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330 D. Tondeur and F. Teng<br />

As regards research, while it is hard to see that a single breakthrough could<br />

solve all these problems, the challenges are numerous. For example, new<br />

approaches for getting rid of minor pollutants such as S, Cl, Hg, new materials<br />

for burners, boilers, turbines allowing higher temperatures, new membranes and<br />

solid oxygen carriers could change the technological and economic landscape.<br />

Some particular situations have favorable prospects and will certainly be leading<br />

examples in the large-scale deployment of CCS. Oil and gas production have<br />

been mentioned, with associated enhanced recovery and/or geological storage<br />

in aquifers. One also thinks of industrial processes that have a concentrated<br />

CO 2 stream, such as hydrogen production by reforming hydrocarbons. But the<br />

contribution of CCS to climate change mitigation will remain limited until existing<br />

power plants are massively updated with reliable technology. And it may<br />

be anticipated that this is likely to occur only when the cost of carbon rejected<br />

(the carbon tax) becomes ‘ comparable ’ to the cost of the carbon avoided.<br />

References<br />

1. IPCC ( 2005 ). Special Report on Carbon Dioxide Capture and Storage, Working Group III<br />

of IPCC ( B. Metz , O. Davidson , H. C. de Coninck , M. Loos and L. A. Meyer, eds).<br />

Cambridge University Press , Cambridge .<br />

2. Astarita , G. , D. W. Savage and A. Bisio ( 1983 ). Gas Treating with Chemical Solvents,<br />

Ch. 9: Removal of Carbon Dioxide . Wiley , New York .<br />

3. Chakma , A. ( 1997 ). CO 2 Capture Processes: Opportunities for Improved <strong>Energy</strong><br />

Efficiencies . <strong>Energy</strong> Conv. Mgmt. , 38 , S51 – S58 .<br />

4. Gwinner , B. , D. Roizard , F. Lapicque , et al. ( 2006 ). CO 2 Capture in Flue Gas: Semiempirical<br />

Approach to Select a Potential Physical Solvent . Ind. Eng. Chem. Res. , 45 ,<br />

5044 – 5049 .<br />

5. Ruthven , D. , S. Farooq and K. S. Knaebel ( 1994 ). Pressure-Swing Adsorption , p. 352.<br />

VCH , New York .<br />

6. Kikinides , E. S. , R. T. Yang and S. H. Cho ( 1993 ). Concentration and Recovery of<br />

CO 2 from Flue Gases by Pressure-Swing-Adsorption . Ind. Eng. Chem. Res. , 32 , 2714 .<br />

7. Ishibashi , M. , K. Otake , S. Kanamori and A. Yasutake ( 1999 ). Study on CO 2 Removal<br />

Technology from Flue Gas of Thermal Power Plant by Physical Adsorption Method .<br />

In Greenhouse Gas Control Technology ( P. Riemer , B. Eliasson and A. Wokaun , eds) ,<br />

pp. 95 – 100 . Elsevier , Oxford .<br />

8. Favre , E. ( 2007 ). Carbon Dioxide Recovery from Post-combustion Processes; Can<br />

Gas Permeation Membranes Compete with Absorption? J. Membrane Sci., in press.<br />

9. Castle , W. F. ( 1991 ). Modern Liquid Pump Oxygen Plants: Equipment and<br />

Performance, Cryogenic Processes and Machinery . AIChE Ser. No. 294 , 89 , 14 – 1 7 .<br />

10. Brandvoll, O. and O. Bolland ( 2004 ). Inherent CO 2 Capture using Chemical Looping<br />

Combustion in a Natural Gas Fired Power Cycle . ASME J. Eng. Gas Turbines Power ,<br />

126 , 316–321.<br />

11. Ishida , M. and H. Jin ( 2004 ). A New Advanced Power Generation System using<br />

Chemical Looping Combustion . <strong>Energy</strong> , 19 ( 4 ) , 415 – 422 .<br />

12. Richter , H. J. and K. Knoche ( 1983 ). Reversibility of Combustion Processes,<br />

Efficiency and Costing – Second-law Analysis . ACS Symp. Ser. , 235 , 71 – 8 5 .

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