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Tidal Current Energy

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Biomass<br />

163<br />

production of methane-rich biogas from landfill sites as a result of organic material<br />

decomposition results in a significant contribution to atmospheric methane.<br />

At many larger landfill sites, the collection of landfill gas and the production of<br />

electricity using various types of gas engines has been shown to be profitable,<br />

and hence the application of such systems has become widespread. The benefits<br />

are significant, as the methane gas produced becomes a useful energy carrier<br />

rather than a gas that would otherwise contribute to a build-up of greenhouse<br />

gas emissions in the atmosphere [14]. New landfill sites are often specifically<br />

developed in a configuration which encourages anaerobic digestion. In these new<br />

sites, a pipe system for gas collection is designed and implemented prior to waste<br />

deposition. This collection system optimizes the gas output, which can be as high<br />

as 1000 m 3 �h �1 [4]. A variant on engineered landfill systems with gas collection<br />

systems is bioreactor cells, where the biological processes of breaking down the<br />

waste and biogas production are enhanced through process optimization [1].<br />

4.1.2. Hydrolysis/fermentation<br />

Fermentation is used commercially on a large scale in various countries to<br />

produce ethanol from sugar and starch crops, as well as ligno-cellulosic biomass<br />

feedstocks. Typically, the biomass is ground and the cellulose and hemicelluloses<br />

are converted by enzymes to sugars; subsequently, the sugars are<br />

converted by yeast to ethanol. The best known biomass feedstock for ethanol<br />

production is sugar cane, but other organic materials can be used, including<br />

wheat and other cereals, sugar beet, Jerusalem artichoke and wood.<br />

The choice of biomass is important as feedstock costs typically make up 55–80%<br />

of the final alcohol selling price. To date, starch-based biomass remains less expensive<br />

than sugar-based biomass, but requires additional processing [1]. Lignocellulosic<br />

materials such as wood and straw are readily available, but are more<br />

complex due to the presence of longer-chain polysaccharide molecules. Hence<br />

these ligno-cellulosic biomass feedstocks require pretreatment (acid, enzymatic<br />

or hydrothermal hydrolysis) to depolymerize the cellulose and hemicellulose to<br />

monomers, which will subsequently be converted by yeast and bacteria employed<br />

in the process [16,26]. Lignin in biomass is refractory to fermentation and, as<br />

a by-product, is typically employed as boiler fuel or as a feedstock for other<br />

thermochemical conversion processes converting the residual biomass to other<br />

fuels and products [31]. The purification of ethanol by distillation is an energyintensive<br />

step. Production of approximately 496 liters of ethanol per metric<br />

tonne of dry corn is feasible. Hydrolysis techniques for alternative feedstocks are<br />

currently at the pre-pilot stage [26].<br />

4.2. Thermochemical conversion processes<br />

4.2.1. Combustion<br />

Combustion is a thermochemical process that is widely used on a variety of<br />

scales. Direct combustion is a mature and well-established technology with<br />

numerous operating plants around the world. In combustion, the biomass fuel

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