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Atomic Layer Deposition (ALD): An Enabler for Nanoscience and ...

Atomic Layer Deposition (ALD): An Enabler for Nanoscience and ...

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R 2<br />

R 1<br />

N N<br />

R3 R1 N<br />

R 2<br />

C<br />

M<br />

C N N C<br />

R 1 R 3<br />

Harvard University<br />

Metal(III) Amidinates<br />

N<br />

monomer<br />

R 3<br />

R 2<br />

Formamidinates: R 2 = H<br />

Acetamidinates: R 2 = CH 3<br />

Propionamidinates: R 2 = CH 2 CH 3<br />

R 1 <strong>and</strong> R 3 = alkyl groups<br />

Structures of dimers are unknown, probably bridged

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