Historical Painting Techniques, Materials, and Studio Practice
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
elonged to William Mallord Turner (Fig. 4) . It contained seventeen bladders<br />
of solidified oil paint, all of which had been opened <strong>and</strong> sealed with a tack.<br />
Each was labeled in German or English. Two were named as Gebr. Terra di<br />
Verte <strong>and</strong> Gebr. Grune Erde, the term "Gebr." coming from the German<br />
gebrannte for burnt or roasted (24).<br />
EDXRF analysis of the paint on the surface of the bladders showed iron to<br />
be the major constituent with traces of manganese <strong>and</strong> titanium. The Terra<br />
di Verte contained a trace of calcium, the Griine Erde considerably more<br />
with traces of potassium, rubidium, <strong>and</strong> strontium (frequently present in calcium<br />
deposits). Green earth is a complex silicate colored by iron with a<br />
structure similar to mica (25).<br />
Dispersions of the two paints were made. The Gebr. Terra di Verte was a<br />
rich orange-brown comparable to burnt sienna but more translucent. The<br />
Gebr. Griine Erde was similar to raw sienna, but of a greener tone. This must<br />
have been burned at a lower temperature, as a few green particles remained.<br />
Under the microscope, the pigments were identical to green earth, with the<br />
overlapping plates of the crystals visible on the larger particles. Calcite was<br />
seen in both, but the Gebr. Griine Erde had, as indicated by EDXRF, a higher<br />
proportion of it. The labels suggest that both bladders were prepared in Germany,<br />
perhaps from two different sources of green earth.<br />
The appearance of the samples brought to mind the unidentified brown pigment<br />
seen by the author in several nineteenth-century l<strong>and</strong>scape paintings,<br />
usually mixed with Prussian blue, ochres, <strong>and</strong> so forth, to produce greens <strong>and</strong><br />
browns. It was suggested that it was the brown seen in the cross sections from<br />
a painting by Constable then being examined. SEM-EDX analysis of the latter<br />
at the National Gallery laboratory produced a spectrum identical to that for<br />
green earth. It was later identified in several Constable paintings dating from<br />
1811 to 1829 mixed in greens <strong>and</strong> browns (26, 27). Could Merrifield's "eminent<br />
English artist" be John Constable?<br />
The author has tentatively identified burnt green earth in paintings by Peter<br />
de Wint <strong>and</strong> J. F. Millet (28).<br />
Green earth was rarely used in Engl<strong>and</strong>. The author has seen it only in<br />
seventeenth- <strong>and</strong> eighteenth-century wall paintings (oil) <strong>and</strong> cartoons by Verrio,<br />
Laguerre, Thornhill, <strong>and</strong> Robert Adam, all of whom trained in Italy or<br />
France. Verona brown seems to have been adopted in the early nineteenth<br />
century as a translucent addition to the earth <strong>and</strong> organic browns then available.<br />
Verona was a source of one of the better green earths, but was ab<strong>and</strong>oned<br />
earlier this century (29).<br />
By coincidence, Constable Project researcher Sarah Cove visited Brussels <strong>and</strong><br />
brought the author a bottle of pigment, Griine Erde Gebr., from an artists'<br />
suppliers. This modern sample is a darker, duller brown; perhaps burned at a<br />
higher temperature than the earlier examples, it too contains calcite.<br />
Brown pigments tend to be neglected, partly, no doubt, because of the difficulty<br />
in distinguishing the multitude of ochres, organic earths, <strong>and</strong> lakes.<br />
Burnt terra verte has a quite distinctive appearance, is easily identifiable by<br />
EDX, <strong>and</strong> may be more common than previously thought.<br />
Smalt<br />
The earliest blue glass colored with cobalt is from Eridu, Mesopotamia, circa<br />
2000 B.C.E. Recipes survive from Ashurbanipal's library in Nineveh, circa<br />
650 B.C.E. The Indians adopted Sumerian technology <strong>and</strong> were making cobalt<br />
blue glass by the sixth century B.C.E. (30). The Egyptians were using<br />
cobalt by circa 1400 B.C.E. The Romans were familiar with it; it was common<br />
in Western Europe in the seventh century <strong>and</strong> occurs in the Sassanian <strong>and</strong><br />
Islamic periods (31).<br />
The first appearance of smalt is in a wall painting (ca. 1000-1200 C.E.) in<br />
Khara Khoto, Central Asia, <strong>and</strong> in the Church of Our Saviour of the Mon-<br />
Darrah<br />
73