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CHEM01200604009 Sreejith Kaniyankandy - Homi Bhabha ...

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1.3.5. Defect Mediated Relaxation 21<br />

1.4. How Can QDs Help in Solar Cells? 21-23<br />

1.5. “Improving on” QDs 24<br />

1.5.1. Semiconductor-Semiconductor Core Shell Nanostructures 24-25<br />

1.5.2. Semiconductor-Dye Nanostructures 26<br />

1.5.3. Metal-Semiconductor Nanostructures 26-27<br />

1.6. Classical Electron Transfer 27-29<br />

1.6.1. Adiabatic and Non-Adiabatic Process 29-30<br />

1.6.2. Classical Electron Transfer Theory 30-33<br />

1.6.3. Quantum mechanical theory of electron transfer 33-34<br />

1.7 Interfacial Electron Transfer from Molecular Adsorbate to Semiconductor 34-35<br />

1.7.1. Electron Injection 35-37<br />

1.7.2. Back Electron Transfer 37-38<br />

1.8. Synthesis of Semiconductor Quantum Dots 38-41<br />

1.9. Thesis Overview 42-43<br />

1.10. Scope of the Thesis in View of Applications in Photovoltaics 42-43<br />

1.11. Thesis Overview 43-46<br />

Chapter 2<br />

Experimental<br />

2.1. Introduction 48<br />

2.2. UV-Visible Absorption Spectroscopy 48-50<br />

2.3. Fluorescence Spectroscopy 50-51<br />

2.4. X-Ray Diffraction<br />

viii

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