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Final Report - Strategic Environmental Research and Development ...

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Figure 4.26.<br />

Figure 4.27.<br />

Figure 4.28.<br />

Figure 4.29.<br />

Figure 4.30.<br />

Figure 4.31.<br />

Figure 4.32.<br />

Figure 4.33.<br />

Figure 4.34.<br />

Figure 4.35.<br />

Figure 4.36.<br />

Figure 4.37.<br />

Effect of exposure conditions prior to BT on adhesion strength of a<br />

sample cleaned, deoxidized, pretreated with NCP <strong>and</strong> coated with<br />

AVIOX CF 37124.<br />

Failure morphologies of coated samples after Pull-Off test when (a)<br />

Belzona, (b) Araldite 907, <strong>and</strong> (c) Super glue are used to attach the dolly<br />

to the substrate; <strong>and</strong> after (d) BT.<br />

Classification of adhesion test results related to the percent area<br />

removed after the test ASTM D3359.<br />

Comparison between (a) the adhesion strength results obtained from the<br />

BT <strong>and</strong> (b) the classification of adhesion test results from the test<br />

ASTM D3359.<br />

BT results related to (a) the behavior of pressure <strong>and</strong> radius versus time<br />

<strong>and</strong> (b) pressure x radius trend for sample cleaned, deoxidized, treated<br />

with CCC <strong>and</strong> coated with epoxy.<br />

Pressure versus radius for full factorial of AA2024-T3 samples coated<br />

with epoxy.<br />

BT results related to (a) the behavior of pressure <strong>and</strong> radius versus time<br />

<strong>and</strong> (b) pressure x radius trend for sample neither cleaned/deoxidized,<br />

nor treated, <strong>and</strong> coated with acetoacetate.<br />

Pressure x radius trend for samples (a) non-cleaned/deoxidized <strong>and</strong> (b)<br />

cleaned/deoxidized <strong>and</strong> coated with acetoacetate.<br />

Effect of cleaning/deoxidizing <strong>and</strong> CC on the adhesion strength of<br />

acetoacetate to AA2024-T3. C/D means cleaned/deoxidized.<br />

Pressure x radius trend for samples (a) non-cleaned/deoxidized <strong>and</strong> (b)<br />

cleaned/deoxidized <strong>and</strong> coated with AVIOX CF 37619.<br />

Photographs of acetoacetate coated samples after exposure to DI water<br />

at 60°C.<br />

XPS signal measured from a non-treated sample, showing the (a) Si 2s<br />

<strong>and</strong> 2p peaks <strong>and</strong> a magnification of each one, respectively (b) <strong>and</strong> (c)<br />

(old batch).<br />

194<br />

194<br />

195<br />

195<br />

197<br />

197<br />

198<br />

199<br />

199<br />

200<br />

203<br />

204<br />

Figure 5.1. Protocol for chromate-free inhibitor identification. 208<br />

Figure 5.2. Apparatus <strong>and</strong> method for inhibitor slurry testing. 210<br />

Figure 5.3. Synthesis procedure for Pr(OH) 3 . 210<br />

xvii

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