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PERSPECTIVES<br />
772<br />
Pyroclastic flows<br />
∆ 17 O = +0.6‰<br />
hν<br />
*O=C=O *O + C=O<br />
*O + O *O 2 3<br />
*O + H O hν H *O + O 3 2 2 2 2<br />
H 2 *O 2<br />
mass-independent isotope fractionations<br />
driven by the pen<strong>et</strong>ration of ultraviol<strong>et</strong> light<br />
through the thin atmosphere of Mars ( 7, 8).<br />
Further, on Earth such processes would be<br />
wiped out by plate tectonics, but the absence<br />
of subduction on Mars resulted in the preservation<br />
of mass-independent isotope anom<strong>al</strong>ies<br />
( 7, 8). Ever since the Viking mission in<br />
1976, it has been known that Mars’ atmosphere<br />
is escaping the plan<strong>et</strong>’s gravitation<strong>al</strong><br />
grasp with attendant mass fractionation,<br />
but that carbon and oxygen isotopes did not<br />
exhibit the extreme mass-dependent fractionation<br />
observed in nitrogen. Therefore,<br />
a reservoir on Mars must be buffering the<br />
C and O isotopes ( 9). Agee <strong>et</strong> <strong>al</strong>. now show<br />
that the lithosphere may be part of the buffering<br />
(at least for oxygen) because the bulk<br />
oxygen isotope composition of NWA 7034<br />
has been shifted toward the atmospheric end<br />
relative to other martian m<strong>et</strong>eorites (see the<br />
fi gure). Incident<strong>al</strong>ly, this is one of the questions<br />
Curiosity is designed to tackle on<br />
Mars, but Agee <strong>et</strong> <strong>al</strong>. may have beaten the<br />
rover to the punch line.<br />
Upper atmosphere<br />
∆ 17 O ≥ +0.8‰<br />
MgSiO 3 + *O 3 MgSi*O 3 + O 3<br />
Lava flows<br />
∆ 17 O = +0.3‰<br />
Pyroclastic flows?<br />
Spirit of exploration. A cartoon of a volcanic pyroclastic fl ow schematic<strong>al</strong>ly depicting how NWA 7034 may have formed on<br />
Mars ( 4) and how photochemic<strong>al</strong> reactions may imprint isotopic signatures in the newly formed rock. (Ins<strong>et</strong>) An image of<br />
Gusev Crater viewed by Spirit (PIA02688, 19 February 2006) showing possible pyroclastic deposits.<br />
Another interesting aspect of NWA 7034<br />
is its clastic nature, whereby numerous<br />
fragments of rock and miner<strong>al</strong> are bound<br />
tog<strong>et</strong>her. It is unknown wh<strong>et</strong>her these clasts<br />
<strong>al</strong>l originate from a single (pyroclastic) volcanic<br />
eruption, or wh<strong>et</strong>her multiple clasts are<br />
introduced by impact or some other extern<strong>al</strong><br />
agent. Experience with lunar rocks reve<strong>al</strong>ed<br />
a we<strong>al</strong>th of information in 2- to 4-mm rock<br />
fragments; is this an opportunity to repeat<br />
that exercise on Mars?<br />
Agee <strong>et</strong> <strong>al</strong>. measured 0.6 weight percent<br />
water in NWA 7034 with a distinct oxygen<br />
isotope composition from the bulk rock,<br />
effectively a sample of the martian hydrosphere<br />
or permafrost trapped within the<br />
matrix of NWA 7034. What are the host<br />
miner<strong>al</strong>s? As a rock that appears to have<br />
originated at the martian surface, NWA<br />
7034 may contain the elusive hydrous miner<strong>al</strong>s<br />
that host water on Mars and their miner<strong>al</strong>ogy<br />
might now be d<strong>et</strong>ermined in the laboratory,<br />
with important inputs into directing<br />
Curiosity or designing the next generation<br />
of Mars probes.<br />
15 FEBRUARY 2013 VOL 339 SCIENCE www.sciencemag.org<br />
Published by AAAS<br />
And, fi n<strong>al</strong>ly, there is macromolecular<br />
organic carbon<br />
(MMC) recognized in inclusions<br />
within feldspar cryst<strong>al</strong>s<br />
( 4). It is tempting to wonder<br />
wh<strong>et</strong>her the volcanic activity<br />
associated with the igneous<br />
clasts in NWA 7034 provided<br />
a warm haven for martian life.<br />
If so, this is the place to start<br />
a search. Because NWA 7034<br />
is a desert fi nd and not a fresh<br />
f<strong>al</strong>l (even though it appears<br />
rather fresh by Saharan m<strong>et</strong>eorite<br />
standards), an important<br />
question is wh<strong>et</strong>her the organic<br />
matter in NWA 7034 is actu<strong>al</strong>ly<br />
from Mars. This can be<br />
s<strong>et</strong>tled by measurement of the<br />
D/H (deuterium/hydrogen)<br />
ratio for the MMC because the<br />
martian hydrogen is characterized<br />
by a high D/H ratio relative<br />
to terrestri<strong>al</strong> organics ( 10).<br />
If an extraterrestri<strong>al</strong> origin is<br />
indeed confirmed, it may y<strong>et</strong><br />
prove to be m<strong>et</strong>eoritic organics<br />
associated with microm<strong>et</strong>eorite<br />
inf<strong>al</strong>l on the martian surface.<br />
Anyway, the hunt for life<br />
on Mars in another m<strong>et</strong>eorite<br />
will then be on.<br />
If one were to wish for a single<br />
martian m<strong>et</strong>eorite, it would<br />
be NWA 7034, the fi rst known<br />
arch<strong>et</strong>yp<strong>al</strong> crust<strong>al</strong> rock from<br />
Mars. When other such rocks are found, they<br />
may help to clarify many remaining questions<br />
about the martian surface. For example,<br />
has hydrotherm<strong>al</strong> activity occurred on<br />
Mars? Have ore miner<strong>al</strong>izations occurred?<br />
Is there evidence of soil (aeolian dust) in<br />
the breccia? Is trapped ancient atmosphere<br />
(nitrogen, noble gases) present in the amorphous<br />
materi<strong>al</strong>? Stay tuned for more exciting<br />
discoveries.<br />
References<br />
1. H. Y. McSween Jr., M<strong>et</strong>eorit. Plan<strong>et</strong>. Sci. 37, 7 (2002).<br />
2. A. H. Treiman, J. D. Gleason, D. D. Bogard, Plan<strong>et</strong>. Space<br />
Sci. 48, 1213 (2000).<br />
3. H. Y. McSween Jr., G. J. Taylor, M. B. Wyatt, Science 324,<br />
736 (2009).<br />
UNIVERSITY<br />
4. C. B. Agee <strong>et</strong> <strong>al</strong>., Science 339, 780 (2013);<br />
10.1126/science.1228858.<br />
5. R. N. Clayton, T. K. Mayeda, Geochim. Cosmochim. Acta<br />
60, 1999 (1996).<br />
6. T. J. Lapen <strong>et</strong> <strong>al</strong>., Science 328, 347 (2010).<br />
7. H. R. Karlsson, R. N. Clayton, E. K. Gibson Jr.,<br />
T. K. Mayeda, Science 255, 1409 (1992).<br />
8. J. Farquhar, M. H. Thiemens, T. Jackson, Science 280,<br />
1580 (1998).<br />
9. A. O. Nier, M. B. McElroy, Science 194, 1298 (1976).<br />
10. L. A. Leshin, E. Vicenzi, Elements 2, 157 (2006).<br />
NASA/JPL-CALTECH/USGS/CORNELL<br />
10.1126/science.1232490 CREDIT:<br />
on February 14, 2013<br />
www.sciencemag.org<br />
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