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Polymers in Sport and Leisure

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<strong>Polymers</strong> <strong>in</strong> <strong>Sport</strong> <strong>and</strong> <strong>Leisure</strong><br />

5 Athletics <strong>and</strong> Gymnastics<br />

The major uses of polymers <strong>in</strong> athletics are for surfaces<br />

<strong>and</strong> cloth<strong>in</strong>g, which have been discussed <strong>in</strong> Sections 2<br />

<strong>and</strong> 3. <strong>Polymers</strong> have had enormous impact on the<br />

sports <strong>in</strong> both these areas.<br />

Another product which has had a major effect on<br />

performances is the carbon fibre vault<strong>in</strong>g pole. The rules<br />

cover<strong>in</strong>g vault<strong>in</strong>g poles are unusual <strong>in</strong> that they can be<br />

made of any material <strong>and</strong> be of any length <strong>and</strong> diameter.<br />

Indeed, it is necessary that the pole is <strong>in</strong>dividually<br />

matched to the speed <strong>and</strong> mass of the vaulter. The poles<br />

are hollow with vary<strong>in</strong>g thickness along the length <strong>and</strong><br />

top class poles are prebent. An analysis of the stresses<br />

<strong>and</strong> design pr<strong>in</strong>ciples has been given by Burgess (161).<br />

Polymeric foams are used extensively <strong>in</strong> mats for high<br />

jump<strong>in</strong>g <strong>and</strong> pole vault<strong>in</strong>g, gymnastics <strong>and</strong> martial arts.<br />

They vary <strong>in</strong> thickness <strong>and</strong> foam density to suit the<br />

particular application from 750 mm for a pole vault<br />

l<strong>and</strong><strong>in</strong>g area to 20 mm for an elementary exercise mat.<br />

The foam is most commonly polyether or reconstituted<br />

polyurethane but th<strong>in</strong>ner mats sometimes use<br />

polyethylene or ethylene v<strong>in</strong>yl acetate. The prime<br />

objective of the mats is to provide impact absorption<br />

but their resilience <strong>and</strong> stiffness is also important.<br />

Particularly <strong>in</strong> sports such as judo, a large deflection<br />

hamper<strong>in</strong>g movement could be more dangerous than<br />

the effect of fall<strong>in</strong>g. Composite construction us<strong>in</strong>g<br />

layers of different density can be used to obta<strong>in</strong> the<br />

desired characteristics. The mats are typically covered<br />

<strong>in</strong> polyv<strong>in</strong>yl chloride coated nylon <strong>and</strong> have a non-slip<br />

rubber base. Mats are potentially a significant fire<br />

hazard <strong>and</strong> <strong>in</strong> the UK are subject to str<strong>in</strong>gent<br />

flammability requirements which means that foams<br />

must be of a fire retarded grade.<br />

6 W<strong>in</strong>ter <strong>Sport</strong>s<br />

Ski<strong>in</strong>g was once someth<strong>in</strong>g of a m<strong>in</strong>ority <strong>in</strong>terest but<br />

with <strong>in</strong>creased leisure <strong>and</strong> cheap flights it has developed<br />

<strong>in</strong>to a mass sport. W<strong>in</strong>ter sports have cont<strong>in</strong>ued to grow<br />

<strong>in</strong> popularity <strong>and</strong> represent a very large market for<br />

sports goods. With this boom came <strong>in</strong>creased<br />

development of the equipment <strong>and</strong> polymers now have<br />

a major position. In fact it is not an overstatement to<br />

say that w<strong>in</strong>ter sports depend on plastics.<br />

Wooden skis were unresponsive, absorbed water, were<br />

heavy <strong>and</strong> were not very durable. Plastics have allowed<br />

ski<strong>in</strong>g techniques to improve, made the putt<strong>in</strong>g on <strong>and</strong><br />

tak<strong>in</strong>g off of skis easier, improved safety <strong>and</strong> comfort,<br />

<strong>and</strong> reduced costs. Encas<strong>in</strong>g a wood core <strong>in</strong> glass fibre<br />

re<strong>in</strong>forced polyester was the first change followed by<br />

the development of polyurethane foam cores. Quite<br />

rapidly skis became a sophisticated construction made<br />

up of many components which can <strong>in</strong>clude honeycomb<br />

cores, advanced composites <strong>and</strong> a slid<strong>in</strong>g layer of<br />

graphite impregnated polyethylene.<br />

The degree of effort put <strong>in</strong>to development is illustrated<br />

by French manufacturer Rossignol which has been<br />

devot<strong>in</strong>g over 3% of turnover to new product<br />

development for 4 decades <strong>and</strong> has 200 employees<br />

work<strong>in</strong>g <strong>in</strong> research (8). The <strong>in</strong>troduction of modern<br />

materials <strong>and</strong> construction techniques has been<br />

accompanied by quite radical changes <strong>in</strong> the dimensions<br />

<strong>and</strong> shape of skis. Shorter skis with noses at both ends<br />

are said to provide someth<strong>in</strong>g of a bridge between<br />

conventional ski<strong>in</strong>g <strong>and</strong> snowboard<strong>in</strong>g <strong>and</strong> to be<br />

extremely versatile. Generally, skis have become shorter<br />

with the middle be<strong>in</strong>g markedly more narrow than the<br />

ends. A wide range of polymers are used <strong>in</strong> ski <strong>and</strong><br />

snowboard construction <strong>in</strong>clud<strong>in</strong>g rubber as an <strong>in</strong>terface,<br />

glass re<strong>in</strong>forced epoxy structural components,<br />

polyurethane or thermoset cellular core materials,<br />

aramid, carbon <strong>and</strong> graphite fibres, polyethylene soles<br />

<strong>and</strong> <strong>in</strong>jected thermoplastic protective parts. Snowboards<br />

have a similar type of composite structure.<br />

As ski<strong>in</strong>g became a mass sport it quickly became<br />

apparent that leather boots were <strong>in</strong>adequate. As has so<br />

often been the case with the <strong>in</strong>troduction of polymers<br />

the first step was replac<strong>in</strong>g part of the product, an<br />

<strong>in</strong>jection-moulded thermoplastic sole <strong>in</strong> this case.<br />

However, the first all-plastic boot appeared as early as<br />

1967. A ski boot has to be extremely tough <strong>and</strong> reta<strong>in</strong><br />

its properties at low temperatures. Polyurethane meets<br />

these dem<strong>and</strong>s with different hardnesses be<strong>in</strong>g suitable<br />

for different parts of the boot but other polymers are<br />

now <strong>in</strong>corporated.<br />

The b<strong>in</strong>d<strong>in</strong>g which attaches the boot to the ski is a vital<br />

component as it has the seem<strong>in</strong>gly impossible task of<br />

hold<strong>in</strong>g the boot securely throughout the stresses of<br />

ski<strong>in</strong>g but releases it when stresses reach a danger po<strong>in</strong>t.<br />

Here too, plastics have replaced alum<strong>in</strong>ium with several<br />

materials hav<strong>in</strong>g been used, notably fibre re<strong>in</strong>forced<br />

nylon. One design uses Hytrel for the straps <strong>and</strong> hiback,<br />

nylon for the base <strong>and</strong> acetal for the buckles (146).<br />

To complete the plastics dom<strong>in</strong>ation, top-of-the-range ski<br />

pole tubes are made from hybrid fibre re<strong>in</strong>forced materials.<br />

Apart from skis <strong>and</strong> snowboards, polymers are prime<br />

c<strong>and</strong>idates for use <strong>in</strong> the various sledges, toboggans<br />

<strong>and</strong> other snow vehicles. One example reported<br />

11

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