the priority substances of the Water Framework Directive ...

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Marine sediment<br />

The levels <strong>of</strong> nickel in marine sediments are generally<br />

low. Sediments outside Falconbridge have<br />

higher nickel loading, "tilstandsklasse IV" in<br />

Hanevika, outside Falconbridge.<br />

Marine biota<br />

The nickel levels in fish are relatively low.<br />

Fresh water<br />

Nickel has been monitored in rivers. Levels are<br />

generally low, <strong>the</strong> highest samples were Class II.<br />

Fresh water sediment<br />

Nickel levels in fresh water sediments are generally<br />

low, but increasing with latitude. Åsterudtjernet<br />

in Ringerike in Buskerud County and<br />

Vollevatnet in Kristiansand in Vest-Agder<br />

County have significantly higher concentrations.<br />

These are affected by mining and Falconbridge<br />

respectively.<br />

Fresh water biota<br />

There are generally low levels <strong>of</strong> nickel in fresh<br />

water biota.<br />

Need for fur<strong>the</strong>r screening and monitoring<br />

There is no fur<strong>the</strong>r need for screening <strong>of</strong> nickel<br />

and its compounds.<br />

Analysis<br />

There are several well-established techniques for<br />

determination <strong>of</strong> Ni. Several companies <strong>of</strong>fer<br />

this service in Norway and Europe. The most<br />

common techniques are Inductively coupled<br />

plasma mass spectrometry (ICP-MS), Inductively<br />

coupled Plasma Atomic Emission Spectroscopy<br />

(ICP-AES), Graphite Furnace Atomic<br />

Absorption Spectroscopy (GF-AAS) and Flame<br />

Atomic Absorption Spectroscopy (F-AAS).<br />

Methods<br />

<strong>Water</strong> samples are acidified with 1-10% nitric<br />

acid.<br />

For analysis <strong>of</strong> solid samples, <strong>the</strong> methods are<br />

based on digestion with nitric acid/hydrogen<br />

peroxide in sealed containers using microwave<br />

system.<br />

nickel and nickel compounds ::::::::::..<br />

Synergy with o<strong>the</strong>r analyses<br />

The sample digestion method used for determination<br />

<strong>of</strong> nickel can also be used for determination<br />

<strong>of</strong> Pb, Hg, Zn, Cr, As and Cu.<br />

References<br />

� CIRCA: Fact sheets on production, use and<br />

release <strong>of</strong> <strong>priority</strong> <strong>substances</strong> in <strong>the</strong> WFD, Royal<br />

Haskoning 31 December 2003. NICKEL.<br />

� ClassLab: Nikkel.<br />

� HSDB: Nickel.<br />

� WHO: International programme on chemical<br />

safety. Environmental health critera108; NICK-<br />

EL.<br />

� SFT Miljøgifter i produkter Data for 2002.<br />

� Fylkesvise tiltaksplaner for forurensede sedimenter,<br />

Rapport fra fase 1 for Farsundsområdet<br />

med Lyngdalsfjorden, Vest-Agder.<br />

� Miljøovervåkning i Sandefjordsfjorden og<br />

indre Mefjorden, 1997-1998. Delrapport 2.<br />

Miljøgifter i sedimenter. TA-1585/1998.<br />

� Sonderende undersøkelser i norske havner og<br />

utvalgte kystområder. Fase 3. Miljøgifter i sedimenter<br />

på strekningen Ramsund-Kirkenes. TA-<br />

1215/1995.<br />

� Miljøgifter i havneområder i Nordland, TA-<br />

1967/2003.<br />

� Riverine inputs and direct discharges to<br />

Norwegian coastal waters - 2003. Part B: Data<br />

report.<br />

� Heavy metals and persistent organic pollutants<br />

in sediments and fish from lakes in<br />

Nor<strong>the</strong>rn and Arctic regions <strong>of</strong> Norway, rapportnr.<br />

688/97.<br />

� Regional undersøkelse av miljøgifter i<br />

innsjøsedimenter. Delrapport 2. Tungmetaller og<br />

andre sporelementer. Rapportnr. 713/97.<br />

� Miljøgifter og radioaktivitet i norsk fauna -<br />

inkludert Arktis og Antarktis, utredning for DN<br />

nr. 1999-5<br />

A <strong>study</strong> <strong>of</strong> <strong>the</strong> <strong>priority</strong> <strong>substances</strong> <strong>of</strong> <strong>the</strong> <strong>Water</strong> <strong>Framework</strong> <strong>Directive</strong><br />

TA-2140/2005<br />

59:::..

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