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Annual Danish informative inventory report to UNECE. Emission ...

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• Production of container glass/glass wool (SNAP 030315/030316/<br />

040613).<br />

• Production of mineral wool (SNAP 030318).<br />

• Limes<strong>to</strong>ne and dolomite use (SNAP 040618).<br />

• Roof covering with asphalt (SNAP 040610).<br />

• Road paving with asphalt (SNAP 040611).<br />

The time-series for emission of acidifying substances, heavy metals,<br />

NMVOC and particulate matter from 0LQHUDO SURGXFWV (NFR 1A2f/2A)<br />

are presented in Table 4.2 and Table 4.3.<br />

The emission of SO2, NOX and CO from the production of cement depends<br />

on raw materials, fuels and combustion conditions. <strong>Emission</strong>s of<br />

NOX are, among other things, a consequence of high temperature processes<br />

and the emission shows only minor fluctuations. The emission follows<br />

the activity, with a minor decrease in recent years. The emission of<br />

SO2 depends on the S-content in fuels and raw materials. However, the<br />

process acts as a sink for acidifying gases due <strong>to</strong> the alkaline conditions<br />

in the rotary kiln; see Figure 4.1. The emission of CO displays significant<br />

fluctuations that cannot be explained by known fac<strong>to</strong>rs.<br />

The emission of NOX from production of container glass is increasing<br />

slightly until 2004 and thereafter decreasing significantly whereas the<br />

emission of CO is decreasing in the period 1990-2009. In the same period<br />

of time, the activity is nearly constant. <strong>Emission</strong>s of both substances<br />

are related <strong>to</strong> combustion/process conditions and will be investigated<br />

further. <strong>Emission</strong>s of the heavy metals lead, selenium and zinc<br />

are related <strong>to</strong> the raw materials used. Recycled glass constitutes a considerable<br />

part of raw materials and, therefore, the quality/purity of the<br />

glass is a determining fac<strong>to</strong>r. <strong>Emission</strong> of lead shows a decreasing trend<br />

that is in accordance with the attempts <strong>to</strong> avoid lead in glass as well as<br />

in wine bottle seals.<br />

Production of glass wool is expected <strong>to</strong> result in emission of approximately<br />

the same pollutants as in production of container glass. NH3<br />

shows a decreasing trend from 1996-2007 as can be verified by the decreasing<br />

emission pr amount produced. However, the emission has<br />

been stabilised on a higher level in 2008 and 2009. <strong>Emission</strong> of NOX has<br />

been included for 2009 and the time-series will be completed. CO and<br />

heavy metals are planned <strong>to</strong> be investigated and included in the <strong>inven<strong>to</strong>ry</strong>.<br />

205

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