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SleepTech Magazine / May - June 2017

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152<br />

weight polyols within the material.<br />

Polyether polyols account for<br />

about 90% of the polymeric polyols<br />

used industrially; the balance<br />

is polyester polyols.<br />

As is the case for all foam manufacturers<br />

at almost all over the<br />

world Turkish foam manufacturers<br />

have also been suffering some<br />

supply problems of this main input<br />

of their manufacturing process.<br />

Price hikes are also a big problem<br />

for the industry. Depending on<br />

this material for foam production<br />

the industry is almost in a monopoly<br />

of a main supplier. When it<br />

suffers from any cause the entire<br />

industry suffers because the producer<br />

naturally reflects the loss on<br />

prices, delivery and other factors.<br />

Another class of polymeric polyols<br />

is the polyesters. Polyesters are<br />

formed by condensation or stepgrowth<br />

polymerization of diols<br />

and dicarboxylic acids (or their<br />

derivatives), for example diethylene<br />

glycol reacting with phthalic<br />

acid.[5] Alternatively, the hydroxyl<br />

group and the carboxylic acid (or<br />

their derivatives) may be within<br />

the same molecule, as in the case<br />

of caprolactone. The example<br />

below is an idealized structure<br />

that could be obtained by reacting<br />

pentaerythritol (a tetrol) with<br />

gamma-butyrolactone.

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