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MARTES / TUESDAY<br />

16<br />

standards. Furthermore, the necessity is<br />

evident for developing a new standard for<br />

screening wear tests based on the latest<br />

fi ndings, such as multidirectional motion or<br />

lubricant composition<br />

Materials And Methods<br />

A pin-on-disk (POD) wear test machine is a<br />

common wear test method, which has been<br />

widely used to evaluate the wear of polymers<br />

in biotribology. In a POD the polymer, usually<br />

in the form of a pin, slide over the surface of a<br />

rotating disk. Two basic confi gurations can be<br />

distinguished; the pin may be loaded along<br />

its major axis, in a direction either normal to<br />

or parallel with the axis of rotation of the disk.<br />

Hence, the contact area is produced on the<br />

edge (horizontal POD confi guration) or the<br />

face (vertical POD confi guration) of the disk.<br />

According to this defi nition, the wear test<br />

method proposed here was a horizontal POD<br />

(here in after called simply as POD I).<br />

In the POD test device, a wheel or ring in<br />

vertical position wears against an underlying<br />

pin of polyethylene. Figure 1a shows<br />

schematically the loading/motion confi guration.<br />

The contact geometry at the test start<br />

is non-conformal, that is a line-contact. In<br />

this sense, these wear test devices would be<br />

more representative for a knee wear device<br />

than for a <strong>hip</strong> wear device, where the contact<br />

geometry is conformal (also designated as<br />

congruent).<br />

There is no standard regarding this type<br />

of wear device and similar studies are not<br />

present in the literature. Thus, comparison<br />

and analysis of the test conditions proposed<br />

cannot be made. Due to its confi guration,<br />

the closest available standard would be<br />

the ASTM G137-97, with identical contact<br />

geometry and intended too for ranking the<br />

resistance of plastic materials in sliding wear.<br />

However, this standard does not cover biotribological<br />

conditions.<br />

The multidirectional POD (POD II) wear test<br />

method is based on the former unidirectional<br />

POD (POD I) wear test method. However, in<br />

the POD II test method the pin rotates too,<br />

see Figure 1b, and as consequence of the<br />

rotation of the pin this device has a biaxial<br />

pattern motion (i.e. multidirectional). In the<br />

literature, no wear device similar to this can<br />

be found making from it a unique screening<br />

wear test device. The tasks with this wear<br />

test method are in principle the same as for<br />

the former POD I. With the POD II tests,<br />

additionally the effect of the motion type in<br />

the wear resistance of the UHMWPE can<br />

be studied.<br />

The test with the POD test method was performed<br />

as follows. The disk rotates continuously<br />

against an underlying pin of UHMWPE.<br />

A load of ~150 N (15 Kg) was applied to the<br />

pins. It gives a maximum Herztian contact<br />

pressure (po) of ~5 MPa. The relative surface<br />

velocity was 100 rpm for the disk and<br />

for the multidirectional test, the pin velocity<br />

was 99 rpm. The frequency of the disk was<br />

1 Hz. The wear of the UHMWPE pins was<br />

mainly determined by profi lometric measurements.<br />

Weight loss measurements were also<br />

performed after the completion of the test.<br />

The test length was 34 Km.<br />

To the test lubricant distilled water was<br />

added during the test for compensating<br />

water evaporation. As test lubricant, a solution<br />

consisting of bovine serum and distilled<br />

water was used, which had a total protein<br />

concentration of 30 mg/ml. The serum was<br />

purchased at Sigma-Aldrich SrI (Calf serum,<br />

bovine donor; product No.C9676). The soak<br />

adsorption of the UHMWPE pins was determined<br />

using an additional control pin, which<br />

was loaded identically as the UHMWPE<br />

pins in the RPOF machine, but no motion<br />

was applied. The cleaning and drying of the<br />

UHMWPE pins was performed according<br />

to the ASTM 1715 standard. Weighing was<br />

carried out with a Mettler Toledo AT261DeltaRange<br />

® microbalance with an accuracy<br />

of ±10 μg.

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