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Tidal Current Energy

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8<br />

A. R. H. Goodwin<br />

into blocks. A simulation of the reservoir requires of the order of 10 6 calls to a<br />

package that calculates the thermophysical properties of the fluid and so the<br />

methods chosen to estimate these properties must not contribute significantly<br />

to the time required to perform the simulation. This requirement precludes, at<br />

least for routine work, the use of intensive calculation methods that are based<br />

on molecular models. Because of the requirement for simple correlations, for<br />

a particular process, often over a limited temperature and pressure range, the<br />

industry makes frequent utilization of both empirical and semi-empirical methods.<br />

Typically, the seismic and logging measurements are repeated over the<br />

production time of a reservoir and the parameters further adjusted to represent<br />

the measurements obtained as a function of time in a process known within the<br />

industry as history matching [25–27] .<br />

Some of these measurement techniques are also used to monitor natural gas<br />

storage facilities [28] , while others are used to monitor the plums of contaminated<br />

groundwater within the vadose zone beneath Hanford, Washington, USA [29] .<br />

Hanford, which was built on the banks of the Columbia River in the 1940s,<br />

is where the first full-scale nuclear reactor was located for the production of<br />

weapons-grade 239 Pu.<br />

2.2 . Hydrocarbon types<br />

Hydrocarbon reservoirs were formed by the thermogenic and also microbial<br />

breakdown of organic matter known as kerogen that occurred over 10 6 a. When<br />

the temperature of kerogen is increased to about 353 K oil is produced with,<br />

in general, higher density oil obtained from lower temperatures; microbes are<br />

operative for shallow and thus lower temperature oils, thereby also decreasing<br />

the density. Kerogen catagenesis [30] is a reaction producing both hydrocarbon<br />

and a mature kerogen. As the temperature to which the kerogen is exposed<br />

increases as well as the exposure time the density of the hydrocarbon decreases<br />

and at T � 413 K natural gas is produced. In general, kerogen experienced different<br />

temperatures during burial and thus different types of hydrocarbons<br />

were charged into reservoirs. Models to describe the formation of petroleum<br />

reservoirs from kerogen catagenesis have been proposed by Stainforth [31] . Not<br />

surprisingly, the types of hydrocarbon are as diverse in type as the formation in<br />

which they are located.<br />

The hydrocarbon accumulates in porous, permeable rock and migrates<br />

upward in order of decreasing density, owing to faults, fractures and higher<br />

permeable strata, until prevented by an impermeable barrier. The overriding<br />

assumption is that the fluids do not mix and only in reservoirs that contain fluids<br />

near their critical point does mixing occur solely by diffusion [32] . Recently,<br />

Jones et al. [33] have suggested the biodegradation of subsurface crude oil<br />

occurs through methanogenesis.<br />

This chapter will focus on the hydrocarbon resource that can be solid, liquid<br />

or gas rather than the reservoir which can be at temperatures from 270 to 500 K<br />

and pressures up to 250 MPa with lithostatic and hydrostatic pressure gradients

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