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Geo<strong>the</strong>rmal Resources Counail, TRANSACTIONS Vol. 4, September 1980<br />

WATER GEOCHEMISTRY AT CASTLE HOT SPRINGS, ARIZONA<br />

Richard L. Satkln, Kenneth H. Wohletz and Michael F. Sheridan<br />

Department <strong>of</strong> Geology, Arizona State <strong>University</strong>, Tempe, Arizona 85281<br />

ABSTRACT<br />

A geochemical survey <strong>of</strong> springs and wells<br />

in <strong>the</strong> Castle Hot Springs area, Arizona, shows<br />

that three groups <strong>of</strong> waters can be distinguished<br />

by salinity and chemistry. The <strong>the</strong>rmal waters<br />

<strong>of</strong> Group I range from 640 to 820 ppm TDS, and<br />

<strong>the</strong> waters contain high concentrations <strong>of</strong> Si02,<br />

Li"*", and F~. The non-<strong>the</strong>rmal waters <strong>of</strong> Group<br />

II range from 380 to 580 ppm TDS and contain<br />

low concentrations <strong>of</strong> Si02, Li"*", and F~. The<br />

non-<strong>the</strong>rmal waters <strong>of</strong> Group III range from<br />

1600-1650 ppm TDS and contain <strong>the</strong> highest concentrations<br />

<strong>of</strong> Li+, Cl", and SO^^'^.<br />

The discrepancy between <strong>the</strong> low measured<br />

surface temperature at Castle Hot Springs, and<br />

<strong>the</strong> high temperatures estimated from chemical<br />

geo<strong>the</strong>rmometry suggest <strong>the</strong>rmal waters may have<br />

cooled ei<strong>the</strong>r hy conduction, boiling or mixing.<br />

TKe chalcedony mixing raodel yields a"^reservolr<br />

temperature <strong>of</strong> 95°C and a cold water fraction <strong>of</strong><br />

56%.<br />

INTRODUCTION<br />

Castle Hot Springs ie located 70 km northwest<br />

<strong>of</strong> Phoenix, Arizona (<strong>Figure</strong> 11. It is presently<br />

being evaluated for direct-use geo<strong>the</strong>rmal<br />

development <strong>of</strong> <strong>the</strong> resource for space heating and<br />

cooling. The results <strong>of</strong> hydrogeocKemtcal sampling<br />

<strong>of</strong> <strong>the</strong>rmal and non-<strong>the</strong>rmal springs and wells in<br />

<strong>the</strong> area are presented.<br />

GEOLOGIC SETTING<br />

The geologic setting <strong>of</strong> Castle Hot Springs<br />

has been discussed by Sheridan et al. (1979);. Recent<br />

detailed geologic <strong>map</strong>ping has documented a<br />

low-angle slump fault displacing an allochthonous<br />

block <strong>of</strong> Precambrian granite on top <strong>of</strong> a sequence<br />

<strong>of</strong> Tertiary volcanic rocks. The allochthonous<br />

block has been altered and is strongly brecciated<br />

and jointed resulting in increased permeability.<br />

Mixing <strong>of</strong> hydro<strong>the</strong>rmal fluids and cold meteoric<br />

water may be significant along this low-angle<br />

fault. Nielson and Moore (1979) have described a<br />

similar geologic situation at <strong>the</strong> Cove Fort-Sulphurdale<br />

geo<strong>the</strong>rmal system in <strong>Utah</strong>. They suggest<br />

that <strong>the</strong> allochthonous rocks may serve as a <strong>the</strong>rmal<br />

cap on <strong>the</strong> system separating a convective <strong>the</strong>r-<br />

177<br />

mal regime beneath <strong>the</strong> low-angle fault from a<br />

zone <strong>of</strong> conductive heat transport and probable<br />

fresh water influx above <strong>the</strong> principal fault<br />

zone.<br />

Calif<strong>of</strong>nie<br />

<strong>Figure</strong> 1.<br />

Mexico<br />

<strong>Utah</strong><br />

•* Cjstle Hot Sprirgs<br />

• PhoeniK<br />

"""^-^ 0<br />

""-^.^<br />

100 Km<br />

_<br />

Colorado<br />

New<br />

Mexico<br />

Location <strong>map</strong> <strong>of</strong> Castle Hot Springs,<br />

Arizona.<br />

HYDROLOGIC SETTING<br />

The <strong>the</strong>rmal waters <strong>of</strong> Group I display similar<br />

physical and cheraical characteristics. The<br />

waters <strong>of</strong> Group I are: Castle Hot Springs, Alkalai<br />

Spring, Henderson Ranch Spring and <strong>the</strong> Dodd<br />

Well. The <strong>the</strong>rmal waters occur along a 0.8 km<br />

alignment trending N.45°W. which coincides with<br />

<strong>the</strong> trend <strong>of</strong> a major fault system bounding Precambrian<br />

crystalline rocks and Tertiary volcanic<br />

rocks. The <strong>the</strong>rmal springs all emanate at an elevation<br />

<strong>of</strong> 658 meters along <strong>the</strong> same fault system<br />

suggesting an apparent hydrostatic relationship.<br />

The <strong>the</strong>rmal waters display a homogenous chemistry<br />

which indicates <strong>the</strong>y probably originate from <strong>the</strong><br />

same geo<strong>the</strong>rmal reservoir.<br />

WATER SAMPLING AND ANALYTICAL PROCEDURE<br />

An important aspect <strong>of</strong> this investigation is

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